Engineering Commons^™

Exchange Mechanisms In Macroscopic Ordered Organic Magnetic Semiconductors, Naveen Rawat

Graduate College Dissertations and Theses

Small molecule organic semiconductors such as phthalocyanines and their derivatives represent a very interesting alternative to inorganic semiconductor materials for the development of flexible electronic devices such as organic thin field effect transistors, organic Light Emitting Diodes and photo-voltaic cells. Phthalocyanine molecules can easily accommodate a variety of metal atoms as well in the central core of the molecule, resulting in wide range of magnetic properties. Exploration of optical properties of organic crystalline semiconductors thin films is challenging due to sub-micron grain sizes and the presence of numerous structural defects, disorder and grain boundaries. However, this can be overcome by …

Monitor: Automation Tools For Landscape-Scale Acoustic Monitoring, Jonathan Edward Katz

Graduate College Dissertations and Theses

Climate change coupled with land-use change will likely alter habitats and affect state parameters of the animal populations that dwell in them. Affected parameters are anticipated to include site occupancy and abundance, population range, and phenophase cycles (e.g., arrival dates on breeding grounds for migrant bird species). Detecting these changes will require monitoring many sites for many years, a process that is well suited for an automated system. We developed and tested monitoR, an R package that is designed for long-term, multi-taxa automated passive acoustic monitoring programs. monitoR correctly identified presence for black-throated green warbler and ovenbird in 64% and …

An Embodied Approach To Evolving Robust Visual Classifiers, Karol Zieba

Graduate College Dissertations and Theses

From the very creation of the term by Czech writer Karel Capek in 1921, a "robot" has been synonymous with an artificial agent possessing a powerful body and cogitating mind. While the fields of Artificial Intelligence (AI) and Robotics have made progress into the creation of such an android, the goal of a cogitating robot remains firmly outside the reach of our technological capabilities. Cognition has proved to be far more complex than early AI practitioners envisioned. Current methods in Machine Learning have achieved remarkable successes in image categorization through the use of deep learning. However, when presented with novel …

Teenagers' Mode Choice To And From School And Technology Use For Transportation: Analysis Of Students From Five High Schools In Vermont And California, Paola Rekalde Aizpuru

Graduate College Dissertations and Theses

The carhops and drive-ins of the 1950s are symbolic of the freedom that the automobile has granted Americans. What the general public has gained from the automobile, however, may come at the expense of independent mobility and choices for today's adolescents, particularly those not yet old enough to drive or those from lower income families. Sprawl land use development patterns and limited transportation choices in most American cities often hold teenagers and their chauffeuring parents captive to the automobile. At the same time, information and communication technology is fast evolving and changing the ways in which teenagers live, interact, and …

Characterization Of Fillite As A Planetary Soil Simulant In Support Of Rover Mobility Assessment In High-Sinkage/High-Slip Environments, Michael Edwards

Graduate College Dissertations and Theses

This thesis presents the results of a research program characterizing a soil simulant called Fillite, which is composed of alumino-silicate hollow microspheres harvested from the pulverized fuel ash of coal-fired power plants. Fillite is available in large quantities at a reasonable cost and it is chemically inert. Fillite has been selected by the National Aeronautics and Space Administration (NASA) Glenn Research Center to simulate high-sinkage/high-slip environment in a large test bed such as the ones encountered by the Spirit rover on Mars in 2009 when it became entrapped in a pocket of soft, loose regolith on Mars. The terms high-sinkage …

Robot Localization Obtained By Using Inertial Measurements, Computer Vision, And Wireless Ranging, William Baker

Graduate College Dissertations and Theses

Robots have long been used for completing tasks that are too difficult, dangerous, or distant to be accomplished by humans. In many cases, these robots are highly specialized platforms - often expensive and capable of completing every task related to a mission's objective. An alternative approach is to use multiple platforms, each less capable in terms of number of tasks and thus significantly less complex and less costly. With advancements in embedded computing and wireless communications, multiple such platforms have been shown to work together to accomplish mission objectives. In the extreme, collections of very simple robots have demonstrated emergent …

Characterization Of Real-World Particle Number Emissions During Re-Ignition Events From A 2010 Light-Duty Hybrid-Electric Vehicle, Matthew Beach Conger

Graduate College Dissertations and Theses

Despite the increasing popularity of hybrid-electric vehicles (HEVs), few studies have quantified their real-world particle emissions from internal combustion engine (ICE) re-ignition events (RIEVs). RIEVs have been known to occur under unstable combustion conditions which frequently result in particle number emission rates (PNERs) that exceed stabilized engine operation. Tailpipe total PN (5 to 560 nm diameter) emission rates (#/s) from a conventional vehicle (CV) and hybrid electric vehicle (HEV) 2010 Toyota Camry were quantified on a 50 km (32 mi) route over a variety of roadways in Chittenden County, Vermont using the Total On-board Tailpipe Emissions Measurement System (TOTEMS). While …

