Engineering Commons^™

Van Der Waals Epitaxy Of Ultrathin Early Transition Metal (Ti & V) (Di)Selenides: Charge And Magnetic Order In The Ultrathin Limit, Manuel Bonilla Lopez

USF Tampa Graduate Theses and Dissertations

Since the isolation of graphene in 2004, two-dimensional (2D) layered materials, specially the transition metal dichalcogenides (TMDs), have attracted immense interest from theoreticians and experimentalist due to the diversity of properties presented in this family of materials. The main reason for the interest in such materials has been the observation of emergent properties as a consequence of the reduced dimensions, i.e. the monolayer regime. Initially the monolayer regime was obtained via the scotch-tape method. The implementation of exfoliation techniques was successful since layered 2D materials are composed of stacked layers held together by weak van der Walls forces that permits …

Three-Dimensional Rotation Of Paramagnetic And Ferromagnetic Prolate Spheroids In Simple Shear And Uniform Magnetic Field, Christopher A. Sobecki, Yanzhi Zhang, Cheng Wang

Mathematics and Statistics Faculty Research & Creative Works

We examine a time-dependent, three-dimensional rotation of magnetic ellipsoidal particles in a two-dimensional, simple shear flow and a uniform magnetic field. We consider that the particles have paramagnetic and ferromagnetic properties, and we compare their rotational dynamics due to the strengths and directions of the applied uniform magnetic field. We determine the critical magnetic field strength that can pin the particles' rotations. Above the critical field strength, the particles' stable steady angles were determined. In a weak magnetic regime (below the critical field strength), a paramagnetic particle's polar angle will oscillate toward the magnetic field plane while its azimuthal angle …

Reflectivity And Photoemission Electron Microscopy Studies Of Magnetic Heterostructures, Chih-Yeh Huang

Graduate Theses, Dissertations, and Problem Reports

When a thin film thickness becomes ultrathin, the magnetic properties of the thin film can be altered, degraded or even lost. The loss of magnetism has been called the magnetic dead layer (MDL). Considering the trend for miniaturization of information storage and other devices, the MDL is a significant challenge for materials science and engineering. La_1-xSr_xMnO₃ (LSMO) with x=0.3 is an excellent model material that exhibits ferromagnetism at room temperature to study the MDL. This dissertation focuses on understanding the MDL in LSMO films on their own and the effect of this dead layer when …

Magnetic And Electrocatalytic Properties Of Transition Metal Doped Mos2 Nanocrystals, Karthik Chinnathambi

Materials Science and Engineering Faculty Publications and Presentations

In this paper, the magnetic and electrocatalytic properties of hydrothermally grown transition metal doped (10% of Co, Ni, Fe, and Mn) 2H-MoS₂ nanocrystals (NCs) with a particle size 25–30 nm are reported. The pristine 2H-MoS₂ NCs showed a mixture of canted anti-ferromagnetic and ferromagnetic behavior. While Co, Ni, and Fe doped MoS₂ NCs revealed room temperature ferromagnetism, Mn doped MoS₂ NCs showed room temperature paramagnetism, predominantly. The ground state of all the materials is found to be canted-antiferromagnetic phase. To study electrocatalytic performance for hydrogen evolution reaction, polarization curves were measured for undoped and the doped …

Magnetic Studies Of Multiferroic Heterostructures, Ahmed Rayhan Mahbub

MSU Graduate Theses

Multiferroic heterostructures (MHS) consisting of at least two materials with ferroic properties have been a major focus for researchers recently due to its immense potential in device applications. Almost all MHS use ferromagnetic layers making it a very important research area. In this thesis the magnetic properties of different ferromagnetic heterostructures have been investigated. Different bilayers of hard ferromagnet cobalt ferrite (CFO)-soft ferromagnet lanthanum strontium manganese oxide (LSMO) and hard ferromagnet CFO-antiferromagnet nickel oxide (NiO) were fabricated. Pulsed laser deposition technique was used to deposit the thin films on LAO and sapphire substrates. Purpose of using a hard ferromagnetic CFO …

Magnetic And Catalytic Properties Of Transition Metal Doped Mos2 Nanocrystals, Luis Martinez

