Engineering Commons^™

Mass Spectrometry Analysis Of Contaminants Of Emerging Concern: Nanoparticles, Algal Toxins, And Cyanotoxins In Natural Waters And Their Potential Health Impacts, Ariel R. Donovan

Doctoral Dissertations

“The analysis of contaminants of emerging concern is critical to protecting environmental health. In the presented dissertation, two groups of contaminants of emerging concern were assessed using mass spectrometry methods: nanoparticles and algal and cyanotoxins.

Analysis of metal oxide nanoparticles in environmental matrices has been a challenging issue, as most traditional methods require complicated sample preparation methods or that can alter or destroy the nanoparticles in the system. Single particle inductively coupled plasma mass spectrometry (SP-ICP-MS) methods were used to detect metal oxide nanoparticles in surface waters and their removal through drinking water treatment simulations while retaining all information regarding …

Nanoscale Solidification Of Metals By Atomistic Simulations: From Nucleation To Nanostructural Evolution, Avik Mahata

Doctoral Dissertations

"Homogeneous nucleation during solidification in Al (fcc), Fe (bcc) and Mg (hcp) is studied by million-atom molecular dynamics (MD) utilizing the second nearest neighbor modified embedded atom method (2NN-MEAM) potentials. Spontaneous homogenous nucleation from the melt was produced without any influence of pressure, free surface effects and impurities. We also study the effect on the simulation size on homogenous nucleation and the heterogeneity in homogenous nucleation. The heterogeneity in homogenous nucleation originates from the twins, grain boundaries and short range order in the liquid during the initial stages of solidification.

To study the solid-liquid coexistence in binary Al alloys, interatomic …

Plasmonic Metamaterial For Structural Color Printing And Spontaneous Emission Control, Wei Wang

Doctoral Dissertations

”Plasmon polaritons or plasmons are a collective oscillation movement of free electrons in metal at optical frequencies. The frequency-dependent complex dielectric function makes the metal property at optical frequencies behave totally different with that at other spectral ranges with lower frequency such as infrared and microwaves. This novel property makes the so called plasmonics or nanoplasmonics a rapid growing research field over the past few years. Many innovative concepts and applications have been developed such as perfect absorber, structural color printing, and quantum emitter spontaneous emission enhancement.

In this dissertation two of the most important applications will be addressed. The …

Design And Performance Of Fiber-Reinforced Concrete With Adapted Rheology For Construction And Repair Of Bridge Structures, Ahmed Abdelrazik

Doctoral Dissertations

“The objective of this document is to design high-performance fiber-reinforced self-consolidating concrete (FR-SCC) for infrastructure repair and fiber-reinforced super-workable concrete (FR-SWC) for bridge construction. The investigated fibers included propylene synthetic fibers, hooked steel fibers, double and triple hooked steel fibers, hybrid crimped steel fiber and polypropylene multifilament fibers, and micro-macro steel fibers. The fiber volume varied between 0 and 0.75%. An expansive agent (EA) was incorporated to compensate for shrinkage and induce compression in the concrete at early age. Two types of EA (G and K) were employed at 0 to 8%, by mass of binder. The investigated FRSCC and …

Characterization Of A Green Electric Solid Propellant For Electric Propulsion, Matthew Scott Glascock

Doctoral Dissertations

"Electric solid propellants are advanced solid chemical rocket propellants that can be controlled (ignited, throttled and extinguished) through the application and removal of an electric current. These propellants are also being considered for use in ablative pulsed plasma thruster and multimode systems. In this work, the behavior and performance of a novel green electric solid propellant operating in an electrothermal ablation-fed pulsed plasma thruster was investigated. Using an inverted pendulum micro-Newton thrust stand, the impulse bit and specific impulse of the device using the electric solid propellant were measured for short-duration and long-duration runs to end-of-life, at energy levels of …

Modeling Strategies For Estimating And Suppressing Electromagnetic Interference And Improving Power Integrity, Tamar Makharashvili

Doctoral Dissertations

"Decoupling capacitors are used to suppress high-frequency noise in power distribution networks. The inductance associated with a mounted decoupling capacitor can vary by 26% depending on characteristics of the printed circuit board. Here, simple and accurate inductance models of 2- and 8-terminal capacitors including connections to the power and return plane are developed. Circuit models of the capacitors and layout are created using the partial equivalent element circuit method which provide options for circuit-level simulations as well as analytic estimation of inductance. The circuit solution matches results from the full-wave simulation model within 9% for the 8-terminal capacitor and within …

