Engineering Commons^™

Chromatographic Analysis Of The Chemical Composition Of Pyrolysis Distillate, Sh.T. Juraev, B.F. Muxiddinov, U.T. Tailakov

Chemical Technology, Control and Management

The paper presents the results of a study of the physico-chemical characteristics of the liquid fraction of products of thermal oxidative pyrolysis of worn tires. The mass fraction of the volatile gas compounds, the optimal boiling points of the obtained condensates and the flashpoint of pyrolysis liquids, together with the mass composition of cracking products of rubber products at high-temperature pyrolysis at a temperature of 800-900 °C, were determined. Chromatographic analysis allowed us to determine the composition, mainly the mass composition of pyrolysis products, which consisted of carbon (42.8%), higher aliphatic and aromatic hydrocarbons (17.0%), methane (10.2%), benzene (4.2%) and …

Valorization Of Spent Vetiver Roots For Biochar Generation, Sameer Neve, Dibyendu Sarkar, Manas Warke, Teresa Bandosz, Rupali Datta

Michigan Tech Publications, Part 2

Vetiver root is widely used to produce essential oils in the aromatherapy industry. After the extraction of oil, the roots are disposed of as waste. The central objective of this research was to explore the conversion of this waste into a resource using a circular economy framework. To generate biochar, vetiver roots were pyrolyzed at different temperatures (300, 500, and 700 °C) and residence times (30, 60, and 120 min). Analysis showed the root biochar generated at 500 °C and held for 60 min had the highest surface area of 308.15 m2/g and a yield of 53.76%, in addition to …

Modular Open-Source Design Of Pyrolysis Reactor Monitoring And Control Electronics, Finn K. Hafting, Daniel G. Kulas, Etienne Michels, Sarvada Chipkar, Stefan Wisniewski, David Shonnard, Joshua M. Pearce

Michigan Tech Publications, Part 2

Industrial pilot projects often rely on proprietary and expensive electronic hardware to control and monitor experiments. This raises costs and retards innovation. Open-source hardware tools exist for implementing these processes individually; however, they are not easily integrated with other designs. The Broadly Reconfigurable and Expandable Automation Device (BREAD) is a framework that provides many open-source devices which can be connected to create more complex data acquisition and control systems. This article explores the feasibility of using BREAD plug-and-play open hardware to quickly design and test monitoring and control electronics for an industrial materials processing prototype pyrolysis reactor. Generally, pilot-scale pyrolysis …

Establishing Physical And Chemical Mechanisms Of Polymerization And Pyrolysis Of Phenolic Resins For Carbon-Carbon Composites, Ivan Gallegos, Josh Kemppainen, Jacob R. Gissinger, Malgorzata Kowalik, Adri Van Duin, Kristopher E. Wise, S. Gowtham, Gregory Odegard

Michigan Tech Publications, Part 2

The complex structural and chemical changes that occur during polymerization and pyrolysis critically affect material properties but are difficult to characterize in situ. This work presents a novel, experimentally validated methodology for modeling the complete polymerization and pyrolysis processes for phenolic resin using reactive molecular dynamics. The polymerization simulations produced polymerized structures with mass densities of 1.24 ± 0.01 g/cm3 and Young's moduli of 3.50 ± 0.64 GPa, which are in good agreement with experimental values. The structural properties of the subsequently pyrolyzed structures were also found to be in good agreement with experimental X-ray data for the phenolic-derived carbon …

Upgrading Biomass To Bio-Oil: Catalytic Hydrodeoxygenation And Pyrolysis Of Vanillin And Anisole Biomass Model Compounds, Ahmad J. Yaghi

