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Full-Text Articles in Engineering

A Molecular Dynamics Study Of Water Confined In Between Two Graphene Sheets Under Compression, Ming-Lang Tseng, Ayomide Adesiyan, Abdelaziz Gassoumi, Nima E. Gorji Jan 2023

A Molecular Dynamics Study Of Water Confined In Between Two Graphene Sheets Under Compression, Ming-Lang Tseng, Ayomide Adesiyan, Abdelaziz Gassoumi, Nima E. Gorji

Articles

Several studies have demonstrated interest in creating surfaces with improved water interaction and adaptive properties because the behavior of water confined at the nanoscale plays a significant role in the synthesis of materials for technological applications. Remarkably, confinement at the nanoscale significantly modifies the characteristics of water. We determine the phase diagram of water contained by graphene stack sheets in slab form, at T=300 K, and for a constant pressure using molecular dynamics simulations. We discover that, as shown in the simulation, water can exist in both the liquid and vapor phases depending on the confining geometry and compressibility ratio. …


Survey Of Routing Techniques-Based Optimization Of Energy Consumption In Sd-Dcn, Mohammed Nsaif, Gergely Kovásznai, Ali Malik, Ruairí De Fréin Jan 2023

Survey Of Routing Techniques-Based Optimization Of Energy Consumption In Sd-Dcn, Mohammed Nsaif, Gergely Kovásznai, Ali Malik, Ruairí De Fréin

Articles

The increasing power consumption of Data Center Networks (DCN) is becoming a major concern for network operators. The object of this paper is to provide a survey of state-of-the-art methods for reducing energy consumption via (1) enhanced scheduling and (2) enhanced aggregation of traffic flows using Software-Defined Networks (SDN), focusing on the advantages and disadvantages of these approaches. We tackle a gap in the literature for a review of SDN-based energy saving techniques and discuss the limitations of multi-controller solutions in terms of constraints on their performance. The main finding of this survey paper is that the two classes of …


Anti-Bacterial Activity Of Indoor Light Activated Photocatalysts, Suresh Pillai, Michael Seery, Damian Synnott, Stephen Hinder, Georg Michlits Feb 2013

Anti-Bacterial Activity Of Indoor Light Activated Photocatalysts, Suresh Pillai, Michael Seery, Damian Synnott, Stephen Hinder, Georg Michlits

Articles

Nanocrystalline photocatalysts, prepared under ambient conditions using a microwave assisted syn-thesis, show indoor light photocatalytic activity for the degradation of Staphylococcus aureus and Escherichia coli. The zinc sulphide (ZnS) nanomaterials, prepared by a microwave assisted synthesis, are shown to be cubic blende structure with an average crystallite size of 4–6 nm. The anti-bacterial activ-ity of these nanomaterials is investigated under irradiation from a 60 W light bulb and photocatalytic activity is revealed to be due to the defects present in the crystal structure. The ZnS shows anti-bacterial action as both a bacteriostatic and bacteriocidal (88% reduction in the amount of …


A Highly Efficient Tio2-Xcx Nano-Heterojunction Photocatalyst For Visible-Light Induced Antibacterial Applications, Vinodkumar Etacheri, Michael Seery, Stephen Hinder, Georg Michlits, Suresh Pillai Jan 2013

A Highly Efficient Tio2-Xcx Nano-Heterojunction Photocatalyst For Visible-Light Induced Antibacterial Applications, Vinodkumar Etacheri, Michael Seery, Stephen Hinder, Georg Michlits, Suresh Pillai

Articles

Visible-light-induced antibacterial activity of carbon-doped anatase-brookite titania nano-heterojunction photocatalysts are reported for the first time. These heterostructures were prepared using a novel low temperature (100 °C) non-hydrothermal low power microwave (300 W) assisted method. Formation of interband C 2p states was found to be responsible for the band gap narrowing of the carbon doped heterojunctions. The most active photocatalyst obtained after 60 minutes of microwave irradiation exhibits a 2-fold higher visible-light induced photocatalytic activity in contrast to the standard commercial photocatalyst Evonik-Degussa P-25. Staphylococcus aureus inactivation rate constant for carbon-doped nano-heterojunctions and the standard photocatalyst was 0.0023 and -0.0081 min …


Double Quantum Dot Photoluminescence Mediated By Incoherent Reversible Energy Transport, S. Yu Kruchinin, A. V. Federov, A. V. Baranov, T. S. Perova, Kevin Berwick Jan 2010

Double Quantum Dot Photoluminescence Mediated By Incoherent Reversible Energy Transport, S. Yu Kruchinin, A. V. Federov, A. V. Baranov, T. S. Perova, Kevin Berwick

Articles

We present a theoretical study of the stationary photoluminescence of two, direct-gap, semiconductor nanocrystals, taking into account electronic excitation energy-transfer processes due to electrostatic interaction. The results obtained here allow for the incoherent reversible energy transport that occurs when the intraband relaxation rate in a quantum dot acceptor is comparable to, or less than, the energy-transfer rate. We investigate the secondary emission of two different electronic level schemes that can be realized experimentally, obtain analytical expressions for the luminescence differential cross section, and perform an analysis of its spectrum. It is shown that when excitation is not in resonance with …


Synthesis Of High-Temperature Stable Anatase Tio2 Photocatalyst, Suresh Pillai, Declan Mccormack, Michael Seery, Pradeepan Periyat, Steven Hinder, John Colreavy, Reenamol George, Hugh Hayden Jan 2006

Synthesis Of High-Temperature Stable Anatase Tio2 Photocatalyst, Suresh Pillai, Declan Mccormack, Michael Seery, Pradeepan Periyat, Steven Hinder, John Colreavy, Reenamol George, Hugh Hayden

Articles

In the absence of a dopant or precursor odification, anatase to rutile transformation in synthetic TiO2 sually ccurs at a temperature of 600 700 °C. Conventionally, metal oxide dopants (e.g., Al2O3 nd SiO2 are used o tune the anatase to rutile transformation. A simple methodology is reported here to extend the anatase utile transformation by employing various concentrations of urea. XRD and Raman spectroscopy were used uring thermal treatment. A significantly higher anatase phase (97%) as been obtained at 800 C with use of a 1:1 Ti(OPr)4 urea composition and 11% anatase composition is etained even after calcining …