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Dissertations

1993

Chemical reaction

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Full-Text Articles in Engineering

Kinetic Study Of Decomposition Of Azo Dyes And Phenol In Advanced Oxidation Processes Reaction Mechanisms, Pathways And Intermediates, Hung-Yee Shu May 1993

Kinetic Study Of Decomposition Of Azo Dyes And Phenol In Advanced Oxidation Processes Reaction Mechanisms, Pathways And Intermediates, Hung-Yee Shu

Dissertations

Advanced Oxidation Processes (AOP) are an emerging technology for treatment of various hazardous organics in wastewater and groundwater. However, the kinetics and mechanisms for AOP have not been well understood. A mechanism including light intensity was studied for the decomposition of azo dyes and phenol in an AOP reactor with a 5,000 watt low pressure mercury lamp. UV light absorption is an important parameter. The effect of pH, hydrogen peroxide dosage, and dye concentration on the decomposition of azo dyes in an H2O2/UV reactor were also studied. Reaction pathways and intermediates of phenol oxidation by different …