Theses

The purpose of this project is to investigate capacity of selected formulations of catalysts toward the hydrodeoxygenation (HDO) of biomass model compounds in the gas phase with the underlying aim to produce hydrocarbon cuts that can be directly used as transportation fuels. The first part of this project is to devoted to illustrate procedures for the synthesis of potent (HDO) catalysts. Synthesized catalysts encompass nickel (Ni), cobalt (Co) and palladium (Pd) supported on zeolite, cerium oxide (CeO₂) or alumina (Al₂O₃). Various characterization techniques such as X-ray Diffraction (XRD), Temperature Programmed Reduction (TPR) were deployed …

Deconstructed Plastic Substrate Preferences Of Microbial Populations From The Natural Environment, Lindsay I. Putman, Laura G. Schaerer, Ruochen Wu, Daniel G. Kulas, Ali Zolghadr, Rebecca Ong, David Shonnard, Stephen Techtmann

Michigan Tech Publications

Over half of the world's plastic waste is landfilled, where it is estimated to take hundreds of years to degrade. Given the continued use and disposal of plastic products, it is vital that we develop fast and effective ways to utilize plastic waste. Here, we explore the potential of tandem chemical and biological processing to process various plastics quickly and effectively. Four samples of compost or sediment were used to set up enrichment cultures grown on mixtures of compounds, including disodium terephthalate and terephthalic acid (monomers of polyethylene terephthalate), compounds derived from the chemical deconstruction of polycarbonate, and pyrolysis oil …

Fire Protection And Life Safety Analysis Of The 2704-Hv Hanford Building, Guillermo Rodriguez

Fire Protection Engineering: Culminating Experience Project Reports

This report analyzes multiple aspects of fire protection and life safety design for the 2704-HV Building located at the Hanford Nuclear Reservation Site in Washington State. The analysis contained within focuses on both prescriptive and performance-based designs for the fire systems within the structure. The 2704-HV building is a two-story office building containing approximately 90 individual full-office spaces on each floor along with approximately 60 individual cubicle office spaces on each floor. There are various other types of gathering spaces within the 2704-HV layout including: conference rooms, showers, kitchen and dining areas, training rooms, and lobbies.

The 2704-HV building was …

A Study Of Biochar Production Via Continuous Vacuum-Assisted Pyrolysis, Max Wohlgenant

Graduate Theses & Non-Theses

The present study focuses upon the design, fabrication, and feasibility of the bulk production of scientific biochar for mobile delivery. In the 2022 annual report, the National Academies of Science, Engineering, and Medicine recommended the integration of mobile, decentralized reactors that employ flexible manufacturing and circular economic principles. Biochar production, involving the thermal degradation of biomass under an inert atmosphere to yield remediation media is an ideal material to satisfy this recommendation. Many potential application sites, such as abandoned mines, are remote and limit the construction of large infrastructure. The continuous vacuum-assisted pyrolysis (CVAP) reactor was designed to: increase biochar …

Value Added Products From Nonconventional Agricultural Biomass Waste Through Thermochemical Transformation, Nicolas A. Sarmiento

Electronic Thesis and Dissertation Repository

The alteration of temperature patterns around the world has become noticeable in the recent decade. Sea level rise, wildfires, and high temperatures have made people realize that climate change is affecting humans more tangibly than ever. Therefore, the United Nations have pushed to make policies to mitigate this problematic situation. This research investigated the production of biochar from agricultural waste through pyrolysis for fighting climate change and adding value to waste. Experiments in a laboratory scale reactor were conducted to obtain yields of pyrolytic products. Then, analysis of products provided data for characterization and the LCA of the tomato plant …

Investigation Of Fiber Orientation And Mechanical Properties Of Pyrolysis Recycled Carbon-Fiber Reinforced Thermoset Composite, Reva N. Simmons, Harry Lee, Garam Kim

Discovery Undergraduate Interdisciplinary Research Internship

With increasing demand of carbon fiber reinforced fiber thermoset composites, establishing a sustainable cycle for these materials becomes crucial. Pyrolysis is a process of reclaiming carbon fiber from thermoset composites by thermally degrading the polymer at high temperatures allowing the fibers to be extracted. Carbon fiber reclaimed through current pyrolysis processes for thermoset composites typically loses its original shape and orientation, making it difficult to reorganize the fibers. This study investigated the feasibility of maintaining the fiber orientations for continuous fiber reinforced thermoset composite during pyrolysis by stitching the carbon fiber layup to a conformable copper mesh during the manufacturing …

