Engineering Commons^™

Developing A Crystal Viewer Tool For Nanohub, Osiris V. Ntarugera, Gerhard Klimeck

Gerhard Klimeck

Most materials found in nature have their atoms arranged in a regular and repeated pattern known as crystalline structure; this is particularly true for metals. It is very important to understand the crystal structure of materials in order to predict their properties such as the electric conductivity, heat transfer, and more. Particularly, students and scholars in the field of material science need a way to visualize the different crystal structures. Atomic structures of elements are not visible to the naked eye. In that context, a computer based tool can be used to simulate and to visualize the crystal structures of …

Thermomechanical Behavior Of Nickel Base Single Crystal Superalloy Towards Understanding Of Weld Hot Cracking, S S. Babu, J M. Vitek, S A. David, M Murugananth

Muruganant Marimuthu

"Thermomechanical responses of three single crystal superalloys were measured in between 600 and 1200 degrees C using a thermomechanical simulator. On-heating results showed no softening while testing below 1000 degrees C. In contrast, extensive softening was observed while testing above 1000 degrees C. This rapid softening is related to dissolution of gamma' precipitates. During on-cooling tests from 1300 degrees C, strength recovery of these samples occurred only below 900 degrees C. The delay in strength recovery is attributed to the extent of undercooling required for rapid decomposition of the gamma phase into mixture of gamma and gamma' phases."

Magnetic Properties In Polycrystalline And Single Crystal Ca-Doped Lacoo3, R Zeng, J C. Debnath, Dapeng Chen, P Shamba, Jianli Wang, S J. Kennedy, S J. Campbell, Tania M. Silver, S. X. Dou

Jianli Wang

Polycrystalline (PC) and single crystalline (SC) Ca-doped LaCoO3 (LCCO) samples with the perovskite structure were synthesized by conventional solid-state reaction and the floating-zone growth method. We present the results of a comprehensive investigation of the magnetic properties of the LCCO system. Systematic measurements have been conducted on dc magnetization, ac susceptibility, exchange-bias, and the magnetocaloric effect. These findings suggest that complex structural phases, ferromagnetic (FM), and spin-glass/cluster-spin-glass (CSG), and their transitions exist in PC samples, while there is a much simpler magnetic phase in SC samples. It was also of interest to discover that the CSG induced a magnetic field …

Magnetocapacitance Effect In Nonmultiferroic Yfe03 Single Crystal, Z X. Cheng, H Shen, J Xu, Peng Liu, S J. Zhang, Jianli Wang, Xiaolin Wang, S X. Dou

Jianli Wang

YFeO3 single crystal displays two relaxor-like dielectric relaxations, one at low temperature (170300 K) and one at high temperature (370520 K), which are attributed to the activation of electrons and oxygen vacancies, respectively. Above the temperature at which electrons are activated, the sample displays a large magnetocapacitance effect. Comparison of the impedance Cole-Cole plots measured with and without applied magnetic field reveals that the occurrence of magnetocapacitance effect is accompanied with an increasing in DC conductivity under magnetic field after the activation of electrons, which is explained by the enhancement of electron jumping in Fe2b-O-Fe3b chains by magnetic field. Thus …

Visualization Of Vortex Motion In Feas-Based Bafe1.9ni0.1as2 Single Crystal By Means Of Magneto-Optical Imaging, Zhi W. Lin, Yong Jian Li, Jian G. Zhu, Xiaolin Wang, S. X. Dou, Youguang Guo, Gang Lei, Yi Wang, Matthew Philips, Michael Cortie, Yan-Cheng Li, Ki-Young Choi, Xun Shi

