Engineering Commons^™

Mechanical Properties And Performance Of A Novel Nano-Engineered Unitized Composite With Quasi-Isotropic Layup, Brian Matthew Pudlo

Theses and Dissertations

Carbon nanotubes (CNTs) exhibit outstanding mechanical, electrical, and thermal properties, but are a challenge to effectively implement into macroscopic composites for aerospace applications. This research investigates the mechanical properties and performance of a newly developed hybrid NanoStitch composite, alongside a control polymer matrix composite, at room temperature. Both composite material systems investigated in this work have quasi-isotropic layup. Monotonic tension-tofailure, tension-tension fatigue, and creep tests were performed to characterize the performance of the composites under cyclic and sustained loading. Experimental results obtained for the quasi-isotropic NanoStitch composite were compared to those obtained for the quasi-isotropic control composite. The properties and …

Mechanical Properties And Performance Of A Novel Nano-Engineered Unitized Composite For Aerospace Systems, Benjamin C. Lam

Theses and Dissertations

Carbon nanotubes (CNTs) exhibit outstanding mechanical properties, such as exceptionally high tensile stiffness and strength, combined with excellent electrical and thermal characteristics. This research investigates the mechanical properties and performance of a newly developed hybrid nano-engineered composite. The carbon fiber/polymer matrix composite incorporates a forest of vertically aligned CNTs, called NanoStitch, between the prepreg plies. Basic tensile properties of both material systems were investigated for both on-axis [0/90] and off-axis [±45] fiber orientations at room temperature. Tension-tension fatigue tests were performed with a frequency of 1.0 Hz and a ratio of minimum stress to maximum stress of R= 0.05. Fatigue …

Electro-Mechanical Characterization Of Carbon Nanotube Sheets In Simulated Space Environments: The Dawn Of “Carbon Spacecraft”, Jacob W. Singleton

Theses and Dissertations

Carbon nanotube (CNT) materials are exciting candidates for spacecraft by virtue of their unprecedented specific mechanical and electrical properties. Analysis in this thesis identifies 14 types of CNT-sheets with distinct variables, and discovers the mechanisms controlling macroscopic properties. Specimen variables include acid treatment, polymer coatings, production method, and combinations. Mechanical testing includes tensile-tests and investigation with scanning electron microscopy and energy-dispersive x-ray spectroscopy. Physical properties testing include electromagnetic interference (EMI) shielding effectiveness (SE) and electrical conductivity. This research also highlights the resilience of CNT-sheets to atomic oxygen and thermal fatigue qualifying them for performance in space. EP CNT-sheets have decreased …

Removal Of Perfluorooctanoic Acid From Water Using Primitive, Conventional And Novel Carbonaceous Sorbent Materials, Christopher K. Brown

Theses and Dissertations

Polyfluoroalkyl Substances (PFAS), like perfluorooctanoic acid, have been used for the last 50 years in a wide variety of industrial processes and consumer-based products, including polymer additives, lubricants, fire retardants and suppressants, pesticides, and surfactants (Buck et al. 2015). The Department of Defense (DoD) has used PFAS-based Aqueous Film Forming Foam (AFFF) at fire training facilities and aircraft hangars. AFFF has contaminated approximately 600 sites classified as fire training facilities with PFAS (Huang, 2013).

This study focused on testing the most likely carbonaceous adsorbent compounds to remediate PFAS-contaminated sites on Air Force installations. Batch tests were performed to determine the …

Electrical And Physical Property Characterization Of Single Walled Carbon Nanotube Ink For Flexible Printed Electronics, Kristian E. Warner Jr.

Theses and Dissertations

This research presents a method of characterizing single-walled carbon nanotube (SWCNT) ink. This research also examines the results of our characterization efforts. First, the process of ink jet printing SWCNT ink onto organic and inorganic substrates is discussed. Next, the tests for measuring sheet resistance, conductance, inductance, adherence, thickness, roll-off, and S-parameters of the ink are described. Results and findings of the research are presented. The SWCNT ink created by Brewer Science © is shown to be an effective material for additive manufacturing using an aerosol jet printer, but not an inkjet printer. The ink is shown to have a …

Carbon Allotrope Dependence On Temperature And Pressure During Thermal Decomposition Of Silicon Carbide, Munson J. Anderson

Theses and Dissertations

Bulk CNT and graphene films form on SiC using a metal-catalyst-free thermal decomposition approach. In this work, the background vacuum pressure and temperature used in the decomposition process are varied to investigate their impact on the type and quality of carbon allotrope formed on the SiC substrate. The carbon nanostructure growth is performed using two approaches, both of which involve intense heating (1400-1700°C) of SiC under moderate vacuum conditions (0.01 - 0.00001 Torr). The first growth method uses a conventional graphite resistance furnace capable of annealing waferscale samples over 1700°C under vacuum. Using this approach, post-growth characterization is performed using …