Jcati Carbon Fiber Recycler: Oven Heating System, Kezyah Mantanona

All Undergraduate Projects

Central Washington University Mechanical Engineering Technology students are working with the Joint Center for Aerospace Technology Innovation (JCATI) to create a device that recycles carbon fiber wing trimmings produced by the wing manufacturing process for the Boeing 777 airplanes. The solution to this problem was to utilize crushing, shredding, and pyrolysis to remove the resin from the composite material and provide carbon fiber that can be repurposed. This project focuses on both the Oven Enclosure which will house the Oven Heating System as well as the heating elements and control circuit that are responsible for allowing the material to reach …

Determining Kinetic Parameters Of Cellulose And Lignin Pyrolysis By Gaussian Process Regression (Gpr) Method, Pichayaporn Viriya-Amornkij, Kazunori Kuwana

Progress in Scale Modeling, an International Journal

The ignition and flame-spread processes in the forest and urban fires involve the pyrolysis reactions of biomass materials. One of the most common methods for estimating the fire performance of a material is the evaluation of kinetic parameters, i.e., activation energy (𝐸), pre-exponential factor (𝐴), and reaction model (𝑓(𝛼)), from thermogravimetric analysis (TG) data. Typically, 𝐸 is estimated based on an Arrhenius-type equation such as Kissinger, Kissinger-Akahira-Sunose (KAS), and Friedman equations. Then, its value is adjusted along with other parameters by assuming a reaction model, e.g., the 𝑛-order model. This study proposes a Gaussian process regression (GPR) method to determine …

Biochar Preparation, Investigation Of Properties And Application As A Low-Cost Adsorbent – A Review, A Kh Aripov, S M. Turabdzhanov, Sh Komilova, O Sh Qodirov, G S. Rakhimova, T V. Darabkova, Zh Aimenova, L S. Rakhimova

Technical science and innovation

An overview of current developments in biochar application in water and wastewater treatment is given in this article, along with a brief explanation of the sorption mechanisms for removing contaminants and the techniques for biochar preparation. In order to encourage the continued use of biochar in effective water and wastewater treatment, future research directions and environmental concerns about biochar are also presented.

Ultrafast Laser Direct Writing Of Conductive Patterns On Polyimide Substrate, Ishrat Jahan Biswas, Enrique Contreras Lopez, Farid Ahmed, Jianzhi Li

Manufacturing & Industrial Engineering Faculty Publications and Presentations

Laser direct writing (LDW) is a fast and cost-effective method for printing conductive patterns in flexible polymer substrates. The electrical, chemical, and mechanical properties of polyimide (PI) make it an attractive material choice for laser writing of conductive circuits in such polymer. Electrically insulating PI has shown great potential for flexible printed electronics as LDW enables selective carbonization in the bulk of such material leading to the formation of conductive lines. However, existing studies in this area reveal a few key limitations of this approach including limited conductivity of written structures and fragility of carbonized PI. Therefore, more research is …

Enhancement Of Energy Efficiency For Thermal Energy And Biomass Driven Applications, Osama Mansour Selim Elsayed

Theses and Dissertations

The importance of gas turbine blades is to convert the thermal energy into shaft work output, which makes the turbine blades are one of the critical components of the gas turbines. Besides the mechanical stresses caused by the centrifugal force and the fluid forces, the thermal stresses arise because of the temperature gradient within the blade materials. This paper aims to have a uniform circumferential temperature field at the combustor exit, consequently reducing the thermal stresses caused by the non-uniform temperature distribution along the turbine blade. The validation of the simulation results with the experiments showed an acceptable agreement with …