Open Access Theses & Dissertations

Magnetism and catalytic activity of nanoscale layered two-dimensional (2D) transition metal dichalcogenides (TMDs) have gained an increasing research interest in the recent past. To broaden the current knowledge and understanding on this subject, in this work, together with my collaborators, I study the magnetic and electrocatalytic properties of hydrothermally grown pristine and transition metal doped (10% of Co, Ni, Fe and Mn) 2H-MoS2 nanosheets/nanocrystals (NCs), with the particle size of 25-30 nm. A broad range of experimental measurements such as x-ray diffraction, transmission electron microscopy, x-ray photo absorption spectroscopy, Raman spectroscopy, magnetic, catalytic and electron spin resonance have been employed …

Effects Of The Internal Magnetic Field On The Magneto-Mechanical Properties Of Magnetic Shape Memory Alloys, Anthony Hobza

Boise State University Theses and Dissertations

Shape memory alloys are a class of functional material which recover from large strains without permanent deformation. The strain is accommodated by the displacement of twin boundaries in the martensite phase. The shape memory alloy Ni-Mn-Ga is also ferromagnetic. Ni-Mn-Ga preferentially magnetizes along a certain crystallographic axis. This direction of easy magnetization changes across twin boundaries, such that the directions in neighboring twin domains are nearly perpendicular.

The interaction of magnetic moments and interfaces including the crystal surface and twin boundary interfaces has a large role in the magnetization process of the material. The goal of this study is to …

Exploring Magnetic Nanostructures Embedded Within Single-Crystal Silicon For Generation Of Spin-Polarized Carriers, Machara Krishna Girish Malladi

Legacy Theses & Dissertations (2009 - 2024)

Integrating magnetic functionalities with silicon holds the promise of developing, in the most dominant semiconductor, a paradigm-shift information technology based on the manipulation and control of electron spin and charge. Here, we demonstrate an ion implantation approach enabling the synthesis of a ferromagnetic layer within a defect free Si environment by exploiting an additional implant of hydrogen in a region deep below the metal implanted layer. Upon post-implantation annealing, nanocavities created within the H-implanted region act as trapping sites for gettering the implanted metal species, resulting in the formation of metal nanoparticles in a Si region of excellent crystal quality. …

The Effects Of Strain And Vacancies On The Electric And Vibrational Properties Of Ferroelectric Batio3 From First-Principles, Aldo Serge Michael Raeliarijaona

Graduate Theses and Dissertations

The studies of ferroelectricity (FE) are of technological significance because of the multitude of applicable properties that ferroelectric materials exhibit. The mastery, and control of these properties necessitate the knowledge of the fundamental physics governing these insulating materials.

In this dissertation I present the results of first-principles investigations of the behavior of the fundamental ferroelectric properties under strain, and in the presence of vacancies. In the first part I introduce the important FE properties, their common behavior, and their numerous valuable applications. Following this background on FEs, a review of theoretical methods is presented with topics such as: Density Functional …

Exploration Of Artificial Multiferroic Thin-Film Heterostructures Using Composition Spreads, K.-S. Chang, M. A. Aronova, C.-L. Lin, M. Murakami, M.-H. Yu, Jason R. Hattrick-Simpers, O. O. Famodu, S. Y. Lee, R. Ramesh, M. Wuttig, I. Takeuchi, C. Gao, L. A. Bendersky

Jason R. Hattrick-Simpers

We have fabricated a series of composition spreads consisting of ferroelectric BaTiO₃ and piezomagnetic CoFe₂O₄ layers of varying thicknesses modulated at nanometer level in order to explore artificial magnetoelectricthin-film heterostructures. Scanning microwavemicroscopy and scanning superconducting quantum interference device microscopy were used to map the dielectric and magnetic properties as a function of continuously changing average composition across the spreads, respectively. Compositions in the middle of the spreads were found to exhibit ferromagnetism while displaying a dielectric constant as high as ≈120.