Insights Into Well Performance And Completion Optimization Using A Coupled Fracfocus And Drillinginfo Database, Mustafa A. Al-Alwani

Doctoral Dissertations

“The hydraulic fracturing designs, drilling, and completion trends are undergoing continuous change as the oil and gas industry pushing the boundaries of the traditional designs to increase wells productivity and meet the energy demand. The lateral length in addition to the amount of proppant and water used in well stimulation have witnessed a paradigm shift over the past few years. The motivation for this work began with a desire to better understand well performance as a function of the type of fracturing fluid treatment applied. An early objective was to compare whether East Texas Cotton Valley wells stimulated with water …

Active-Passive Dynamic Consensus Filters: Theory And Applications, John Daniel Peterson

Doctoral Dissertations

”This dissertation presents a new method for distributively sensing dynamic environments utilizing integral action based system theoretic distributed information fusion methods. Specifically, the main contribution is a new class of dynamic consensus filters, termed active-passive dynamic consensus filters, in which agents are considered to be active, if they are able to sense an exogenous quantity of interest and are considered to be passive, otherwise, where the objective is to drive the states of all agents to the convex hull spanned by the exogenous inputs sensed by active agents. Additionally, we generalize these results to allow agents to locally …

Deep Understanding Of Degradation In Lithium Ion Batteries Through Experimental And First-Principles Study, Yufang He

Doctoral Dissertations

"The growing interests in Lithium-ion Batteries (LIBs) have significantly accelerated the development of active materials. However, the key challenge is that electrode materials suffer from degradation, which include transition metal dissolution, solid electrolyte interphase (SEI) layer formation, and mechanical fracture. To address these issues, applying an ultrathin coating onto active materials via Atomic Layer Deposition (ALD) is an efficient way. Although numerious works have been done for active material performance improvement via ALD technology, the fundamental enhancement mechanisms of ALD coating on battery performance improvement are not yet known. Therefore, this dissertation consists of four papers, which focused on the …

Detection And Elimination Of Rock Face Vegetation From Terrestrial Lidar Data Using The Virtual Articulating Conical Probe Algorithm, Kenneth John Boyko

Doctoral Dissertations

"A common use of terrestrial lidar is to conduct studies involving change detection of natural or engineered surfaces. Change detection involves many technical steps beyond the initial data acquisition: data structuring, registration, and elimination of data artifacts such as parallax errors, near-field obstructions, and vegetation. Of these, vegetation detection and elimination with terrestrial lidar scanning (TLS) presents a completely different set of issues when compared to vegetation elimination from aerial lidar scanning (ALS). With ALS, the ground footprint of the lidar laser beam is very large, and the data acquisition hardware supports multi-return waveforms. Also, the underlying surface topography is …

Chemically-Bonded Enamel-Coated Steel Pipelines For Corrosion Protection And Flow Efficiency, Liang Fan

Doctoral Dissertations

"This study is to explore and develop chemically-bonded enamel coating (200-300 um) on steel pipes, when subjected to soil and thermal environments, in order to improve the corrosion protection and safety of hazardous liquid and natural gas pipelines while reducing pressure loss. Out of five types of enamels and their various mixtures, Tomatec slurry and GP2118 powder were selected for steel pipeline applications. They were applied at approximately 810 °C to the inside surface of steel pipes in wet and electrostatic processes, respectively. The thickness and surface roughness of the enamel coating were measured using a gauge and an optical …

Assessment And Prediction Of Surface Water Vulnerability From Non-Point Source Pollution In Midwestern Watersheds, Fadhil K. Jabbar

Doctoral Dissertations

"Non-point source pollution is the leading cause of impairment in surface water in the Midwest. In this research, we seek to predict which watersheds are most vulnerable to point source pollution without field sampling using publically available GIS databases. Watersheds with higher vulnerability ratings can then be targeted for water quality monitoring, and funds used to improve watershed health can be distributed with greater efficacy. To better understand and target watershed vulnerability, we used three different approaches. In the first project, 35 sub-watersheds were sampled in the Lower Grand Watershed, which is a highly agricultural watershed in northern Missouri/southern Iowa. …