Cmos Compatible Carbonization Of Polymer For Elctrochemical Sensors, Mohammad Aminul Haque

Doctoral Dissertations

Carbon-based electrodes that are integrable with CMOS readout electrodes possess great potential in a wide range of cutting-edge applications. The primary scientific contribution is the development of a processing sequence which can be implemented on CMOS chips to fabricate pyrolyzed carbon microelectrodes from 3D printed polymer microstructures to develop lab-on-CMOS monolithic electrochemical sensor systems. Specifically, optimized processing conditions to convert 3D printed polymer micro- and nano-structures to carbonized electrodes have been explored in order to obtain sensing electrodes for lab-on- CMOS electrochemical systems. Processing conditions have been identified, including a sequel of oxidative and inert atmosphere anneals to form pyrolyzed …

Co2 Adsorption Using Mg-Mof-74/Activated Biochar Composites Produced From The Pyrolysis Of Lignocellulosic Biomass, Conner Brosdan Pope

Masters Theses

Adsorption is a promising carbon capture and storage (CCS) technology with porous solids like activated biochar (AB), graphene oxides (GO), and metal-organic frameworks (MOF) exhibiting different advantages related to separating carbon dioxide (CO₂) from gas mixtures. Accordingly, the synthesis of MOF/GO composites demonstrates synergism between CO₂ adsorption-driving physicochemical characteristics of MOFs and GOs. However, the synthesis of MOF/AB composites has not been explored in the literature to date even though AB shares many physical and chemical similarities with GO. This research project aimed to synthesize MOF/AB composites with appropriate physicochemical characteristics and CO₂ adsorption capacities for …

Date-Leaf Carbon Particles For Green Enhanced Oil Recovery, Bashirul Haq, Md Abdul Aziz, Dhafer Al Shehri, Nasiru Salahu Muhammed, Shaik Inayath Basha, Abbas Saeed Hakeem, Mohammed Ameen Ahmed Qasem, Mohammed Lardhi, Stefan Iglauer

Research outputs 2022 to 2026

Green enhanced oil recovery (GEOR) is an environmentally friendly enhanced oil recovery (EOR) process involving the injection of green fluids to improve macroscopic and microscopic sweep efficiencies while boosting tertiary oil production. Carbon nanomaterials such as graphene, carbon nanotube (CNT), and carbon dots have gained interest for their superior ability to increase oil recovery. These particles have been successfully tested in EOR, although they are expensive and do not extend to GEOR. In addition, the application of carbon particles in the GEOR method is not well understood yet, requiring thorough documentation. The goals of this work are to develop carbon …

Investigation Of Recyclable And Renewable Crude Oil From Biomass And Plastics, Golam Chowdhury

Dissertations and Theses

In the present world, the nonrenewable source of petroleum crude oil is suspected to cause irreversible climate impacts. So, refinery companies are looking for renewable and recyclable crude oil (RCOs). Biomass and Plastics are a great sources of RCOs. The goal of this work is to design, build and operate a pyrolysis reactor which is capable of converting different solid feedstock derived from waste to pyrolysis oil. The oils are characterized by GC-MS and sent to BASF Corporation in Iselin, NJ for catalytic upgrading potential. In this study, the feedstock ranged from virgin plastic resins (LDPE, HDPE, PS, PP), recycled …

Thermochemical Conversion Of Plastic To Value Added Products, Anastasia L. Maslak

Electronic Thesis and Dissertation Repository

In this study, the use of pyrolytic cracking for managing non-recyclable plastic waste by conversion into value-added liquid and gaseous products was investigated. A single-stage reactor and a novel, two-stage reactor set-up were used for experiments involving polyethylene and polypropylene. Parameters including feedstock composition, feed rate, temperature and residence time were studied. The two-stage approach was investigated to overcome existing transportation limitations involved in the typical plastic waste lifecycle. Bulky plastic collected in towns and cities must be transported to industrial facilities typically located elsewhere for reprocessing. Both HDPE and LDPE showed promising results for olefin recovery with ethylene gas …