Numerical Simulations Of Reacting Flow In An Inductively Coupled Plasma Torch, Maximilian Dougherty

Graduate College Dissertations and Theses

In the design of a thermal protection system for atmospheric entry, aerothermal heating presents a major impediment to efficient heat shield design. Recombination of atomic species in the boundary layer results in highly exothermic surface-catalyzed recombination reactions and an increase in the heat flux experienced at the surface. The degree to which these reactions increase the surface heat flux is partly a function of the heat shield material. Characterization of the catalytic behavior of these materials takes place in experimental facilities, however there is a dearth of detailed computational models for the fluid dynamic and chemical behavior of such facilities. …

Statistical Analysis Of High Sample Rate Time-Series Data For Power System Stability Assessment, Goodarz Ghanavati

Graduate College Dissertations and Theses

The motivation for this research is to leverage the increasing deployment of the phasor measurement unit (PMU) technology by electric utilities in order to improve situational awareness in power systems. PMUs provide unprecedentedly fast and synchronized voltage and current measurements across the system. Analyzing the big data provided by PMUs may prove helpful in reducing the risk of blackouts, such as the Northeast blackout in August 2003, which have resulted in huge costs in past decades.

In order to provide deeper insight into early warning signs (EWS) of catastrophic events in power systems, this dissertation studies changes in statistical properties …

Organic Chemical Characterization Of Primary And Secondary Biodiesel Exhaust Particulate Matter, John Kasumba

Graduate College Dissertations and Theses

Biodiesel use and production has significantly increased in the United States and in other parts of the world in the past decade. This change is driven by energy security and global climate legislation mandating reductions in the use of petroleum-based diesel. Recent air quality research has shown that emission of some pollutants such as CO, particulate matter (PM), SO2, hydrocarbons, and carcinogenic polycyclic aromatic hydrocarbons (PAHs) is greatly reduced with biodiesel. However, studies have also shown that some unregulated emissions, such as gas-phase carbonyls, are increased with biodiesel combustion. Very limited research has been done to investigate the particle-phase carbonyl …

Aero-Thermal Characterization Of Silicon Carbide Flexible Tps Using A 30kw Icp Torch, Walten Owens

Graduate College Dissertations and Theses

Flexible thermal protection systems are of interest due to their necessity for the success of future atmospheric entry vehicles. Current non-ablative flexible designs incorporate a two-dimensional woven fabric on the leading surface of the vehicle. The focus of this research investigation was to characterize the aerothermal performance of silicon carbide fabric using the 30 kW Inductively Coupled Plasma Torch located at the University of Vermont. Experimental results have shown that SiC fabric test coupons achieving surface temperatures between 1000°C and 1500°C formed an amorphous silicon dioxide layer within seconds after insertion into air plasmas. The transient morphological changes that occurred …

Direct Numerical Simulation Of Ablative Boundaries In Turbulent And Laminar Flows, Ryan Campbell Crocker

Graduate College Dissertations and Theses

Rapid surface ablation by a turbulent flow creates complex flow and surface phenomena arising from the evolving boundary topography and its interaction with a turbulent flow that transports the ablative agent onto the surface. The dynamic nature of ablative flow boundaries generate unsteady flow dynamics and thermodynamics occurring over a wide range of scales. The non-equilibrium nature of these phenomena pose a major challenge to the current fundamental understanding of turbulence, which is mostly derived from equilibrium flows, and to Computational Fluid Dynamics (CFD). The simulation of moving boundaries is a necessary tradeoff between computational speed and accuracy. The most …

The Effect Of Biodiesel Blends On Particle Number Emissions From A Light Duty Diesel Engine, Tyler Samuel Feralio

Graduate College Dissertations and Theses

Numerous studies have shown that respirable particles contribute to adverse human health outcomes including discomfort in irritated airways, increased asthma attacks, irregular heartbeat, non-fatal heart attacks, and even death. Particle emissions from diesel vehicles are a major source of airborne particles in urban areas. In response to energy security and global climate regulations, the use of biodiesel as an alternative fuel for petrodiesel has significantly increased in recent years. Particle emissions from diesel engines are highly dependent on fuel composition and, as such, the increased use of biodiesel in diesel vehicles may potentially change the concentration, size, and composition of …

Geomechanical Characterization Of Marcellus Shale, Rafael Villamor Lora

Graduate College Dissertations and Theses

Given their potential applications for a number of engineering purposes, the geomechanics of shale reservoirs is becoming one of the most important issues in modern geomechanics. Borehole stability modeling, geophysics, shale oil and shale gas reservoirs, and underground storage of CO2 and nuclear waste are some of these potential applications to name a few. The growing interest in these reservoirs, as a source for hydrocarbons production, has resulted in an increasing demand for fundamental material property data.

