Engineering Commons^™

Visualization Of Molecular Dynamics Simulation Data, Suroj Shrestha

Honors Theses

No abstract provided.

Engineering Design Of A Prototype Ammonia Absorption Tower, Andrew Warren Calogero

Honors Theses

No abstract provided.

Reductive Dechlorination Of High Concentrations Of 1,2-Dichloroethane, 1,2-Dichloropropane, And 1,1,2-Trichloroethane By Dehalogenimonas Sp., Andrew D. Maness

LSU Master's Theses

The research goals presented here were to evaluate the solvent concentrations over which Dehalogenimonas lykanthroporepellens strain BL-DC-9T and Dehalogenimonas sp. IP3-3 are able to reductively dechlorinate 1,2-dichloroethane (1,2-DCA), 1,2-dichloropropane (1,2-DCP), and 1,1,2-trichloroethane (1,1,2-TCA). Both of these novel bacteria were isolated from contaminated groundwater at the PetroProcessors of Louisiana, Inc. Superfund site located near Baton Rouge. Both cluster in the phylum Chloroflexi, related to, but distinct from, the widely studied, reductively dechlorinating “Dehalococcoides” strains .

Although previous research demonstrated that strains BL-DC-9T and IP3-3 are able to reductively dechlorinate a variety of polyhalogenated alkanes, the solvent concentration at which the strains …

The Use Of A Mixed Chlorella Cyanobacteria Culture As A Protein Source For Aquaculture, Marjan Sadat Mohtashamian

LSU Master's Theses

The increase in the global demand for fish feed in the last decades has resulted in the over exploitation of natural resources to produce more fishmeal supplies for aquaculture industry. The supply issues and high prices of fishmeal products have raised the incentives to seek for suitable alternatives to replace fishmeal protein. As a by-product of biofuel production process, residual microalgal biomass may be a low cost feed ingredient to the aquaculture diet. The potential of the use of a post lipid extraction Chlorella vulgaris/Leptolyngbya sp. Co-Culture (Louisiana co-culture) as a protein source in aquaculture feeds could help offset fishmeal. …

Fatigue Performance Of Existing Bridges Under Dynamic Loads From Winds And Vehicles, Wei Zhang

LSU Doctoral Dissertations

During the life cycle of bridges, varied amplitude of stress ranges on structural details are induced by the random traffic and wind loads. The progressive deteriorated road surface conditions might accelerate the fatigue damage accumulations. Micro-cracks in structural details might be initiated. An effective structural modeling scheme and a reasonable fatigue damage accumulation rule are essential for stress range acquisitions and fatigue life estimation. The present research targets at the development of a fatigue life and reliability prediction methodology for existing steel bridges under real wind and traffic environment with the capability of including multiple random parameters and variables in …

Computer Simulations Of Faceted Nanoparticles And Carbon Nanotubes In Liquid Crystals, Shivkumar Shankar Bale

LSU Doctoral Dissertations

The purpose of this research is to investigate the use of liquid crystals (LCs) to manipulate and organize faceted nanoparticles and carbon nanotubes (CNTs). Computer simulations at different levels of detail are used to study these systems. Results from this project will be relevant for potential applications of these systems in displays, nanoscale electronics, electro-optical switches, and in the development of composites with unique mechanical, thermal and/or electronic properties. In this research, two independent but directly related projects were carried out. In the first part of the research, we investigated the torque that develops when faceted nanoparticles, namely cubes and …

A Thermodynamic Framework For The Modeling And Optimization Of Crystallization Processes, David John Widenski

LSU Doctoral Dissertations

Crystallization is a widely used chemical engineering separation unit operation process. Since this technique can produce high purity products it is used for the industrial production of many chemical compounds, such as pharmaceuticals, agrochemicals, and fine chemicals. The production of these products is a multi-million dollar industry. Any methods to improve the production of these products would be highly valued. Thus, the main objective of this work is to target model-based optimal strategies for crystallization operations specifically targeting crystal size and crystal size distribution (CSD). In particular, take the knowledge gained and translate it into an economically and practically feasible …

Copper-Cobalt Catalysts For Conversion Of Syngas To Ethanol And Higher Alcohols, Miranda Louise Smith

