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Conversion And Kinetics In The Reaction Of Chloroform With Water Vapor At High Temperatures, Chii-Guang Hwang

Theses

This is an experimental study on thermolytic reactions of chloroform with excess water vapor where kinetic parameters are determined and complete product analysis made at atmospheric pressure over a temperature range from 550to 1050°C. In this study, water vapor was introduced as a reactant to convert chlorine in chlorocarbons to stable HCl which is an easily neutralized end-product and thereby completely destroy chloroform. Substantial amounts of thermodynamically stable species: HCl, CO, CO₂, C(s) etc. were observed as products.

The reaction was studied in a 46cm tubular flow reactor mounted in a furnace that had three independently temperature-controlled heating …