Room-Temperature Spin-Polarized Organic Light-Emitting Diodes With A Single Ferromagnetic Electrode, Baofu Ding, Qunliang Song, Kamal Alameh

Research outputs 2014 to 2021

In this paper, we demonstrate the concept of a room-temperature spin-polarized organic light-emitting diode (Spin-OLED) structure based on (i) the deposition of an ultra-thin p-type organic buffer layer on the surface of the ferromagnetic electrode of the Spin-OLED and (ii) the use of oxygen plasma treatment to modify the surface of that electrode. Experimental results demonstrate that the brightness of the developed Spin-OLED can be increased by 110% and that a magneto-electroluminescence of 12% can be attained for a 150 mT in-plane magnetic field, at room temperature. This is attributed to enhanced hole and room-temperature spin-polarized injection from the ferromagnetic …

Defects Induced Ferromagnetism In Plasma-Enabled Graphene Nanopetals, Zengji Yue, Donghan Seo, Kostya Ostrikov, Xiaolin Wang

Faculty of Engineering and Information Sciences - Papers: Part A

Ferromagnetism in graphene is fascinating, but it is still a big challenge for practical applications due to the weak magnetization. In order to enhance the magnetization, here, we design plasma-enabled graphene nanopetals with ultra-long defective edges of up to 105 m/g, ultra-dense lattice vacancies, and hydrogen chemisorptions. The designed graphene nanopetals display robust ferromagnetism with large saturation magnetization of up to 2 emu/g at 5 K and 1.2 emu/g at room temperatures. This work identifies the plasma-enabled graphene nanopetals as a promising candidate for graphene-based magnetic devices. 2014 AIP Publishing LLC.

Spin-Cycloid Instability As The Origin Of Weak Ferromagnetism In The Disordered Perovskite Bi0.8la0.2fe0.5mn0.5o3, J Bertinshaw, D L. Cortie, Z X. Cheng, M Avdeev, A J. Studer, F Klose, C Ulrich, X L. Wang

Australian Institute for Innovative Materials - Papers

Powder neutron diffraction and magnetometry studies have been conducted to investigate the crystallographic and magnetic structure of Bi0.8La0.2Fe0.5Mn0. 5O3. The compound stabilizes in the Imma orthorhombic crystal symmetry in the measured temperature range of 5 to 380 K, with a transition to antiferromagnetic order at TN≈240 K. The spin cycloid present for BiFeO3 is found to be absent with 50% Mn3+ cation substitution, leading to G-type antiferromagnetic order with an enhanced out-of-plane canted ferromagnetic component, evident from measurable weak-ferromagnetic hysteresis. Structural modifications do not solely explain this behavior, indicating that modified electron exchange interactions must be taken into account. A …

Room Temperature Magnetism In Semiconducting Films Of Zno Doped With Ferric Ions, S. D. Yoon, Y. J. Chen, D. Heiman, A. Yang, N. Sun, C. Vittoria, V. G. Harris

Nian X. Sun

Films consisting of Zn₁₋ₓFeₓO were prepared by alternating-target laser ablation deposition. The Fe doping levels ranged from x=0.016 to 0.125 at. %. X-ray diffraction and energy dispersive x-ray spectroscopy measurements showed only (002n) reflections of the ZnO host and confirmation of the Fe concentration, respectively. For films grown on (001) Al₂O₃ at 300 K, room temperature average saturation magnetization, < 4πMs >, measured from superconducting quantum interference device (SQUID) hysteresis loops for x=0.125 ± 0.025 was 172 G. Although SQUID measurements were sensitive to the average value of the saturation magnetization, ferrimagnetic resonance measurements appeared to be sensitive only to the saturation …

Coexistence Of Ferromagnetism And Cluster Glass State In Superconducting Ferromagnet Rusr2eu1.5ce0.5cu2o10, Rashmi Nigam, Alexey V. Pan, S X. Dou

Shi Xue Dou

Systematic dc and ac magnetic susceptibility measurements performed on RuSr₂Eu_1.5Ce_0.5Cu₂O_10−δ (Ru1222) demonstrate a paramagnetic to ferromagnetic transition around 95 K. The third harmonic of the ac susceptibility reveals that the system undergoes a spin glass transition below 75 K. The features of the zero-field cooled and field cooled dc magnetization curves of Ru1222 material resemble those of a cluster glass state, rather than those of a canonical spin glass state. The magnetization versus applied field loops do not saturate, even at very high applied fields, resulting in the short range …

