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Properties Of Non-Tilted Bent-Core Orthogonal Smectic Liquid Crystal, S. Sreenilayam, M. Nagaraj, Yuri Panarin, J. K. Vij, A. Lehmann, C. Tschierske
Properties Of Non-Tilted Bent-Core Orthogonal Smectic Liquid Crystal, S. Sreenilayam, M. Nagaraj, Yuri Panarin, J. K. Vij, A. Lehmann, C. Tschierske
Articles
We present the properties of different achiral orthogonal polar smectic phases observed in a homologous series of bent-core molecular compounds. The macroscopically uniaxial SmAPR phase transforms to biaxial state by the application of higher electric fields and biaxial SmAPA phase undergoes biaxial-uniaxial-biaxial texture transformation with increasing electric fields,i.e.,initial antiferroelectric structure transforms into ferroelectric state under higher electric fields and it shows three different optically distinguishable states. The SmAPAR phase shows an entirely different response compared to other polar smectic phases under study. The dielectric measurements in the SmAPAR phase is the evidence of antiferroelectric behavior of uniaxial state. The polarizing …
Structure And Polymorphism Of Biaxial Bent-Core Smectic Liquid Crystal, S. Sreenilayam, M. Nagaraj, Yuri Panarin, J. K. Vij, A. Lehmann, C. Tschierske
Structure And Polymorphism Of Biaxial Bent-Core Smectic Liquid Crystal, S. Sreenilayam, M. Nagaraj, Yuri Panarin, J. K. Vij, A. Lehmann, C. Tschierske
Articles
The mesomorphic properties of a homologous series of achiral bent-core compounds are studied by polarizing optical microscopy, electro-optics and polarization measurements. Induction of a new orthogonal smectic phases with the increase of alkyl side chain length was observed. One of the compounds exhibits a unique phase transition between four non-tilted smectic phases (SmAPA–SmAPAR-SmAPR-SmA). The uniaxial but antiferroelectric nature of SmAPAR phase was confirmed by POM, current response, the 2nd harmonic electro-optic response and polarization measurements. The structure of SmAPAR phase was studied theoretically by Next-Nearest-Neighbor model and was identified as SmAPα.