Investigating Blast Fume Propagation, Concentration And Clearance In Underground Mines Using Computational Fluid Dynamics (Cfd), Raymond Ninnang Tiile

Doctoral Dissertations

"Blasting activities using standard industry explosives is an essential component of underground hard rock mining operations. Blasting operations result in the release of noxious gases, presenting both safety and productivity threats. Overestimation of post-blast re-entry time results in production losses, while underestimation leads to injuries and fatalities. Research shows that most underground mines simply standardize post-blast re-entry times based on experiences and observations. Few underground mines use theoretical methods for calculating post-blast re-entry time. These theoretical methods, however, are unable to account for the variations in the blasting conditions. Literature review shows that: (i) there is currently no means of …

Dynamic Impact Induced By Tornadoes Through Simulations Based On Two-Way Wind-Structure Interactions, Tiantian Li

Doctoral Dissertations

"Tornadoes have become a significant cause of property damage, injuries and life losses. Investigations of tornadoes indicate that most fatalities were caused by building failure. For example, in the Joplin, MO tornado of 22 May 2011, 161 people were killed, and 84% fatalities were related to building failure. Therefore, it is imperative to develop science-based tornado-resistant building codes, in order to provide a better level of occupant protection from tornadoes and to minimize the tornado-induced damage. This requires in-depth understanding of the wind characteristics of tornadoes and their wind effects on civil structures, based on which design tornadic wind loading …

Hydrodynamics Of Trickle Bed Reactors (Tbrs) Packed With Industrial Catalyst Using Advanced Measurement Techniques, Mohammed Jaber Al-Ani

Doctoral Dissertations

"The impacts of the packing characteristics on the hydrodynamics od a trickle bed reactor (TBR) have been investigated using advanced measurements techniques of Gamma-ray densitometry (GRD) and Optical fiber probe and conventional measurement techniques of high-frequency differential pressure transducer and load cell. Two different reactor sizes of bench and pilot plant scale were used. Bench-scale TBR carried out the experiments to assess phase distribution and catalyst utilization with 1.18 cm inside diameter and 72 cm length at ambient pressure and temperature. The mixture of catalyst and fine particles displayed considerable improvements in the phase distribution, liquid holdup profile, and catalyst …

Microstructural Evolution Of Zirconium Carbide (Zrcₓ) Ceramics Under Irradiation Conditions, Raul Florez

Doctoral Dissertations

A comprehensive understanding of the microstructural evolution of Zirconium Carbide (ZrC₂) ceramics under irradiation conditions is required for their successful implementation in advanced Gen-IV gas-cooled nuclear reactors. The research presented in this dissertation focusses on elucidating the ion and electron irradiation response of ZrC₂ ceramics. In the first part of the research, the microstructural evolution was characterized for ZrC₂ ceramics irradiated with 10 MeV Au³⁺ ions up to doses of 30 displacement per atom (dpa) at 800 ºC. Coarsening of the defective microstructure, as a function of dose, was revealed by transmission electron microscopy analysis. …

Investigating The Use Of Different Types Of Sealant Materials For Cement Remedial Applications, Murad Mohammedahmed Abdulfarraj

Doctoral Dissertations

"The overall objective is to investigate the ability of several material to mitigate cement failures such as channels, fractures, and micro-annuli in oil and gas wells. The sealant material that can also be used in the wells that are used for geologic storage of carbon dioxide CO₂. Evaluating the sealant material is critical to improve the zonal isolation of the wells, which would lead to safer operations. The approach of this dissertation is to utilize particles gel that has been used successfully in conformance control application, and epoxy resin systems, that have superior seal characteristics compared to conventional …

Hardware Architectures For Compact Microwave And Millimeter Wave Cameras, Matthew Jared Horst

Doctoral Dissertations

"Millimeter wave SAR imaging has shown promise as an inspection tool for human skin for characterizing burns and skin cancers. However, the current state-of-the-art in microwave camera technology is not yet suited for developing a millimeter wave camera for human skin inspection. Consequently, the objective of this dissertation has been to build the necessary foundation of research to achieve such a millimeter wave camera. First, frequency uncertainty in signals generated by a practical microwave source, which is prone to drift in output frequency, was studied to determine its effect on SAR-generated images. A direct relationship was found between the level …