Possible Room-Temperature Ferromagnetism In Hydrogenated Carbon Nanotubes, Adam L. Friedman, Hyunkyung Chun, Yung Joon Jung, Don Heiman, Evan R. Glaser, Latika Menon

Yung Joon Jung

We find that ferromagnetism can be induced in carbon nanotubes (CNTs) by introducing hydrogen. Multiwalled CNTs grown inside porous alumina templates contain a large density of defects resulting in significant hydrogen uptake when annealed at high temperatures. This hydrogen incorporation produces H-complex and adatom magnetism which generates a sizable ferromagnetic moment and a Curie temperature near TC=1000  K. We studied the conditions for the incorporation of hydrogen, the temperature-dependent magnetic behavior, and the dependence of the ferromagnetism on the size of the nanotubes.

Possible Room-Temperature Ferromagnetism In Hydrogenated Carbon Nanotubes, Adam L. Friedman, Hyunkyung Chun, Yung Joon Jung, Don Heiman, Evan R. Glaser, Latika Menon

Donald Heiman

We find that ferromagnetism can be induced in carbon nanotubes (CNTs) by introducing hydrogen. Multiwalled CNTs grown inside porous alumina templates contain a large density of defects resulting in significant hydrogen uptake when annealed at high temperatures. This hydrogen incorporation produces H-complex and adatom magnetism which generates a sizable ferromagnetic moment and a Curie temperature near TC=1000  K. We studied the conditions for the incorporation of hydrogen, the temperature-dependent magnetic behavior, and the dependence of the ferromagnetism on the size of the nanotubes.

Investigation Of Electrical Transport In Hydrogenated Multiwalled Carbon Nanotubes, Adam L. Friedman, Hyunkyung Chun, Don Heiman, Yung Joon Jung, Latika Menon

Donald Heiman

Highly disordered multiwalled carbon nanotubes of large outer diameter (~60 nm) fabricated by means of chemical vapor deposition process inside porous alumina templates exhibit ferromagnetism when annealed in a H2/Ar atmosphere. In the presence of an applied magnetic field, there is a transition from positive to negative magnetoresistance. The transition may be explained in terms of the Bright model for ordered and disordered carbon structures. Additionally, temperature dependent electrical transport experiments exhibit a zero-bias anomaly at low temperature.

Effects Of Boron Addition To The Atomic Structure And Soft Magnetic Properties Of Fecob Films, Aria Yang, Hassan Imrane, Jing Lou, Johnny Kirkland, Carmine Vittoria, Nian Sun, Vincent G. Harris

Nian X. Sun

The magnetic, microwave, and the atomic structure properties of (Fe₀.₇Co₀.₃)1-xBx sputtered films on glass substrates were investigated. The addition of boron induced a decrease in coercivity and ferromagnetic resonance linewidth. The amorphous structure was formed at x ∽0.075. Extended x-ray absorption fine structure (EXAFS) of Fe and Co showed the reduced Fourier transform (FT) amplitude, and increased Debye-Waller factors as x was increased, indicating the increased disorder due to the thermal and structural displacements. Possible Fe-B bonding was observed with a reduced bond length, which indicates boron atoms' preference for staying in the interstitial sites in bcc unit cell.

Resonance Damping In Ferromagnets And Ferroelectrics, Allan Widom, Somu Sivasubramanian, Carmine Vittoria, S. Yoon, Yogendra N. Srivastava

Carmine Vittoria

The phenomenological equations of motion for the relaxation of ordered phases of magnetized and polarized crystal phases can be developed in close analogy with one another. For the case of magnetized systems, the driving magnetic field intensity toward relaxation was developed by Gilbert. For the case of polarized systems, the driving electric field intensity toward relaxation was developed by Khalatnikov. The transport times for relaxation into thermal equilibrium can be attributed to viscous sound wave damping via magnetostriction for the magnetic case and electrostriction for the polarization case.

