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Unveiling The Ferrielectric Nature Of Pbzro3-Based Antiferroelectric Materials, Zhengqian Fu, Xuefeng Chen, Zhenqin Li, Tengfei Hu, Linlin Zhang, Ping Lu, Shujun Zhang, Genshui Wang, Xianlin Dong, Fangfang Xu

Australian Institute for Innovative Materials - Papers

© 2020, The Author(s). Benefitting from the reversible phase transition between antiferroelectric and ferroelectric states, antiferroelectric materials have recently received widespread attentions for energy storage applications. Antiferroelectric configuration with specific antiparallel dipoles has been used to establish antiferroelectric theories and understand its characteristic behaviors. Here, we report that the so-called antiferroelectric (Pb,La)(Zr,Sn,Ti)O3 system is actually ferrielectric in nature. We demonstrate different ferrielectric configurations, which consists of ferroelectric ordering segments with either magnitude or angle modulation of dipoles. The ferrielectric configurations are mainly contributed from the coupling between A-cations and O-anions, and their displacement behavior is dependent largely on the chemical …