Military Applications Of Geological Engineering, Stephen H. Tupper

Doctoral Dissertations

"This work examines the premise that military engineering and geological engineering are intellectually paired and overlapped in practice to a significant extent. Geological engineering is an established, albeit young, academic discipline that enjoys wide industry and civil demand and is supported by many professional organizations. In contrast, military engineering is an ancient, empirically derived training or "OJT" program with practice-based trade-associations that has narrow government-only utility. The premise is formed by decades-long observation of U. S. Army military engineer officers completing a Master of Science degree in geological engineering as a complement to their practice-based training in military engineering at …

Plugging Performance Of Preformed Particle Gels In Fractures And Its Influencing Factors, Ze Wang

Doctoral Dissertations

"Preformed particle gels (PPG) has been successfully applied to combat the water channeling caused by fractures or fracture-like channels. Understanding the placement and plugging of PPG in fractures is crucial for gel treatment design. The objective of the dissertation is to explore the plugging performance of three PPG products in two types of fracture models, the partially and fully open fractures. The following studies has been conducted and conclusions have been drawn based on the results and analysis. First, the placement and plugging performance of conventional PPG was investigated using core flooding experiments conducted partially open fractures. The plugging efficiency …

Electrodeposition Of Epitaxial Metal Thin Films On Silicon For Energy Conversion And Flexible Electronics, Qingzhi Chen

Doctoral Dissertations

"This research focuses on epitaxial electrodeposition of two coinage metals: Au and Ag thin films on the silicon surface and their applications in flexible electronics and energy conversion and storage. The first paper: Photoelectrochemistry of ultrathin, semi-transparent, and catalytic gold films electrodeposited epitaxially onto n-silicon (111) describes the epitaxial electrodeposition of Au thin films on n-type Si using a simple HAuCl4 bath and the photoelectrochemical properties of the Au-Si junction barrier. The effect of the Au layer on the interfacial energetics as well as the stability of the photoelectrode as a function of the Au coverage/thickness is determined in a …

Non-Invasive Microwave And Millimeter Wave Reflectometry And Imaging For Human Skin Diagnosis And Materials Characterization, Yuan Gao

Doctoral Dissertations

"Microwave and millimeter wave reflectometry and synthetic aperture radar (SAR) imaging techniques have been successfully applied in many applications, such as nondestructive testing and evaluation (NDT&E), security inspection and medical diagnosis. In this dissertation, the feasibility of using microwave and millimeter reflectometry and SAR imaging for burn diagnosis is investigated through both simulations and measurements, with promising results. To correctly model the interaction between electromagnetic waves and skin, the proper knowledge of the complex permittivity of healthy skin is critically important. To this end, the common used measurement methods for in vivo skin complex permittivity are reviewed and analyzed in …

Nanomorphology Dependent Optical And Mechanical Properties Of Aerogels, Chandana Mandal

Doctoral Dissertations

"Aerogels are very low density, light weight open pore materials. A hypothesis that is under intense current investigation by the scientific community states that the mechanical properties of nanostructured polymers depend on their nanomorphology. Aerogels are nanostructured ultra-lightweight nanoporous materials with skeletal frameworks that can display a wide range of nanomorphologies. Thereby aerogels comprise a suitable platform for testing not only that hypothesis but also a wide range of other properties such as light scattering for applications, for example, in thermally insulating windows.

To study the mechanical properties of nanostructured matter as a function of nanomorphology, various shape-memory polyurethane aerogels …

Reactor Configurations To Support Advanced Material Research, Thaqal Mazyad Alhuzaymi

Doctoral Dissertations

"The research goal is to configure a research reactor with multi-spectral capability for advance material research. This required the consideration of high and low-power levels alongside advanced fuel with high physical density and low enriched ²³⁵U. Selected fuel was U-10Mo with 19.75% ²³⁵U enrichment. The fuel and control rods system geometries were adopted from Missouri S&T Reactor (MSTR).