Application Of Compositional Data Analysis To Determine The Effects Of Heating Mode, Moisture Status And Plant Species On Pyrolysates, David R. Weise, Thomas H. Fletcher, Mohammad-Saeed Safdari, Elham Amini, Javier Palarea-Albaladejo

Faculty Publications

Pyrolysate gas mixtures are multivariate and relative in nature. Statistical techniques applied to these data generally ignore their relative nature. Published data for permanent gases (CO, CO2, H2, CH4) and tars produced by pyrolysing 15 wildland fuels were reanalysed using compositional data analysis techniques. Mass and mole fractions were compositionally equivalent. Plant species, moisture status and heating mode effects on compositional balances formed from subsets of pyrolysates were tested. Plant species affected the amount of phenol, primary and secondary/tertiary tars relative to permanent gases and relative amounts of single- and multi-ring compounds. Plant moisture status affected the amount of CO …

Pyrolysis Kinetics Of Wildland Vegetation Using Model-Fitting Methods, Ellie Amini, Mohammad-Saeed Safdari, Nathan Johnson Brigham, David R. Weise, Thomas H. Fletcher

Faculty Publications

Slow-heating pyrolysis experiments of 14 plant species native to forests in the southern United States were conducted in a TGA to find the kinetic parameters for slow pyrolysis of all live and air-dried plant samples. Kinetic coefficients were determined from the data using model-fitting methods, resulting in single kinetic parameters for the entire pyrolysis process which can be used by wildland fire modelers. The model forms explored here are a simple one-step model and single and multiple reaction distributed activation energy (DAE) models. The mass loss and derivative mass loss data were fitted simultaneously at heating rates of 10, 20, …

Economic Feasibility Of Mixed Plastic Waste Pyrolysis Using Twin Reactor System In Northwest Arkansas, Carol Rogers, Patricia Means, Renato Gonzalez, Kaida Sheets, Hayden Townsend

Chemical Engineering Undergraduate Honors Theses

Plastic waste generation is increasing at an unsustainable rate while recycling solutions remain stagnant. As a chemical means of recycling, mixed plastic waste pyrolysis can generate synthetic oil appropriate for use as fuel in power generation from plastic waste that otherwise accumulates in landfills. With the scaling of a commercial plastic pyrolysis process in Northwest Arkansas (NWA) modeled after an operational sawdust pyrolysis unit in Huntsville, Arkansas, economic analysis resulted in 26.3% internal rate of return. Therefore, construction of a commercial mixed plastic-to-fuel pyrolysis plant is economically justified and should be pursued. To effectively implement the proposed design, NWA must …

Coal Pyrolysis Models For Use In Massively Parallel Oxyfuel-Fired Boiler Simulations, Andrew Perry Richards

Theses and Dissertations

Accurately modeling key aspects of coal combustion allows for the virtual testing and application of new technologies and processes without the need for investments in lab- and pilot-scale facilities, since such facilities may only be used for a few small tests. However, modeling of subprocesses must not only be accurate but computationally efficient. Modeling of coal devolatilization reactions and processes are one of the important parts of large-scale simulations of coal combustion systems. The work presented here details efforts to improve the modeling of coal devolatilization processes in massively-parallel simulations of coal combustors, including: (1) devolatilization rate/yield models, (2) modeling …

Jcati Pyrolysis System, Jack Dutton

All Undergraduate Projects

The Joint Center for Aerospace Technology Innovation (JCATI) project is designed to recycle carbon fiber pieces for use in manufacturing. Part of the system requires the removal of resin from the carbon fibers to facilitate the recycling of carbon fiber. To accomplish this task the pyrolysis process is implemented using a commercial grade oven with a conveyor system. Argon gas is injected into the shroud and over the oven to purge the interior of oxygen. The conveyor system enables this to be a batch process. A ramp is used to allow simple addition of material to the conveyor system and …

