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Pyrolysis And Oxidation Of Chloromethanes Experiment And Modeling, Wenpin Ho
Pyrolysis And Oxidation Of Chloromethanes Experiment And Modeling, Wenpin Ho
Dissertations
An experimental study on pyrolysis and oxidation of CH2Cl2 and CH3Cl in oxygen/hydrogen or oxygen/methane mixtures and argon bath gas was carried out at 1 atmosphere pressure in tubular flow reactors. Degradation of CH2Cl2, or CH3CI, along with the formation and destruction of intermediate and final products was analyzed systematically over 873 to 1273°K, with average residence times of 0.2 to 2.0 seconds.
Thermochemical parameters: enthalpy, entropy, and heat capacities for many chloro-oxy-carbon products and intermediates are calculated using the techniques of group additivity and the THERM computer code. …