Laboratory analysis and constitutive models have shown that rock elastic and deformational properties are not single-value, well-defined parameters for a given rock. Finding …

The Interaction Mechanisms Of A Screw Dislocation With A Defective Coherent Twin Boundary In Copper, Qiongjiali Fang

Graduate College Dissertations and Theses

Σ3{111} coherent twin boundary (CTB) in face-centered-cubic (FCC) metals and alloys have been regarded as an efficient way to simultaneously increase strength and ductility at the nanoscale. Extensive study of dislocation-CTB interaction has been carried out by a combination of computer simulations, experiments and continuum theory. Most of them, however, are based on the perfect CTB assumption. A recent study [Wang YM, Sansoz F, LaGrange T, et al. Defective twin boundaries in nanotwinned metals. Nat Mater. 2013;12(8):697-702.] has revealed the existence of intrinsic kink-like defects in CTBs of nanotwinned copper through nanodiffraction mapping technique, and has confirmed the effect of …

Ruo2 Nanorods As An Electrocatalyst For Proton Exchange Membrane Water Electrolysis, Richard Smith

Graduate College Dissertations and Theses

The desire for pure diatomic hydrogen gas, H2(g), has been on the rise since the concept of the hydrogen economy system was proposed back in 1970. The production of hydrogen has been extensively examined over 40 + years as the need to replace current fuel sources, hydrocarbons, has become more prevalent. Currently there are only two practical and renewable production methods of hydrogen; landfill gas and power to gas. This study focuses on the later method; using various renewable energy sources, such as photovoltaics, to provide off-peak energy to perform water electrolysis. Efficient electrolysis takes place in electrochemical cells which …

Evaluation Of Key Geomechanical Aspects Of Shallow And Deep Geothermal Energy, Robert Alexander Caulk

Graduate College Dissertations and Theses

Geothermal energy has become a focal point of the renewable energy revolution. Both shallow and deep types of geothermal energy have the potential to offset carbon emissions, reduce energy costs, and stimulate the economy. Before widespread geothermal exploration and exploitation can occur, both shallow and deep technologies require improvement by theoretical and experimental investigations. This thesis investigated one aspect of both shallow and deep geothermal energy technologies. First, a group of shallow geothermal energy piles was modeled numerically. The model was constructed, calibrated, and validated using available data collected from full-scale in-situ experimental energy piles. Following calibration, the model was …

Bioinspired Study On The Mechanical Performance Of Helicoidal Fiber Structures, Brian Ribbans

Graduate College Dissertations and Theses

Helicoidal fiber structures are essential to shell structures of many animals, such arthropods and human bones. Despite prior studies, limited research exists to quantify the mechanical behavior of helicoidal fiber structures with respect to the architecture of the fibers and matrices. The objective of this research is to use an integrated experimental and modeling approach to study the mechanical performance of helicoidal fiber structures under compressive and shear loadings. First, bioinspired helicoidal fiber specimens are created using 3D printed fiber cores and epoxy matrices. Load-displacement curves are collected for the helicoidal fiber specimens under monotonic torsional and compressive loadings to …

Phosphate Removal And Recovery From Wastewater By Natural Materials For Ecologically Engineered Wastewater Treatment Systems, Daniel Thomas Curran

Graduate College Dissertations and Theses

Eutrophication due to excess loading of phosphorus (P) is a leading cause of water quality degradation within the United States. The aim of this study was to investigate P removal and recovery with 12 materials (four calcite varieties, wollastonite, dolomite, hydroxylapatite, eggshells, coral sands, biochar, and activated carbon. This was accomplished through a series of batch experiments with synthetic wastewater solutions ranging from 10-100 mg PO₄-P/ L. The results of this study were used to establish large-scale, calcite-based column filter experiments located in the Rubenstein School of Environment and Natural Resources' Eco-Machine. Influent and effluent wastewater samples were routinely collected …

Burst Pressure Properties And Ex Vivo Analysis Of Alginate-Based Hydrogels For Tissue Sealant Applications, Patrick Nelson Charron

Graduate College Dissertations and Theses

Lung diseases, cancers, and trauma can result in injury to the connective tissue lining the lung, i.e., the pleura. Pleural injuries lead to pneumothoraxes or pleural effusions, i.e., air or fluid leaking out of the lung respectively, and potential lung collapse - an immediately life threatening condition. While several bioengineered soft tissue sealants exist on the market, there is only one sealant FDA-approved for use in pulmonary surgery. In addition, very limited techniques are presented in the literature for characterizing the burst properties of hydrogel tissue sealants. For my thesis, I proposed to develop a protocol for characterizing the burst …

