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Full-Text Articles in Engineering
Functionalized Graphitic Nanoreinforcement For Cement Composites, Nima Zohhadi
Functionalized Graphitic Nanoreinforcement For Cement Composites, Nima Zohhadi
Theses and Dissertations
Physical and mechanical properties of graphitic nanomaterials, in particular multiwalled carbon nanotubes (MWCNTs) and graphene nano-platelets (GNPs) make them promising candidates for nanoreinforcement of cement composites. The two key challenges associated with the incorporation of MWCNTs and GNPs are to attain uniform dispersion and interfacial bonding within the composite matrix. The effects of three main-stream dispersion techniques (namely, ultrasonication, acid-etching, and surfactant-coating) on the mechanical properties and microstructure of MWCNT- and GNP-cement composites were experimentally studied. Compressive strength tests and different characterization techniques including dynamic light scattering, Raman spectroscopy, Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, and transmission …
Redox Stable Anodes For Solid Oxide Fuel Cells, Guoliang Xiao, Fanglin Chen
Redox Stable Anodes For Solid Oxide Fuel Cells, Guoliang Xiao, Fanglin Chen
Faculty Publications
Solid oxide fuel cells (SOFCs) can convert chemical energy from the fuel directly to electrical energy with high efficiency and fuel flexibility. Ni-based cermets have been the most widely adopted anode for SOFCs. However, the conventional Ni-based anode has low tolerance to sulfur-contamination, is vulnerable to deactivation by carbon build-up (coking) from direct oxidation of hydrocarbon fuels, and suffers volume instability upon redox cycling. Among these limitations, the redox instability of the anode is particularly important and has been intensively studied since the SOFC anode may experience redox cycling during fuel cell operations even with the ideal pure hydrogen as …
Bio-Inspired And Low-Content Polymer Cement Mortar For Structural Rehabilitation, Nima Zohhadi
Bio-Inspired And Low-Content Polymer Cement Mortar For Structural Rehabilitation, Nima Zohhadi
Theses and Dissertations
Use of polymers as partial replacement for Portland cement in cement mortar and concrete can diminish several drawbacks of these composites such as low tensile strength and strain capacity, high permeability and low adhesion. Main reasons for the use of polymers are to improve damage tolerance, adhesion, and resistance to water permeation. Various polymers with a wide range of physical and mechanical properties have been used in fabrication of cementitious composites. Typical polymer content for such composites is 5% to 20% (by the weight of cement) for both mortar and concrete. There are also drawbacks associated with the use of …
Influence Of Crystal Structure On The Electrochemical Performance Of A-Site-Deficient Sr1-SNb0.1Co0.9O3-Δ Perovskite Cathodes, Yinlong Zhu, Ye Lin, Xuan Shen, Jaka Sunarso, Wei Zhou, Shanshan Jiang, Dong Su, Fanglin Chen, Zongping Shao
Influence Of Crystal Structure On The Electrochemical Performance Of A-Site-Deficient Sr1-SNb0.1Co0.9O3-Δ Perovskite Cathodes, Yinlong Zhu, Ye Lin, Xuan Shen, Jaka Sunarso, Wei Zhou, Shanshan Jiang, Dong Su, Fanglin Chen, Zongping Shao
Faculty Publications
The creation of A-site cation defects within a perovskite oxide can substantially alter the structure and properties of its stoichiometric analogue. In this work, we demonstrate that by vacating 2 and 5% of Asite cations from SrNb0.1Co0.9O3-δ (SNC1.00) perovskites (Sr1-sNb0.1Co0.9O3-δ,s = 0.02 and 0.05; denoted as SNC0.98 and SNC0.95, respectively), a Jahn–Teller (JT) distortion with varying extents takes place, leading to the formation of a modified crystal lattice within a the perovskite framework. Electrical conductivity, electrochemical performance, chemical compatibility and microstructure of Sr1-sNb0.1Co …