Shi Xue Dou

Superconductivity has been found in newly discovered iron-based compounds. This paper studies the motion of magnetic vortices in BaFe_1.9Ni_0.1As₂ single crystal by means of the magneto-optical imaging technique. A series of magneto-optical images reflecting magnetic flux distribution at the crystal surface were taken when the crystal was zero-field cooled to 10 K. The behavior of the vortices, including penetration into and expulsion from the single crystal with increasing and decreasing external fields, respectively, is discussed. The motion behavior is similar to that observed in high-T_c superconducting cuprates with strong vortex pinning; however, the …

Anisotropic And Excellent Magnetocaloric Properties Of La 0.7ca0.3mno3 Single Crystal With Anomalous Magnetization, J.C Debnath, Rong Zeng, Jung Ho Kim, Dapeng Chen, S X. Dou

Shi Xue Dou

Magnetic properties and the magnetocaloric effect (MCE) have been investigated in La0.7Ca0.3MnO3 single crystal with applied field along both the ab-plane and the c-direction. Due to the magnetocrystalline anisotropy, the crystal exhibits anisotropy in the MCE. Upon application of a 5 T field, the magnetic entropy changes (SM), reaching values of 7.668 J/(kg K) and 6.412 J/(kg K) for both the ab-plane and the c-direction, respectively. A magnetic entropy change of 3.3 J/(kg K) was achieved for a magnetic field change of 1.5 T at the Curie temperature, TC = 245 K. Due to the absence of grains in the …

Effect Of Frozen Spin On The Magnetocaloric Property Of La0.7ca0.3coo3 Polycrystalline And Single Crystal Samples, J C. Debnath, R Zeng, J H. Kim, P Shamba, Dapeng Chen, S X. Dou

Shi Xue Dou

Polycrystalline (PC) and single crystalline (SC) samples of La0.7Ca0.3CoO3 (LCCO) with the perovskite structure were synthesized by conventional solid-state reaction and the floating-zone growth method. We conducted isothermal magnetization measurements of the PC and SC samples at temperatures from 2.8 K to 140 K, and evaluated the magnetic entropy change (−ΔSM) under zero field cooling (ZFC) and field cooling (FC) to 2.8 K. An interesting result has been obtained, where the −ΔSM–T curves in the low temperature range show totally different features between the ZFC and FC cooling procedures. The −ΔSM shows a large inverse irreversibility value for the ZFC …

Single-Crystal Growth And Anisotropic Magnetic Properties Of Nonstoichiometric Three-Layer Sodium Cobalt Oxides, Dapeng Chen, Xiaolin Wang, C T Lin, S X. Dou

Shi Xue Dou

Large single crystals of α-NaxCoO2 (x=0.91, 0.92, and 0.93) have been successfully fabricated by using the traveling solvent floating zone method. Details on the crystal growth are discussed. The crystal structures were characterized using powder x-ray diffraction and Rietveld refinement. The magnetic susceptibility measurements show that the magnetic properties depend strongly on x. The compound was found to be antiferromagnetic at TN ≈ 20 K for x=0.91 and x=0.92, and paramagnetic for x=0.93. The in-plane and out-of-plane anisotropies were observed for the x=0.91 crystals. In addition, the derived anisotropic g-factor ratios (gab /gc) from the anisotropic susceptibility along H||ab and …

Competition Between The Crystal Field And The Exchange Field In Er3+ Doped Ndmno3, Fang Hong, Zhenxiang Cheng, Xiaolin Wang, S X. Dou

Shi Xue Dou

A careful investigation of specific heat shows that the ground state splitting of Nd3þ has been modified by the Er3þ doping, as it shows a nonlinear dependence on the Er3þ doping rate, due to the competition between the crystal field and the exchange field. This competition could be further confirmed by the anomalies in the magnetic entropy and the ground state splitting found in Nd0.9Er0.1MnO3. On the contrary, the ground state splitting of Er3þ has a linear dependence on the doping rate, indicating its stronger dependence on the crystal field rather than the exchange field.

