Engineering Commons^™

Analysis Of Nitrated Polycyclic Hydrocarbons, Pah-Quinones And Related Compounds In Ambient Air, Yalan Wang

Theses

Studies were conducted to characterized airborne particulate extractable organic matter (EOM) with respect to chemical composition and biological activity. It has been well established that the nitrated polycyclic hydrocarbons (nitroPAH) are environmental contaminants. To identify nitro-PAH in ambient air sample, a technique was developed involving introduction of a reducer column into an reversephase high performance liquid chromatography (HPLC) system. Strong fluorescence signals were achieved from nitro-PAH and detected together with u.v. signals for the qualitative and quantitative analysis of nitro-PAH. 2-Nitrotriptycene was synthesized according to published procedures and used as an internal standard. By use of the above technique, 9nitroanthracene, …

Three Studies On Airborne Polycyclic Aromatic Hydrocarbons, Carol Sophia Eveleens

Theses

Three studies have been conducted on polycyclic aromatic hydrocarbons found on airborne particulate matter. The first investigation involves the determination of fly ash "activity" in the reaction of two PAHs adsorbed on its surface. Mass spectrometry is used to monitor the exchange of hydrogen and deuterium atoms between anthracene and anthracene-d10. The results indicate that some fly ashes exhibit "activity" in the reactions of PAHs adsorbed on its surface. The second investigation involves the determination of cyclopenta[cd]pyrene (CcdP) and benzo[ghi]flouranthene (BghiF) on samples of airborne particulate material collected from two automobile traffic tunnels. Glass capillary gas chromatography with a precolumn …

Thermal Rearrangement Studies Of Deuterium Labeled Dibenzo [A,E] Cyclooctatetraenes, Charles W. Wenger

Theses

In an attempt to further substantiate the findings of Stiles and Salisbury on the rearrangement of aryl disubstiuted dibenzo [a, e] cyclooctatetraenes a new pair of derivatives were synthesized. The 5,6 and 5,11 dideuteriodibenzo-[a,e] cyclcoctetetraenes were prepared. The 5,6 derivative was prepared starting with dibenzo [a,e] cyclooctene-5,6-dione. The 5,11 derivative was prepared starting with o-tolualdehyde. In the case of the 5,6 derivative the deuterium was introduced by a LiAlD₄ reduction of the dibenzo [a,e]-cyclooctene-5,6-dione. The 5,11 derivative had been labeled with deuterium in the final step during the Wittig reaction. The use of methanol-d₁ as the solvent in …

Solvents Screening For Hydrocarbons Separation Of Close Molar Volumes, Dilip K. Kapasi

Theses

The approximate physical model for solute-solvent inter?actions presented by J, M, Prausnitz and R, Anderson¹ is briefly discussed, Applicability of Weimer, Prausnitz³ and Helpinstill, Van Winkle⁷ models is investigated using experimental values of activity coefficients for C₅ hydrocarbons in 13 solvents including one nonpolar and 12 polar solvents. Independent correlations, based on our experimental values at 45°C for normal and isopentane have been developed. Although the required thermodynamic properties are obtained through a comparative analysis of all the available and estimated methods, dependable values of activity coefficients for Isopentane and 1-Pentene could not be obtained through …

Evaluation Of Benedict's Equation For Calculation Of Critical Pressures Of Hydrocarbon Mixtures, Thomas William Owens

Theses

An introduction to the problem of critical pressure calculations of mixtures is presented, followed by a brief history of prior work in this field. Mentioned in the history are the correlations of Watson and Nelson, Smith and Watson, Mayfield, Kuratta and Katz, Benedict, and Edmister. Another section contains a series of tables showing critical pressure calculated by Benedict's equation as contrasted to other data appearing in the literature. An evaluation of the equation is then made from the comparisons.

Included are curves of the values shown in the tables end a series of curves depicting the deviation of these values …