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Full-Text Articles in Engineering
Solution Atomic Layer Deposition Of Smooth, Continuous, Crystalline Metal-Organic Framework Thin Films, Maïssa K.S. Barr, Soheila Nadiri, Dong-Hui Chen, Peter G. Weidler, Sebastian Bochmann, Helmut Baumgart, Julien Bachmann, Engelbert Redel
Solution Atomic Layer Deposition Of Smooth, Continuous, Crystalline Metal-Organic Framework Thin Films, Maïssa K.S. Barr, Soheila Nadiri, Dong-Hui Chen, Peter G. Weidler, Sebastian Bochmann, Helmut Baumgart, Julien Bachmann, Engelbert Redel
Electrical & Computer Engineering Faculty Publications
For the first time, a procedure has been established for the growth of surface-anchored metal–organic framework (SURMOF) copper(II) benzene-1,4-dicarboxylate (Cu-BDC) thin films of thickness control with single molecule accuracy. For this, we exploit the novel method solution atomic layer deposition (sALD). The sALD growth rate has been determined at 4.5 Å per cycle. The compact and dense SURMOF films grown at room temperature by sALD possess a vastly superior film thickness uniformity than those deposited by conventional solution-based techniques, such as dipping and spraying while featuring clear crystallinity from 100 nm thickness. The highly controlled layer-by-layer growth mechanism of sALD …
Gold/Qds-Embedded-Ceria Nanoparticles: Optical Fluorescence Enhancement As A Quenching Sensor, Nader Shehata, Effat Samir, Ishac Kandas
Gold/Qds-Embedded-Ceria Nanoparticles: Optical Fluorescence Enhancement As A Quenching Sensor, Nader Shehata, Effat Samir, Ishac Kandas
Electrical & Computer Engineering Faculty Publications
This work focuses on improving the fluorescence intensity of cerium oxide (ceria) nanoparticles (NPs) through added plasmonic nanostructures. Ceria nanoparticles are fluorescent nanostructures which can emit visible fluorescence emissions under violet excitation. Here, we investigated different added plasmonic nanostructures, such as gold nanoparticles (Au NPs) and Cadmium sulfide/selenide quantum dots (CdS/CdSe QDs), to check the enhancement of fluorescence intensity emissions caused by ceria NPs. Different plasmonic resonances of both aforementioned nanostructures have been selected to develop optical coupling with both fluorescence excitation and emission wavelengths of ceria. In addition, different additions whether in-situ or post-synthesis have been investigated. We found …
Thermoelectric Porous Mof Based Hybrid Materials, Engelbert Redel, Helmut Baumgart
Thermoelectric Porous Mof Based Hybrid Materials, Engelbert Redel, Helmut Baumgart
Electrical & Computer Engineering Faculty Publications
Porous hybrid materials and MOF (Metal-Organic-Framework) films represent modern designer materials that exhibit many requirements of a near ideal and tunable future thermoelectric (TE) material. In contrast to traditional semiconducting bulk TE materials, porous hybrid MOF templates can be used to overcome some of the constraints of physics in bulk TE materials. These porous hybrid systems are amenable for simulation and modeling to design novel optimized electron-crystal phonon-glass materials with potentially very high ZT (figure of merit) numbers. Porous MOF and hybrid materials possess an ultra-low thermal conductivity, which can be further modulated by phonon engineering within their complex porous …
Charge Storage In Wo³ Polymorphs And Their Application As Supercapacitor Electrode Material, Vaibhav Lokhande, Abhishek Lokhande, Gon Namkoong, Jin Hyeok Kim, Taeksoo Ji
Charge Storage In Wo³ Polymorphs And Their Application As Supercapacitor Electrode Material, Vaibhav Lokhande, Abhishek Lokhande, Gon Namkoong, Jin Hyeok Kim, Taeksoo Ji
Electrical & Computer Engineering Faculty Publications
Tungsten oxide is a versatile material with different applications. It has many polymorphs with varying performance in energy storage application. We report simple and facile way to synthesize four phases of tungsten oxide from same precursor materials only by changing the pH and temperature values. Monoclinic, hexagonal, orthorhombic and tetragonal phase obtained, were analyzed and tested for supercapacitor application. The electrochemical analysis of four phases indicates that the hexagonal phase is best-suited electrode material for supercapacitor. The hexagonal phase exhibits higher specific capacitance (377.5 Fg-1 at 2 mVs-1), higher surface capacitive contribution (75%), better stability and rate …
Microstructural Evaluation Of Aluminium Alloy A365 T6 In Machining Operation, Bankole I. Oladapo, S. Abolfazl Zahedi, Francis T. Omigbodun, Edwin A. Oshin, Victor A. Adebiyi, Olaoluwa B. Malachi
Microstructural Evaluation Of Aluminium Alloy A365 T6 In Machining Operation, Bankole I. Oladapo, S. Abolfazl Zahedi, Francis T. Omigbodun, Edwin A. Oshin, Victor A. Adebiyi, Olaoluwa B. Malachi
Electrical & Computer Engineering Faculty Publications
The optimum cutting parameters such as cutting depth, feed rate, cutting speed and magnitude of the cutting force for A356 T6 was determined concerning the microstructural detail of the material. Novel test analyses were carried out, which include mechanical evaluation of the materials for density, glass transition temperature, tensile and compression stress, frequency analysis and optimisation as well as the functional analytic behaviour of the samples. The further analytical structure of the particle was performed, evaluating the surface luminance structure and the profile structure. The cross-sectional filter profile of the sample was extracted, and analyses of Firestone curve for the …
Novel Contact Materials For Improved Performance Cdte Solar Cells, Angus Rocket, Robert Collins, Sylvain Marsillac
Novel Contact Materials For Improved Performance Cdte Solar Cells, Angus Rocket, Robert Collins, Sylvain Marsillac
Electrical & Computer Engineering Faculty Publications
This program has explored a number of novel materials for contacts to CdTe solar cells in order to reduce the back contact Schottky barrier to zero and produce an ohmic contact. The project tested a wide range of potential contact materials including TiN, ZrN, CuInSe2:N, a-Si:H and alloys with C, and FeS2. Improved contacts were achieved with FeS2. As part of understanding the operation of the devices and controlling the deposition processes, a number of other important results were obtained. In the process of this project and following its conclusion it led to research …
Optical Characterization Of Nanomaterials, Mun S. Jeong, Gon Namkoong, Clare C. Byeon, Jong Su Kim, Hong S. Lee
Optical Characterization Of Nanomaterials, Mun S. Jeong, Gon Namkoong, Clare C. Byeon, Jong Su Kim, Hong S. Lee
Electrical & Computer Engineering Faculty Publications
No abstract provided.