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Full-Text Articles in Engineering

Water Chemistry Dynamics In Four Vernal Pools In Maine, Usa, Lydia H. Kifner Dec 2017

Water Chemistry Dynamics In Four Vernal Pools In Maine, Usa, Lydia H. Kifner

Electronic Theses and Dissertations

Vernal pools are small seasonal wetlands that are a common landscape feature that contribute to biodiversity in northeastern North American forests. However, even basic information about their biogeochemical functions, such as carbon cycling, is limited. Dissolved gas concentrations (CH4, CO2) and other water chemistry parameters were monitored weekly at the bottom and surface of four vernal pools in central and eastern Maine, USA, from April to August 2016. The vernal pools were supersaturated with respect to CH4 and CO2 at all sampling dates and locations. Concentrations of dissolved CH4 and CO2 ranged …


Electrocarboxylation: An Effective Process For Fixation Of Co2 Into Organic Carboxylic Acids, Huan Wang, Jia-Xing Lu Jun 2017

Electrocarboxylation: An Effective Process For Fixation Of Co2 Into Organic Carboxylic Acids, Huan Wang, Jia-Xing Lu

Journal of Electrochemistry

Conversion and utilization of greenhouse gas carbon dioxide (CO2) have become more and more significant to the sustainable development of the global economy. Among them, electrocarboxylation of organic substrates is an effective process. Under mild conditions such as ambient temperature and pressure, carbocations generated by electroreduction of organic substrates can react with CO2 into corresponding carboxylic acids. This paper introduces the recent progress of our group in electrochemical carboxylation, including electrocarboxylation of varies active organic substrates and asymmetric electrocarboxylation.


The Problem Of The Anode Electrolyte In H-Type Electrolytic Cell For Electrochemical Reduction Of Carbon Dioxide, Rui Zhang, Wei-Xin Lv, Li-Xu Lei Feb 2017

The Problem Of The Anode Electrolyte In H-Type Electrolytic Cell For Electrochemical Reduction Of Carbon Dioxide, Rui Zhang, Wei-Xin Lv, Li-Xu Lei

Journal of Electrochemistry

Electrochemical reduction of carbon dioxide (CO2) was studied in the H-type electrolytic cell. It was found that the voltage between the cathode and the anode would increase during the long time electrolysis process, for this reason the electrolytic process would be unsustainable. After the experimental investigations carried out by constant potential electrolysis, constant current electrolysis, pH test and KHCO3 concentration analysis of anode electrolyte before and after the electrolysis, the increase in cell voltage might be caused by the following process: H+, that was generated from the anodic oxygen evolution reaction, reacted with HCO3 …


Ammonia And Carbon Dioxide Emissions Of Three Laying-Hen Housing Systems As Affected By Manure Accumulation Time, Timothy A. Shepherd, Hongwei Xin, John P. Stinn, Morgan D. Hayes, Yang Zhao, Hong Li Jan 2017

Ammonia And Carbon Dioxide Emissions Of Three Laying-Hen Housing Systems As Affected By Manure Accumulation Time, Timothy A. Shepherd, Hongwei Xin, John P. Stinn, Morgan D. Hayes, Yang Zhao, Hong Li

Biosystems and Agricultural Engineering Faculty Publications

Laying-hen housing design and management are the most significant factors affecting the generation and release of gaseous ammonia to the atmosphere. Transitioning the hen housing type from traditional high-rise (where manure is stored within the house for about one year) to modern manure-belt style (where manure is removed every 1 to 4 d and placed into long-term storage) has significantly improved in-barn air quality and reduced farm-level ammonia emissions. As a direct result of the advantages, 100% of new construction for U.S. egg production incorporates manure-belt systems that regularly remove manure from the houses. However, manure-belt system designs (e.g., active …