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Full-Text Articles in Engineering

Waste Hemp Fibers (Hfs) Derived Porous Carbons: Preparation, Characterization, And Potential Applications, Manju Gurung Aug 2020

Waste Hemp Fibers (Hfs) Derived Porous Carbons: Preparation, Characterization, And Potential Applications, Manju Gurung

Electronic Thesis and Dissertation Repository

The main objective of the present research was to develop environmentally friendly and cost-effective porous carbon materials of improved properties from waste hemp fibers. Two different types/categories of porous carbons were prepared from hemp fibers. In one type, porous carbon materials were developed by a simple one-step method of carbonization and activation. The other type of carbon materials developed in this study were nitrogen-containing activated carbons, which were developed by introduction of nitrogen-containing functional groups on the surface of hemp fibers followed by activation and carbonization. The pore structure/distribution and surface chemistry of the prepared carbons were investigated through the …


Development Of Technologies For High Value Products From Biomass Pyrolysis, Chiara Barbiero Aug 2020

Development Of Technologies For High Value Products From Biomass Pyrolysis, Chiara Barbiero

Electronic Thesis and Dissertation Repository

Phragmites australis (Cav.) Trin. ex. Steud. is an invasive perennial grass found in North America, which is rapidly spreading throughout Ontario, damaging the native ecosystem and endangering the wildlife. This infestation has caused a decrease in biodiversity and nutrient availability to the agricultural crops through competition. One of the most effective management practices is spading them, leaving a huge number of dead stalks that need to be disposed of. Pyrolysis was selected as an alternative thermochemical method to convert this feedstock to value-added bioproducts, such as bio-oil and biochar, and to produce valuable renewable chemicals from the pyrolysis oil, such …


Smouldering Combustion Treatment Of Soils And Granular Activated Carbon Contaminated With Per- And Polyfluoroalkyl Substances, Alexandra L. Duchesne Mar 2020

Smouldering Combustion Treatment Of Soils And Granular Activated Carbon Contaminated With Per- And Polyfluoroalkyl Substances, Alexandra L. Duchesne

Electronic Thesis and Dissertation Repository

Per- and polyfluoroalkyl substances (PFAS) are emerging contaminants, ubiquitous in the environment, and are challenging to remediate. Self-sustaining Treatment for Active Remediation (STAR) destroys organic contaminants embedded in porous media using smouldering combustion. Self-sustaining smouldering conditions allow the reaction to propagate through the contaminated media without external energy. This study explored STAR as a remediation option for PFAS-impacted granular activated carbon (GAC) and PFAS-contaminated soil. Three smouldering mixtures were used (i) PFAS-spiked GAC and sand, (ii) PFAS-spiked soil and GAC, (iii) PFAS-contaminated field site soil and GAC. Smouldering temperatures were greater than 900˚C, destroying the GAC. Post-treatment PFAS concentrations of …