LSU Doctoral Dissertations

Higher alcohols produced by catalytic conversion of synthesis gas are potential octane enhancers for transportation fuels. Copper-cobalt catalysts have emerged as alternatives to the ethanol-selective, but expensive, rhodium-based ones. The reducibility of the catalyst and the CO adsorption mode are important factors in directing the selectivity of CO hydrogenation toward methanol, hydrocarbons, or higher alcohols. In this study, Cu/SiO2, Co/SiO2, and bimetallic CuCo/SiO2 catalysts, as well as their tin-promoted analogues, were synthesized and characterized by TPR, in situ XRD, in situ XANES, and in situ DRIFTS. Cobalt addition to Cu/SiO2 created an amorphous fraction of CuO that was more easily …

Thermal Field Investigations And Applications To Integral Abutment Bridges With Frp Panels, Bo Kong

LSU Doctoral Dissertations

Expansion joints are often considered as one of the most vulnerable elements affecting the sustainability of traditional jointed bridges. Over the past several decades, a new type of integral abutment bridge (IAB) has been proposed, where the joints are eliminated at the abutments and/or along the length of the bridges. Although with wide acceptances, the IABs have not been largely applied in practice. Many arguments are unsettled and there are no national design guidelines currently. Among all, the thermal behavior is one of the most concerned issues, and that, to a large extent, limits the maximum length of IABs that …

Growth Rate And Productivity Of A Louisiana Native Microalgae/Cyanobacteria Co-Culture: Feasibility For Use In Industrial Biotechnology Applications, Athens Gomes Silaban

LSU Master's Theses

Interest in biofuels research has increased in the era of uncertainty of the current fossil fuel sustainability and global climate concerns. Microalgae offer advantages over terrestrial plants as a potential source of biomass-based fuel. In this study, a Louisiana native microalgae/cyanobacteria (Chlorella vulgaris/Leptolyngbya sp.) co-culture was examined to provide foundational information of its growth conditions. Batch studies were conducted to determine optimum nitrogen and irradiance level that yields maximum co-culture biomass growth and productivity under aerated and non-aerated conditions. The optimum nitrogen level was 2.94 mM N and the optimum initial scalar irradiance range was between 400 – 800 µmol …

Characterizing Impact Induced Hot-Spot Morphology In Granular Solid Explosive, John Gilbert

LSU Master's Theses

Deformation induced ignition of heterogeneous solid explosives is believed to originate at hot-spots within the material which are local regions of elevated temperature resulting from dissipative mechanisms such as plastic deformation and inter-particle friction. Inert meso-scale modeling of these materials can principally account for hot-spot formation enabling the characterization of hot-spot size and temperature distributions which are important for ignition but are di_x000E_cult to experimentally resolve. The focus of this study is to characterize hot-spot morphology, as well as the distribution of hot-spots, behind quasi-steady compaction waves computed from predicted temperature fields resulting from numerical simulations of rigid planar piston …

Biodegradation And Distribution Of Crude Oil Sampled At Fourchon Beach, Kendall Ray Lemelle

LSU Master's Theses

This study was developed to determine the distribution and fate of crude oil spilled from the Deepwater Horizon oil rig starting on April 24, 2010. Crude oil from this spill contaminated portions of Fourchon Beach, Louisiana which was the study site for this thesis. Understanding the fate processes that affect crude oil once it’s released is important because the compounds that comprise oil can be hazardous to humans and wildlife. Composite and small surface residual ball (SSRB) samples were collected from the supratidal zone of Fourchon Beach and analyzed for PAHs and alkanes. Alkane concentrations decreased significantly over time, while …

Electric Elevator Drive With Position Control, Peter James Ford

LSU Master's Theses

This thesis is a study on the implementation of an elevator’s position-controlled electric drive. The information contained within this paper serves as a framework to expand the usefulness of electric drives through the addition of digital control systems and switching power supplies. The tangible example of an elevator driven by a permanent-magnet DC motor is used for this paper so that students may relate to the work and apply it to their future projects. The tasks to be accomplished in order to achieve an electric elevator drive with position control are: determining the parameters of the permanent-magnet DC motor, designing …

Efficacy Of Multifunctionalized Saccharide Constructs For The Attenuation Of Amyloid-Beta Toxicity, Dhruva Dilip Dhavale