A high-power configuration (HPC) at 2 megawatts and low-power configuration (LPC) at 200 kilowatts were considered. Neutronic performances of the configurations were modeled using Monte Carlo N-particle (MCNP) transport code, version 6. Thermal-hydraulic analysis was performed with ANSYS Fluent. The …

Investigating The Performance Of High Viscosity Friction Reducers Used For Proppant Transport During Hydraulic Fracturing, Mohammed Salem Ba Geri

Doctoral Dissertations

"Over the last few recent years, high viscosity friction reducers (HVFRs) have been successfully used in the oil and gas industry across all premier shale plays in North America including Permian, Bakken, and Eagle Ford. However, selecting the most suitable fracture fluid system plays an essential role in proppant transport and minimizing or eliminating formation damage.

This study investigates the influence of the use of produced water on the rheological behavior of HVFRs compared to a traditional linear guar gel. Experimental rheological characterization was studied to investigate the viscoelastic property of HVFRs on proppant transport. In addition, the successful implication …

Multi-Body Dynamic And Finite Element Modeling Of Ultra-Large Dump Truck - Haul Road Interactions For Machine Health And Haul Road Structural Integrity, Bruno Ayaga Kansake

Doctoral Dissertations

"Haul truck capacities have increased due to their economies of scale in large-scale surface mine production systems. Ultra-large trucks impose high dynamic loads on haul roads. The dynamic loads are exacerbated by road surface roughness and truck over-loading. The dynamic forces also subject trucks to high torsional stresses, which affect truck health. Current haul road response models are 2D and use static truckloads for low capacity trucks. Existing 3D models consider the road as a two-layer system. No models capture the truck dynamic effects on haul roads and predict strut pressures during haulage.

Lagrangian mechanics was used to formulate the …

Biomaterials For Bone Regeneration, Youqu Shen

Doctoral Dissertations

"The purpose of this Ph.D. research is to investigate and improve two classes of hydroxyapatite (HA)-based biomaterials for bone repair: calcium phosphate microspheres and bioactive silicate glass scaffolds. These biomaterials were prepared with modified compositions and microstructures and then were evaluated for bone regeneration.

The open HA microspheres with dense convex surfaces and rough and porous concave surfaces were obtained by sectioning closed hollow HA microspheres. Bone regeneration with the open HA microspheres was greater than with the closed HA microsphere at 12 weeks. Hollow biphasic calcium phosphate (BCP) microspheres have been prepared with different fractions of HA and β-TCP …

Thermomechanical Analysis Of Rock Asperity In Fractures Of Enhanced Geothermal Systems, Chao Zeng

Doctoral Dissertations

"Enhanced Geothermal Systems (EGS) offer great potential for dramatically expanding the use of geothermal energy and become a promising supplement for fossil energy. The EGS is to extract heat by creating a subsurface system to which cold water can be added through injection wells. Injected water is heated by contact with rock and returns to the surface through production well. Fracture provides the primary conduit for fluid flow and heat transfer in natural rock. Fracture is propped by fracture roughness with varying heights which is called asperity. The stability of asperity determines fracture aperture and hence imposes substantial effect on …

Improvements In Digital Image Correlation And Application In Material Mechanical Test, Yunlu Zhang

Doctoral Dissertations

"Digital image correlation (DIC) is a non-contact full-field optical measurement method. With the advantages of high accuracy, low cost, and simple implementation, it has been widely applied in the area of experimental mechanics. In this study, DIC algorithm has been improved in the aspects of the pixel-level searching method and reference frame update strategy. The feature matching based method is proposed to provide an initial guess for all points of interest with semi-subpixel level accuracy in cases with small or large translation, deformation, or rotation. The bisection searching strategy is presented to automatically adjust the frame step for varying practical …

Deep Neural Network Learning-Based Classifier Design For Big-Data Analytics, Krishnan Raghavan

Doctoral Dissertations

"In this digital age, big-data sets are commonly found in the field of healthcare, manufacturing and others where sustainable analysis is necessary to create useful information. Big-data sets are often characterized by high-dimensionality and massive sample size. High dimensionality refers to the presence of unwanted dimensions in the data where challenges such as noise, spurious correlation and incidental endogeneity are observed. Massive sample size, on the other hand, introduces the problem of heterogeneity because complex and unstructured data types must analyzed. To mitigate the impact of these challenges while considering the application of classification, a two step analysis approach is …