Magnetocapacitance Effect In Nonmultiferroic Yfe03 Single Crystal, Z X. Cheng, H Shen, J Xu, Peng Liu, S J. Zhang, Jianli Wang, Xiaolin Wang, S X. Dou

Shi Xue Dou

YFeO3 single crystal displays two relaxor-like dielectric relaxations, one at low temperature (170300 K) and one at high temperature (370520 K), which are attributed to the activation of electrons and oxygen vacancies, respectively. Above the temperature at which electrons are activated, the sample displays a large magnetocapacitance effect. Comparison of the impedance Cole-Cole plots measured with and without applied magnetic field reveals that the occurrence of magnetocapacitance effect is accompanied with an increasing in DC conductivity under magnetic field after the activation of electrons, which is explained by the enhancement of electron jumping in Fe2b-O-Fe3b chains by magnetic field. Thus …

Crystal Structure And Electronic And Thermal Properties Of Tbfeaso0.85, N Kaurav, Y.T Chung, Y.K Kuo, R S Liu, T S Chan, J.M Chen, J.F Lee, H.S Sheu, Xiaolin Wang, S X. Dou, Sung-Ik Lee, Y.G Shi, A.A Belik, K Yamaura, E Takayama-Muromachi

Shi Xue Dou

The crystal structure and the electronic and thermal properties of a high-quality polycrystalline TbFeAsO0.85 sample made by a high-pressure technique are investigated. The crystal structure, as determined by synchrotron X-ray powder diffraction, possesses a tetragonal unit cell (space group: P4/nmm) with lattice parameters of a=b=3.8851 Å and c =8.3630 Å. In order to elucidate the electronic structure and oxidation states of corresponding elements, X-ray absorption near-edge structure (XANES) spectra are presented. The XANES spectra confirm that the oxidation states of Fe, As, and Tb in the TbFeAsO0.85 sample are ~Fe2+, ~As3−, and ~Tb3+, respectively, which are consistent with the previously …

Angular Dependence Of Pinning Potential, Upper Critical Field, And Irreversibility Field In Underdoped Bafe1.9co0.1as2 Single Crystal, Mahboobeh Shahbazi, Xiaolin Wang, S R. Ghorbani, S. X. Dou, K Y. Choi

Shi Xue Dou

Underdoped BaFe1.9Co0.1As2 single crystal was studied by angular dependence of magneto-transport at fields up to 13 T over a wide range of temperature. Our results show that pinning potential, Uo, decreases slightly for h45 and remains constant for h45, while the upper critical field, Hc2, and the irreversibility field, Hirr, increase with h. According to anisotropic Ginzburg-Landau theory, the anisotropy was determined by scaling the resistivity under different magnetic fields below the superconducting critical temperature, Tc. Anisotropy, C, in the underdoped crystal is found to be temperature dependent and decreases from 2.1 to 1.8 for as T is reduced from …

Dynamics Of Flux-Line Bundles And Voltage-Current Characteristics In A Ba(K)Fe2as2 Single Crystal, K H. Muller, S K. H Lam, Xiaolin Wang, S X. Dou

Shi Xue Dou

Understanding the flux-line dynamics in layered superconductors is of utmost importance for many superconductor applications, yet extracting from measurements the relevant parameters remains a major challenge. Here we report on measurements and theoretical model calculations of voltage-current (V-I) characteristics of a superconducting Ba0.72K0.28Fe2As2 single crystal slightly below its transition temperature in perpendicular magnetic fields between 0.01 and 7 T. We propose a model that describes the flux-line dynamics above, as well as below, the depinning current. The model fits the experimental V-I characteristics remarkably well and is used to extract from the data the field dependence of (a) the depinning …

Thickness-Shear Vibration Of A Rectangular Quartz Plate With Partial Electrodes.Pdf, Huijing He

Huijing He

Analysis Of Electrically-Forced Vibrations Of Piezoelectric Mesa Resonators.Pdf, Huijing He, Guoquan Nie, Jinxi Liu, Jiashi Yang

Huijing He