LSU Doctoral Dissertations

There is evidence that amyloid-beta (Aβ) toxicity is mediated through interactions and binding with neuronal surface sialic acids in Alzheimer’s disease (AD). The binding affinity is higher if the sialic acids are clustered and toxicity of Aβ was attenuated by removal of neuronal sialic acids. Thus, interfering with cell membrane-Aβ binding using biomimetics that could reproduce the clustered sialic acid structure could present us with a potential target for therapeutic intervention in AD. Based on this hypothesis, we developed several multifunctionalized sialic acid labeled chitosan compounds of different valency, or number of sialic acid per chitosan molecule, to attenuate Aβ …

A Modeling, Optimization, And Analysis Framework For Designing Multi-Product Lignocellulosic Biorefineries, Paritosh Kumar Sharma

LSU Doctoral Dissertations

The objective of this research is to propose a methodology to develop modular decision analysis frameworks to design value chains for enterprises in the renewable fuels and chemicals sector. The decision support framework focuses on providing strategic decision support to startup and new product ventures. The tasks that are embedded in the framework include process and systems design, technology and product selection, forecasting cost and market variables, designing network capacities, and analysis of risks. The Decision support system (DSS) proposed is based on optimization modeling; systems design are carried out using integer programming with multiple sets of process and network …

Multiscale Viscoplastic-Viscodamage Analysis Of Shape Memory Polymer Fibers With Application To Self Healing Smart Materials, Amir Shojaei

LSU Doctoral Dissertations

Self-healing smart material systems have been introduced into the research arena and they have already been deployed into industrial applications. The Close-Then-Heal (CTH) healing mechanism for polymeric self-healing systems is addressed herein and then a new generation of Shape Memory Polymer (SMP) based self-healing system is proposed in this work. This system incorporates SMP fibers to close the cracks while the embedded Thermoplastic Particles (TPs) are diffused into the crack surfaces upon heating and provide a molecular level of healing. The SMP fiber manufacturing procedure is briefly addressed in this work in which the bobbin of SMP fibers are heat …

Effects Of Recycled Asphalt Shingle On The Rheological And Molecular Composition Properties Of Asphalt Cement, Saman Salari

LSU Master's Theses

Recycling of asphalt shingles in flexible pavements has received interests in recent years due to economic, environmental, and social reasons. The objective of this study is to introduce a new approach to recycle asphalt shingles in asphalt paving construction in which RAS is ground to ultra-fine sizes and blended with asphalt binder through a wet process. In this method, the ground recycled material is blended with the binder at high temperature prior to mixing with the aggregates. Two unmodified binders that are classified as PG64-22 and PG52-28 were blended with two contrasting sources of RAS, originating from tear-off and manufacturer …

Shear Strength Evaluation Of An Erosional Soil System At Fourchon Beach, Jacques Pierre Boudreaux

LSU Master's Theses

South Louisiana is vanishing. Subsidence due to relative sea level rise with erosion of weak wetland soils together produce devastating rates of land loss for this area. It is believed that high rates of erosion are due to weak strength properties of fine-grained sediments in the beaches, marshes, and other wetlands in coastal Louisiana. Wave action is known to initiate the movement of weak coastal soils in a manner that is related to the difference between the shear stresses applied by waves and the critical shear strength of erosional sediments. Direct shear tests were performed on samples obtained from the …

Turbine Blade Internal Cooling: Trailing Edge, Coolant-Passage Entry, Bend Effect And Improvement In Thermal Performance, Krishnendu Saha

LSU Doctoral Dissertations

Efficient cooling of gas turbine blade is imperative for safe operation of the gas turbine engine at high temperatures. In the present work, two converging lattice structures suitable for trailing edge applications are tested and their performance is compared with a conventional pin-fin configuration. Another constant cross section lattice structure is tested to see the cooling efficiency of lattice channels with different number of sub-channels. Converging lattice structures show higher heat transfer enhancement and comparable or higher thermal performance than traditional pin-fin cooling used in gas turbine trailing edge. The highest pressure drop incurred in a multi-pass channel is at …

Dynamic Characterization Of Vocal Fold Virbrations, Zhenyi Wei

LSU Doctoral Dissertations

An emerging trend among voice specialists is the use of quantitative protocols for the diagnosis and treatment of voice disorders. Vocal fold vibrations are directly related to voice quality. This research is devoted to providing an objective means of characterizing these vibrations. Our goal is to develop a dynamic model of vocal fold vibration, and map the parameter space of the model to a class of voice disorders; thus, furthering the assessment and diagnosis of voice disorder in clinical settings.

