Engineering Commons^™

A Comparative Study On The Stability And Degradation Of Perovskite Solar Cells, Jyotiska Chakraborty

Masters Theses

This study aims to investigate the environmental factors that affect the performance and longterm stability of the perovskite solar cells (PSCs). PSCs are based on organo-metallic halides (perovskites) that act as a light-sensitive compound that produces excitons when placed under the light. However, PSCs have a limited operating lifetime due to the degradation of the perovskite layer. There are many factors like moisture, UV light, and temperature that lead to the degradation of the perovskite layer. From the literature review, it was found that the PSCs do not degrade with the presence of oxygen in a dry and dark environment. …

Characterization Of Nano-Cellulose Based Composites For Biomedical Applications, Mitchell P. Chesley

Electronic Theses and Dissertations

The number of orthopedic surgeries performed globally has steadily increased over the past decade due to the standardization of procedures as well as technological advancements. During this time orthopedic devices have been composed predominantly of metals, such as Titanium, Vanadium, Molybdenum, and Stainless steel, as well as their alloys, due to the high strength and durability of these materials. However, metals may, in fact, be suboptimal for orthopedic devices. For example, metals exhibit Young’s modulus much greater than the surrounding bone, inducing localized stress-shielding promoting cortical atrophy, which can lead to osteoporosis. In recent years polymers have been successfully explored …

Wetting Metamorphosis Of Hydrophobic Fluoropolymer Coatings Submerged In Water And Ultrasonically Vibrated, Matthew Trapuzzano, Nathan B. Crane, Rasim Guldiken, Andrés Tejada-Martínez

Faculty Publications

Many important processes, from manufacture of integrated circuit boards, to an insect’s ability to walk on water, depend on the wetting of liquids on surfaces. Wetting is commonly controlled through material selection, coatings, and/or surface texture. However, wetting is sensitive to environmental conditions. In particular, some hydrophobic fluoropolymer coatings are sensitive to extended water exposure as evidenced by a declining contact angle and increasing contact angle hysteresis. Understanding “degradation” of these coatings is critical to applications that employ them. The durability of a series of fluoropolymer coatings were tested by measuring the contact angle before, during, and after extended submersion …

Effect Of Grain Size And Interface Engineering On The Photovoltaic Performance And Stability Of Perovskite Solar Cells, Abdullah Al Mamun

Electrical & Computer Engineering Theses & Dissertations

Organic-inorganic halide perovskite solar cells (PSCs) have grown rapidly in recent years due to their outstanding optoelectronic properties, high efficiency, and low-cost. However, this emerging solar cell technology is experiencing some challenges such as defects, hysteresis, and long-term stability, which need to be addressed in order to make it commercially available. This dissertation aims to assist in overcoming some of the barriers and is therefore important to the field of perovskite solar cells.

Initially, this dissertation focuses on investigating the role of grain interiors (GIs) and grain boundaries (GBs) of perovskite film using chemically, spatially, and temporally resolved measurements at …

Scaling Film Cooling Adiabatic Effectiveness With Mass Transfer And Thermal Experimental Techniques, Luke J. Mcnamara

Theses and Dissertations

With increasing engine temperatures, it is becoming more important to design effective film cooling schemes. Low temperature, large scale tests are often implemented in the design process to reduce cost and complexity. A nondimensional adiabatic effectiveness can be used as an indication of the performance of a film cooling scheme. However, the coolant flow rate must be properly scaled between the low temperature tests and engine temperatures to accurately predict film cooling effectiveness. This process is complicated by gas property variation with temperature. Tests are commonly conducted using thermal measurement techniques with infrared thermography (IR), but the use of pressure …

Mechanical Properties And Degradation Of High Capacity Battery Electrodes: Fundamental Understanding And Coping Strategies, Yikai Wang

Theses and Dissertations--Chemical and Materials Engineering

Rechargeable lithium ion and lithium (Li) metal batteries with high energy density and stability are in high demand for the development of electric vehicles and smart grids. Intensive efforts have been devoted to developing high capacity battery electrodes. However, the known high capacity electrode materials experience fast capacity fading and have limited cycle life due to electromechanical degradations, such as fracture of Si-based electrodes and dendrite growth in Li metal electrodes. A fundamental understanding of electromechanical degradation mechanisms of high capacity electrodes will provide insights into strategies for improving their electrochemical performance. Thus, this dissertation focuses on mechanical properties, microstructure …

Material Characterizations Of Organic-Inorganic Halide Perovskites Using Various Deposition Techniques For Planar Perovskite Solar Cell, Shaimum Shahriar

Open Access Theses & Dissertations

Organic-inorganic halide perovskites have rapidly become emerging materials for photovoltaic applications. Strong characterization methods are needed to fully comprehend the chemistry and composition of perovskite solar cells. Understanding the interaction between layers inside a cell and how they react with the environment is important to achieve optimum manufacturing processes, and improve the efficiency of perovskite solar cells. The present work demonstrates the material characterizations of organic-inorganic halide perovskites using (i) one-step deposition, (ii) two-steps deposition, (iii) solvent-to-solvent extraction, and (iv) mixed-cation solution processing. Investigations by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and scanning electron microscopy (SEM) have been undertaken …

Persulfate Oxidation-Assisted Membrane Distillation Process For Micropollutant Degradation And Membrane Fouling Control, Muhammad Bilal Asif, Zulqarnain Fida, Arbab Tufail, Jason Van Der Merwe, Frederic Leusch, Biplob K. Pramanik, William E. Price, Faisal I. Hai

Faculty of Engineering and Information Sciences - Papers: Part B

In this study, long-term performance of a persulfate (PS)-assisted direct contact membrane distillation (DCMD) process was examined for the treatment of secondary treated effluent spiked with a mixture of micropollutants including three pesticides and nine pharmaceuticals. A stand-alone DCMD ('control') was also operated under identical operating conditions for comparison. Depending on the micropollutant, the stand-alone DCMD achieved 86 to >99% removal. In comparison, removal by the PS-assisted DCMD was >99% for all investigated micropollutants. This was attributed to the fact that sulfate radicals (SO4-) formed following the activation of PS at the DCMD operating temperature (i.e., 40 °C) achieved micropollutant-specific …

Degradation And Hydrate Phase Equilibria Measurement Methods Of Monoethylene Glycol, Khalid Alef, Stefan Iglauer, Ahmed Barifcani

Research outputs 2014 to 2021

Monoethylene glycol (MEG), a common chemical used for the inhibition of gas hydrate formation may undergo degradation in the regeneration/reclamation process. Limited research exists on the effect of degradation of MEG on hydrate formation, production facilities and equipment especially in the presence of other chemical additives. The proposed method allows for streamlining the process of preparing, degrading and analysis of MEG solutions for hydrate testing and degradation products.

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Procedure to prepare accurate MEG solutions avoiding oxidative degradation of MEG (i.e., controlling oxygen ingress).

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Two methods are suggested to mimic field-like degradation of MEG solutions (i.e., degradation by reclamation …