Effect Of Rainfall Events On The Thermal And Moisture Exposure Of Underground Electric Cables, Andrew Fuhrmann

Graduate College Dissertations and Theses

Cable ampacity analysis is generally performed assuming constant worst-state environmental conditions, which often correspond to a dry soil condition or to a condition with uniform ambient soil moisture content. The characteristic time scale of thermal variation in the soil is large, on the order of several weeks, and is similar to the time scale between rainfall events in many geographic locations. Intermittent rainfall events introduce significant transient fluctuations that influence the thermal conditions and moisture content around a buried cable both by increasing thermal conductivity of the soil and by increasing the moisture exposure of the cable insulation. This paper …

Experimental Investigation And Analysis Of High-Enthalpy Nitrogen Flow Over Graphite, Andrew Lutz

Graduate College Dissertations and Theses

The high-enthalpy flow generated by hypersonic vehicles traveling within the Earth's atmosphere inherently delivers an elevated heat flux to the vehicle surface. In addition to conductive heating, the liberated energy generated by various exothermic chemical reactions occurring at the vehicle surface further augment the total heat load. Quantifying the rates at which these reactions take place is imperative and remains a significant challenge as developers attempt to design the next generation of thermal protection systems.

This study focused on nitrogen recombination and carbon nitridation, as these reactions are ubiquitous to the most aggressive atmospheric re-entry trajectories in which carbon-based ablative …

Predicting Trajectory Paths For Collision Avoidance Systems, Cesar Barrios

Graduate College Dissertations and Theses

This work was motivated by the idea of developing a more encompassing collision avoidance system that supported vehicle to vehicle (V2V) and vehicle to infrastructure (V2I) communications. Current systems are mostly based on line of sight sensors that are used to prevent a collision, but these systems would prevent even more accidents if they could detect possible collisions before both vehicles were in line of sight.

For this research we concentrated mostly on the aspect of improving the prediction of a vehicle's future trajectory, particularly on non-straight paths. Having an accurate prediction of where the vehicle is heading is crucial …

Multi-Satellite Formation Trajectory Design With Topological Constraints Over A Region Of Interest Using Differential Evolution, David William Hinckley

Graduate College Dissertations and Theses

Satellite formation missions allow for scientific measurement opportunities that are only otherwise possible with the use of unrealistically large satellites. This work applies the Evolutionary Algorithm (EA), Differential Evolution (DE), to a 4-satellite mission design that borrows heavily from the mission specifications for Phase 1 of NASA's Magnetospheric Multi-Scale Mission (MMS). This mission specifies goals for formation "quality" and size over the arc when scientific measurements are to be taken known as the Region of Interest (ROI). To apply DE to this problem a novel definition of fitness is developed and tailored to trajectory problems of the parameter scales of …

Toward An Understanding Of The Breakdown Of Heat Transfer Modeling In Reciprocating Flows, Ian Pond

Graduate College Dissertations and Theses

Reynolds average Navier-Stokes (RANS) modeling has established itself as a critical design tool in many engineering applications, thanks to its superior computational efficiency. The drawbacks of RANS models are well known, but not necessarily well understood: poor prediction of transition, non-equilibrium flows, mixing and heat transfer, to name the ones relevant to our study. In the present study, we use a direct numerical simulation (DNS) of a reciprocating channel flow driven by an oscillating pressure gradient to test several low- and high-Reynolds' RANS models. Temperature is introduced as a passive scalar to study heat transfer modeling. Low-Reynolds' models manage to …

Bayesian Filtering In Nonlinear Structural Systems With Application To Structural Health Monitoring, Kalil Erazo

Graduate College Dissertations and Theses

During strong earthquakes structural systems exhibit nonlinear behavior due to low-cycle fatigue, cracking, yielding and/or fracture of constituent elements. After a seismic event it is essential to assess the state of damage of structures and determine if they can safely resist aftershocks or future strong motions. The current practice in post-earthquake damage assessment relies mainly on visual inspections and local testing. These approaches are limited to the ability of inspectors to reach all potentially damaged locations, and are typically intended to detect damage near the outer surfaces of the structure leaving the possibility of hidden undetected damage. Some structures in …

Quantification Of The Impact Of Intermittent Renewable Penetration Levels On Power Grid Frequency Performance Using Dynamic Modeling, Elizabeth Ann Kirby

Graduate College Dissertations and Theses

As the technology behind renewable energy sources becomes more advanced and cost-effective, these sources have become an ever-increasing portion of the generation portfolios of power systems across the country. While the shift away from non-renewable resources is generally considered beneficial, the fact remains that intermittent renewable sources present special challenges associated with their unique operating characteristics. Because of the high variability of intermittent renewables, the frequency performance of the system to which they are connected can degrade. Generators assigned to regulate frequency, keeping it close to the desired 60 Hz, are forced to ramp up and down quickly in order …