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University of South Florida

Plasticizer

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Full-Text Articles in Engineering

Sorption Of Benzene, Toluene, Ethylbenzene And Different Ratios Of Mixture Solvent By Plasticized Pema Films Using A Qcm Sensor, Xinpeng Li Nov 2019

Sorption Of Benzene, Toluene, Ethylbenzene And Different Ratios Of Mixture Solvent By Plasticized Pema Films Using A Qcm Sensor, Xinpeng Li

USF Tampa Graduate Theses and Dissertations

VOCs (volatile organic compounds) can cause great harm to human health especially benzene, toluene and ethylbenzene. In this work a Quartz Crystal Microbalance (QCM) sensor with a polymer/plasticizer film was developed to quantify the VOCs both in air and water. QCM is an acoustic wave sensor that can be used well in detecting the aromatic compounds in the film. Because more than one VOC is present in the air, this thesis focuses on finding the sorption of different ratios of VOCs (benzene, toluene, ethylbenzene) using a polymer/plasticizer film in QCM. Poly (ethyl methacrylate) (PEMA) was used as the polymer because …


Sorption Of Benzene, Tolueneand Ethylbenzeneby Plasticized Pema And Pema/Pmma Sensing Films Using Aquartz Crystal Microbalance (Qcm) At 298.15k, Deekshitha Adapa Jun 2019

Sorption Of Benzene, Tolueneand Ethylbenzeneby Plasticized Pema And Pema/Pmma Sensing Films Using Aquartz Crystal Microbalance (Qcm) At 298.15k, Deekshitha Adapa

USF Tampa Graduate Theses and Dissertations

Detection of volatile organic compounds (VOC’s) in the environment is important for human health and wellness. Long term exposure of certain VOC’s like benzene, toluene, ethylbenzene and xylene (BTEX) has a severe effect on human health. There are techniques such as gas chromatography, photo ionization, and mass spectroscopy that are time consuming, require gas sampling and are ineffective in real time sensing in air. Acoustic wave devices such as surface acoustic wave (SAW) devices can be used for sensing BTEX compounds in both vapor and liquid phase. The quartz crystal microbalance (QCM) is a low-frequency acoustic wave device, which can …


Sorption Of Benzene, Toluene And Ethylbenzene By Plasticized Poly (Ethyl Methacrylate) Using Quartz Crystal Microbalance At 298.15k, Kiranpreet Kaur Nov 2018

Sorption Of Benzene, Toluene And Ethylbenzene By Plasticized Poly (Ethyl Methacrylate) Using Quartz Crystal Microbalance At 298.15k, Kiranpreet Kaur

USF Tampa Graduate Theses and Dissertations

Quartz crystal microbalances (QCM) are chemical sensors used for liquid and vapor sensing. In this thesis work, plasticized poly (ethyl methacrylate) (PEMA) coated QCM was used to study sorption behavior of benzene, ethylbenzene and toluene in respective polymer at 298.15K. Poly (ethyl methacrylate) (PEMA) is a promising polymer with solubility parameter close to BTEX compounds, but it's glassy and rigid nature at room temperature make it less sensitive. The addition of plasticizers (Diisononyl cyclohexane-1,2-dicarboxylate (DINCH) and Diisooctyl azelate (DIOA)) lowers the glass transition temperature, provides flexibility and thus increases the free volume of the polymer to enhance analyte sorption. In …