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Engineering Commons

Open Access. Powered by Scholars. Published by Universities.®

University of South Carolina

2005

Secondary cells

Articles 1 - 2 of 2

Full-Text Articles in Engineering

Cubic Spline Regression For The Open-Circuit Potential Curves Of A Lithium-Ion Battery, Qingzhi Guo, Ralph E. White Jan 2005

Cubic Spline Regression For The Open-Circuit Potential Curves Of A Lithium-Ion Battery, Qingzhi Guo, Ralph E. White

Faculty Publications

A cubic spline regression model was used to fit the experimental open-circuit potential (OCP) curves of two intercalation electrodes of a lithium-ion battery. All the details of an OCP curve were accurately predicted by the resulting model. The number of regression intervals used to fit an OCP curve was determined in a way such that in each regression interval the OCP exhibits a profile predictable by a third-order polynomial. The locations of the data points used to separate regression intervals were optimized. Compared to a polynomial model with the same number of fitting parameters, the cubic spline regression model is …


A Mathematical Model For A Lithium-Ion Battery/Electrochemical Capacitor Hybrid System, Godfrey Sikha, Ralph E. White, Branko N. Popov Jan 2005

A Mathematical Model For A Lithium-Ion Battery/Electrochemical Capacitor Hybrid System, Godfrey Sikha, Ralph E. White, Branko N. Popov

Faculty Publications

A one-dimensional model for predicting the performance of a battery/electrochemical capacitor-hybrid system has been developed. Simulation results are presented for a LiCoO2|LiPF6 ethylene carbonate/dimethyl carbonate|carbon battery system and a Maxwell PC 10F carbon double-layer electrochemical capacitor. The current shared between the battery and the electrochemical capacitor at very short times depends on the ohmic resistances of the battery and the capacitor. As the discharge proceeds, the operating conditions such as frequency, duty ratio, and peak pulse discharge current control the current shared among parallel circuits. These parameters also determine the extent of the run time increase of …