Effects Of Boron Addition To The Atomic Structure And Soft Magnetic Properties Of Fecob Films, Aria Yang, Hassan Imrane, Jing Lou, Johnny Kirkland, Carmine Vittoria, Nian Sun, Vincent G. Harris

Vincent G. Harris

The magnetic, microwave, and the atomic structure properties of (Fe₀.₇Co₀.₃)1-xBx sputtered films on glass substrates were investigated. The addition of boron induced a decrease in coercivity and ferromagnetic resonance linewidth. The amorphous structure was formed at x ∽0.075. Extended x-ray absorption fine structure (EXAFS) of Fe and Co showed the reduced Fourier transform (FT) amplitude, and increased Debye-Waller factors as x was increased, indicating the increased disorder due to the thermal and structural displacements. Possible Fe-B bonding was observed with a reduced bond length, which indicates boron atoms' preference for staying in the interstitial sites in bcc unit cell.

Effects Of Boron Addition To The Atomic Structure And Soft Magnetic Properties Of Fecob Films, Aria Yang, Hassan Imrane, Jing Lou, Johnny Kirkland, Carmine Vittoria, Nian Sun, Vincent G. Harris

Carmine Vittoria

The magnetic, microwave, and the atomic structure properties of (Fe₀.₇Co₀.₃)1-xBx sputtered films on glass substrates were investigated. The addition of boron induced a decrease in coercivity and ferromagnetic resonance linewidth. The amorphous structure was formed at x ∽0.075. Extended x-ray absorption fine structure (EXAFS) of Fe and Co showed the reduced Fourier transform (FT) amplitude, and increased Debye-Waller factors as x was increased, indicating the increased disorder due to the thermal and structural displacements. Possible Fe-B bonding was observed with a reduced bond length, which indicates boron atoms' preference for staying in the interstitial sites in bcc unit cell.

Investigation Of Electrical Transport In Hydrogenated Multiwalled Carbon Nanotubes, Adam L. Friedman, Hyunkyung Chun, Don Heiman, Yung Joon Jung, Latika Menon

Yung Joon Jung

Highly disordered multiwalled carbon nanotubes of large outer diameter (~60 nm) fabricated by means of chemical vapor deposition process inside porous alumina templates exhibit ferromagnetism when annealed in a H2/Ar atmosphere. In the presence of an applied magnetic field, there is a transition from positive to negative magnetoresistance. The transition may be explained in terms of the Bright model for ordered and disordered carbon structures. Additionally, temperature dependent electrical transport experiments exhibit a zero-bias anomaly at low temperature.

Investigation Of Electrical Transport In Hydrogenated Multiwalled Carbon Nanotubes, Adam L. Friedman, Hyunkyung Chun, Don Heiman, Yung Joon Jung, Latika Menon

United States Navy: Publications

Highly disordered multiwalled carbon nanotubes of large outer diameter (~60 nm) fabricated by means of chemical vapor deposition process inside porous alumina templates exhibit ferromagnetism when annealed in a H₂/Ar atmosphere. In the presence of an applied magnetic field, there is a transition from positive to negative magnetoresistance. The transition may be explained in terms of the Bright model for ordered and disordered carbon structures. Additionally, temperature dependent electrical transport experiments exhibit a zero-bias anomaly at low temperature.

Superconductivity Induced By Phosphorus Doping And Its Coexistence With Ferromagnetism In Eufe2(As0.7p0.3)2, Zhi Ren, Qian Tao, Shuai Jiang, Chunmu Feng, Cao Wang, Jianhui Dai, Guanghan Cao, Zhu-An Xu

Faculty of Engineering - Papers (Archive)

We have studied EuFe$_{2}$(As$_{0.7}$P$_{0.3}$)$_{2}$ by the measurements of x-ray diffraction, electrical resistivity, thermopower, magnetic susceptibility, magnetoresistance and specific heat. Partial substitution of As with P results in the shrinkage of lattice, which generates chemical pressure to the system. It is found that EuFe$_{2}$(As$_{0.7}$P$_{0.3}$)$_{2}$ undergoes a superconducting transition at 26 K, followed by ferromagnetic ordering of Eu$^{2+}$ moments at 20 K. This finding is the first observation of superconductivity stabilized by internal chemical pressure, and supplies a rare example showing coexistence of superconductivity and ferromagnetism in the ferro-arsenide family.

