Engineering Commons^™

Bioaccumulation Of Polychlorinated Biphenyl Compounds And Mercury In A Mining Impacted Aquatic Ecosystem, Michelle Bollini

Dissertations, Master's Theses and Master's Reports

The Keweenaw area continues to be influenced by the century of copper mining that ended nearly 50 years ago. This project is focused on Torch Lake, an aquatic ecosystem that has been heavily impacted by mining waste disposal. The watershed has been impaired by mine discharge and tailings, smelter and smokestack plumes, and poor waste disposal practices. The lake is listed as a Great Lakes Area of Concern with beneficial use impairments of restrictions on fish consumption and a degraded benthic community. Polychlorinated biphenyl compounds (PCBs) and methylmercury (MeHg) are persistent, bioaccumulative, and toxic substances (PBTs). These contaminants pose threats …

A Model To Predict Concentrations And Uncertainty For Mercury Species In Lakes, Ashley Hendricks

Dissertations, Master's Theses and Master's Reports

To increase understanding of mercury cycling, a seasonal mass balance model was developed to predict mercury concentrations in lakes and fish. Results indicate that seasonality in mercury cycling is significant and is important for a northern latitude lake. Models, when validated, have the potential to be used as an alternative to measurements; models are relatively inexpensive and are not as time intensive. Previously published mercury models have neglected to perform a thorough validation. Model validation allows for regulators to be able to make more informed, confident decisions when using models in water quality management. It is critical to quantify uncertainty; …

Evaluation, Improvement, And Application Of Models Of Environmental Fate And Transport Of Atmosphere-Surface Exchangeable Pollutants (Aseps), Tanvir Khan

Dissertations, Master's Theses and Master's Reports

Certain toxic, semivolatile chemicals, also known as atmosphere-surface exchangeable pollutants (ASEPs) are emitted into the environment from anthropogenic activities and natural sources. This dissertation focused on the (i) evaluation and improvement of dry particle deposition and atmosphere-surface exchange parameterizations of ASEPs for use in chemical transport models (CTMs), and (ii) application of a dynamic multimedia model to examine recovery of Lake Superior from historical inputs of polychlorinated biphenyl (PCB) compounds (a class of ASEPs) contamination.

Current knowledge has been inadequate to propose quantitative measures of the relative performance of available dry particle deposition parameterizations. In Chapter 1 of this dissertation, …