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Comparative Evaluation Of The Structural And Other Features Governing Photo-Electrochemical Oxygen Evolution By Ca/Mn Oxides, Ankita Gagrani, Mohammed Alsultan, Gerhard F. Swiegers, Takuya Tsuzuki
Comparative Evaluation Of The Structural And Other Features Governing Photo-Electrochemical Oxygen Evolution By Ca/Mn Oxides, Ankita Gagrani, Mohammed Alsultan, Gerhard F. Swiegers, Takuya Tsuzuki
Australian Institute for Innovative Materials - Papers
Mn-Based oxides, particularly CaMn oxides, have recently attracted significant practical interest as a new class of catalyst due to their elemental and structural similarity to the natural oxygen evolving cluster (OEC) in photosynthetic plant cells. However, their performance as oxygen-generating anodes in photoelectrochemical cells has not been studied in detail. In this work, ultra-fine particles of amorphous MnO2, crystalline MnO2 nanorods, Ca2Mn3O8, CaMn2O4 and CaMnO3 were synthesised using a green and scalable mechanochemical method. The particles were comparatively studied as water oxidation photocatalysts in a photo-electrochemical cell at near-neutral pH. The oxides were immobilized on the anode surface using an …