Coexistence Of Ferromagnetism And Cluster Glass State In Superconducting Ferromagnet Rusr2eu1.5ce0.5cu2o10, Rashmi Nigam, Alexey V. Pan, S X. Dou

Faculty of Engineering - Papers (Archive)

Systematic dc and ac magnetic susceptibility measurements performed on RuSr₂Eu_1.5Ce_0.5Cu₂O_10−δ (Ru1222) demonstrate a paramagnetic to ferromagnetic transition around 95 K. The third harmonic of the ac susceptibility reveals that the system undergoes a spin glass transition below 75 K. The features of the zero-field cooled and field cooled dc magnetization curves of Ru1222 material resemble those of a cluster glass state, rather than those of a canonical spin glass state. The magnetization versus applied field loops do not saturate, even at very high applied fields, resulting in the short range …

Application And Extension Of Glauber Ising-Spin Dynamics In The Context Of A Single Chain Magnet System, Ryan Tucker Kristensen

Legacy Theses & Dissertations (2009 - 2024)

The Glauber Ising-spin dynamic with a local equilibrium approximation is applied to infinite and finite one-dimensional (anti-)ferromagnetic Ising chains with classic nearest neighbor interactions. The application of the Glauber dynamic and local equilibrium approximation is then extended to the one-dimensional ferrimagnetic chain with nearest neighbor interactions. Time dependant behavior and equilibrium states of the one-dimensional ferrimagnetic chain are then discussed in terms of the single chain magnet referred to as CoPhOMe, whose behavior empirical data to date suggest is consistent with a one-dimensional Ising ferrimagnet.

Estimation Of Second Order Phase Transition Temperature Of The Orthorhombic Phase Of Gd5(Sixge1−X)4 Using Arrott Plots, Ravi L. Hadimani, Y. Melikhov, J. E. Snyder, David C. Jiles

David C. Jiles

Gd5(SixGe1−x)4 for 0.41⩽x⩽0.5 is orthorhombic and ferromagnetic at lower temperature, monoclinic and paramagnetic at higher temperature, and shows a first order magnetic-structural phase transition between the two. Magnetic moment versus magnetic field (MH) isotherms were measured just above the first order transitiontemperature for Gd5Si1.95Ge2.05 and Gd5Si2Ge2 samples and the field-induced coupled phase transition from paramagnetic/monoclinic to ferromagnetic/orthorhombic phase was observed. Using the method developed by Arrott [Phys. Rev.108, 1394 (1957)], the ferromagnetic portions of the MH isotherms were used to project the second order magnetic phase transitiontemperature of the orthorhombic phase, a region where the transition does not occur due …

Enhancement Of Ferroelectricity And Ferromagnetism In Rare Earth Element Doped Bifeo3, Zhenxiang Cheng, Xiaolin Wang, S X. Dou, Hideo Kimura, Kiyoshi Ozawa

Australian Institute for Innovative Materials - Papers

Rare earth element doped BiFeO₃ thin films were fabricated using the pulsed laser deposition method and various targets made from different starting Fe₂O₃ and Fe₃O₄ iron source materials. The films fabricated using the targets made from Fe₃O₄ exhibit great enhancement in their ferroelectricity, due to greatly reduced electrical leakage, as well as enhanced magnetization compared to those films deposited using targets from Fe₂O₃. It is suggested that the Fe²⁺ ion plays an important role in compensating for the charge imbalance and reducing current leakage, as …

Including Effects Of Microstructure And Anisotropy In Theoretical Models Describing Hysteresis Of Ferromagnetic Materials, H. Hauser, Y. Melikhov, David C. Jiles

David C. Jiles

Two recent theoreticalhysteresis models (Jiles-Atherton model and energetic model) are examined with respect to their capability to describe the dependence of the magnetization on magnetic field, microstructure, and anisotropy. It is shown that the classical Rayleigh law for the behavior of magnetization at low fields and the Stoner-Wohlfarth theory of domain magnetization rotation in noninteracting magnetic single domain particles can be considered as limiting cases of a more general theoretical treatment of hysteresis in ferromagnetism.