To this end, this dissertation introduces a new seven-mass biomechanical model for the vibration of vocal folds. The model is …

Laboratory Evaluation Of Geosynthetics To Stabilize/Reinforce The Subgrade/Base In Unpaved Roadways, Imran Akond

LSU Master's Theses

This research study evaluates the performance of geosynthetic material for subgrade stabilization and base reinforcement of unpaved test sections. For this purpose, extensive large-scale in-box static plate load tests were conducted on several unreinforced and geosynthetic reinforced, unpaved test sections. This research was conducted in Geotechnical Engineering Research Laboratory (GERL) at Louisiana Transportation Research Center (LTRC). The in-box static plate load tests (ASTM D1196-93) were conducted to evaluate the performance and benefits of geosynthetic material for subgrade stabilization/base reinforcement. A total of forty-seven tests were performed in this regard. The quality control of the section was maintained using non-destructive in-situ …

Synthesis, Characterization, And Testing Of Atomically-Precise Au Clusters Supported On Tio₂ For Co Oxidation, Sarthak Gaur

LSU Doctoral Dissertations

Supported Au catalysts have been studied extensively for CO oxidation. These catalysts are known to catalyze this reaction even at sub-ambient temperatures. While recent literature demonstrates catalytic activity of gold nanoparticles <2 nm, the next stage in fine tuning this catalysis process is to develop gold clusters prepared with atomic precision. Such atomically precise gold catalysts supported on TiO2 hitherto have not been investigated for CO oxidation. The main objective of this work is to synthesize atomically-precise Au38 clusters in a flask-based method using principles of wet chemistry, to characterize these clusters using various advanced spectroscopic techniques, and to test these clusters as potential catalytic materials for CO oxidation. Furthermore, we have tested TiO2-supported Au38 clusters and a commercially purchased Au/TiO2 catalyst for CO oxidation at 30 °C and 60 °C, and used DRIFTS as a probe spectroscopic technique to correlate kinetics with the mechanism occurring on the surface of both catalysts in order to device the mechanistic pathways for CO oxidation. The work reported in this dissertation is the first spectroscopic observation of the phenomena where sulfur may have beneficial effect on the catalytic activity of Au/TiO2 catalysts. Such an interesting observation where sulfur has beneficial effect on catalytic activity of Au/TiO2 catalysts has never been observed in the past. We have also synthesized and tested Fe3O4@Au core-shell nanoparticles supported on TiO2 for CO oxidation. We show for the first time that, core-shell type nanogold catalysts are better suited compared to pure gold nanoparticles for heterogeneous gas phase catalysis of CO oxidation. By conducting comprehensive experiments towards understanding CO oxidation catalysis using X-ray photoelectron spectroscopy, infrared spectroscopy, and temperature programmed reduction, we show that the enhanced catalytic activity is due to a combination of factors ranging from synergistic interaction between Au and Fe, complete removal of organic capping ligands and the presence of metallic gold (Au0) in the active catalyst.

A Novel Rna Extraction Method For Cyanobacteria, Zenghui Zhang

LSU Master's Theses

Research on production of polyhydroxyalkanoates (PHA) by microorganisms has captured attention over the last two decades, since PHA have similar properties as petroleum-based thermoplastics, yet are close to carbon neutral and made from renewable sources. Cyanobacteria are considered to be good PHA producers because of their simple nutrient requirements (mainly water, sunlight and CO2) and fast cell growth. However, knowledge of metabolisms behind PHA production by cyanobacteria is limited. Therefore, gene expression analysis of cyanobacteria is required to get a thorough understanding at the molecular level, and gene expression analysis requires the extraction of high quality RNA. Extracting high quality …

Differential Gene Expression In A Louisiana Strain Of Microalgae, John Joseph Tate

LSU Master's Theses

Considerable interest in alternative energy has stimulated research in biofuels, particularly microalgal biofuels. In particular, strains of algae that accumulate lipids to be used for biofuels must be adapted to outdoor growth and resistant to invasive species. Differential gene expression in a Louisiana algae/cyanobacteria co-culture consisting of approximately 97% Chlorella vulgaris and 3% Leptolyngbya sp. possessing these traits was examined. Possible reasons for the enhanced growth of the co-culture relative to a Chlorella monoculture were reviewed, including cyanobacterial symbiosis and chemicals produced by cyanobacteria or bacteria that could influence the growth of Chlorella. The co-culture and Chlorella monoculture were cultivated …