Assessment Of A Decentralized Solution For Waste Plastic Management In Developing Regions, Chandniben Ashishkumar Joshi

Theses and Dissertations--Chemical and Materials Engineering

Rapid population growth, urbanization and availability of pre-packaged consumer goods have led to increased generation and consumption of plastic – so much so that it has become ubiquitous in the environment. An affordable, durable, and lightweight material of construction, plastic is used in innumerable products in every country on earth. However, this explosion of consumption coupled with the material’s significantly low degradability have led to serious plastic accumulation challenges, which are now an imminent threat to terrestrial and marine species globally. These challenges are especially acute in developing countries, where capital and infrastructure constraints, poor governmental regulation and lack of …

Evaluación De Los Residuos De Sacha Inchi Tratados Mediante El Proceso De Pirólisis Como Medio Filtrante Para La Remoción De Cromo En Aguas Potenciadas, Luisa Fernanda Cárdenas Beltrán, Mónica Tatiana Ramón Uyabán

Ingeniería Ambiental y Sanitaria

Actualmente, la mayoría de las fuentes hídricas en Colombia presentan altos niveles de cromo hexavalente, el cual se genera debido a acciones antropogénicas como vertimientos de industriales textiles, curtiembres de cueros y galvanoplastia, entre otras. Muchas de estas industrias vierten sus aguas sin ser tratadas previamente, generando problemáticas tanto ambientales como de salud pública, debido a que el cromo en su estado hexavalente es altamente toxico; además, su alto potencial de bioacumulación en plantas y animales produce toxicidad en el agua, fauna, flora y suelo (Téllez & Carvajal, 2004). En este contexto se han venido buscando soluciones sostenibles que permitan …

Discussion On Parameters Of High Density 3d Seismic Exploration Acquisition In Coal Mining Districts, Cheng Jianyuan, Wang Qianyao, Zhu Shujie

Coal Geology & Exploration

In order to improve the light tar and gas yield, the yield distribution and composition characteristics of pyrolysis products of bituminous coal from Shaanxi Hongliulin in the nitrogen atmosphere and weak oxygen atmosphere were studied in a fixed bed reactor. The results showed that the yield of char and tar were reduced under the weak oxygen atmosphere, and the yield of CO and CO₂ increased significantly, leading to the increase of total gas yield. Due to the oxidation combustion reaction, the yield of H₂, CH₄ and C₂-C₃ gradually decreased with the increase of …

Clearance Of Solid Household Waste With The Reception Of Alternative Types Of Energy Carriers, Rakhmatullayev F, Turabdhanov S

Technical science and innovation

The research is devoted to improving the technology of obtaining alternative types of energy carriers by applying methods of pyrolysis of unclaimed types of solid domestic wastes of biological origin, which also allow solving the tasks of improving the ecological situation in the places of formation. The practical value and relevance of this research lies in the development of advanced technology for obtaining alternative fuels. The proposed pyrolysis unit allows producing gaseous and liquid hydrocarbons in a continuous cycle. In the atmosphere of the gasifying agent (air, oxygen, water vapor, carbon dioxide or their mixture), the gasification process is primarily …

Pyrolysis Characteristics And Pyrolysis Product Composition Of Bituminous Coal Under Weak Oxidizing Atmosphere, Zang Libin, Cui Hufeng, Li Qingchun

Coal Geology & Exploration

In order to improve the light tar and gas yield, the yield distribution and composition characteristics of pyrolysis products of bituminous coal from Shaanxi Hongliulin in the nitrogen atmosphere and weak oxygen atmosphere were studied in a fixed bed reactor. The results showed that the yield of char and tar were reduced under the weak oxygen atmosphere, and the yield of CO and CO₂ increased significantly, leading to the increase of total gas yield. Due to the oxidation combustion reaction, the yield of H₂, CH₄ and C₂-C₃ gradually decreased with the increase of …