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Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications IV

2017

Uranium carbide – Uranium oxide – Oxidation – HT-ESEM – Ignition

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Oxidation Of Uc: An In-Situ High Temperature Environmental Scanning Electron Microscopy Study, Claudia Gasparrini, Michael J.D. Rushton, William E. Lee, Renaud Podor, Denis Horlait, Olivier Fiquet Sep 2017

Oxidation Of Uc: An In-Situ High Temperature Environmental Scanning Electron Microscopy Study, Claudia Gasparrini, Michael J.D. Rushton, William E. Lee, Renaud Podor, Denis Horlait, Olivier Fiquet

Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications IV

Uranium carbide (UC) has the potential to be used as fuel in Generation IV nuclear reactors thanks to its higher metal atom density and better thermal conductivity when compared to the most commonly used fuel: uranium dioxide (UO2) [1]. Although UC offers improved properties during operation, it needs to be converted into an oxide form after usage as it is reactive and potentially pyrophoric [2] in oxidising environments. Previous oxidation studies on UC, performed over a range of oxygen atmospheres and temperatures, suggest different mechanisms lead to the formation of either a protective or a pulverised non-protective oxide …