A Review Of Offshore Blowouts And Spills To Determine Desirable Capabilities Of A Subsea Capping Stack, Louise Matilde Smith

LSU Master's Theses

The events surrounding the Deepwater Horizon disaster have changed the face of deepwater operations. In order to continue drilling in the Gulf of Mexico, the regulatory body, the Bureau of Safety and Environmental Enforcement (BSEE), has required that applications to conduct work in the Gulf of Mexico (GOM) include a plan to stop, capture, or contain any uncontrolled release of fluids. The capping and containment systems built and implemented by BP during the event are an excellent starting point for minimizing pollution from deepwater subsea blowouts, but the system has limitations. The industry recognizes these limits but is currently focused …

Surface-Modified Plga Nanoparticles For Targeted Drug Delivery To Neurons, Jingyan Li

LSU Master's Theses

The blood-brain barrier (BBB), which protects the central nervous system (CNS) from unnecessary substances, is a challenging obstacle in the treatment of CNS disease such as Parkinson’s Disease (PD). Many therapeutic agents such as hydrophilic and macromolecular drugs cannot overcome the BBB. One promising solution is the employment of polymeric nanoparticles (NPs) such as poly (lactic-co-glycolic acid) (PLGA) NPs as drug carrier. Over the past few years, significant breakthroughs have been made in developing suitable poly (lactic-co-glycolic acid) (PLGA) and poly (lactic acid) (PLA) nanoparticles for drug delivery across the BBB. Recent advances on PLGA/PLA NPs enhanced neural delivery of …

Double-Bond Isomerization Of Long Chain Olefins, James Edward Bruno

LSU Master's Theses

Bruno, James Edward, B.S., Western Michigan University, 2010 Master of Science, Fall Commencement, 2012 Major: Chemical Engineering Double-Bond Isomerization of Long Chain Olefins Thesis directed by Professor Kerry Dooley Pages in thesis, 54. Words in Abstract, 349. ABSTRACT Alkenyl Succinic Anhydride (ASA) is commonly used in the paper industry as a sizing agent. ASA is produced by reacting maleic anhydride with long-chain internal olefins. Such olefins are only available with the double bond in the terminal position, so an isomerization step is necessary. The isomerization can be catalyzed using solid strong acid catalysts, such as those containing sulfonic acid groups. …

Boron Composite Nanoparticles For Enhancement Of Bio-Fuel Combustion, Neng Wang

LSU Master's Theses

Bio-fuels such as ethanol are good candidates to replace fossil fuels, which are being depleted, and whose combustion is associated with net production of greenhouse gases and other environmental issues. However, bio-fuels have low energy densities and can be subject to incomplete combustion. Boron is a promising additive for bio-fuels in combustion applications. It can increase their overall heat release and reduce ignition temperature, because boron itself is among the highest energy density materials. In this study, different B/rare earth oxide and B/Fe composite nanoparticles were produced by simple mechanical milling. Also, a new low temperature milling method was developed …

Quantification Of Nox Reduction Via Nitrate Accumulation On A Tio2 Photocatalytic Concrete Pavement, David James Osborn

LSU Master's Theses

Field trials of photocatalytic pavements were recently initiated and are presently being considered by many states (e.g., Virginia, Texas, New York, and Missouri). Results from this study originate from the country’s first air-purifying asphalt and concrete photocatalytic pavements, constructed on Dec. 20, 2010. The test area is a pavement site located on the LSU campus. The objective of the study is to validate field photocatalytic degradation of NOx in a field environment by measuring the day to day accumulation of the oxidized byproduct; nitrate salts. The mass of nitrates, produced by the real life photocatalytic pavement, were measured. The measurement …

Programmable Cmos Analog-To-Digital Converter Design And Testability, Rajiv Soundararajan

LSU Doctoral Dissertations

In this work, a programmable second order oversampling CMOS delta-sigma analog-to-digital converter (ADC) design in 0.5µm n-well CMOS processes is presented for integration in sensor nodes for wireless sensor networks. The digital cascaded integrator comb (CIC) decimation filter is designed to operate at three different oversampling ratios of 16, 32 and 64 to give three different resolutions of 9, 12 and 14 bits, respectively which impact the power consumption of the sensor nodes. Since the major part of power consumed in the CIC decimator is by the integrators, an alternate design is introduced by inserting coder circuits and reusing the …