Engineering Commons^™

Bridge Maintenance To Enhance Corrosion Resistance And Performance Of Steel Girder Bridges, Luis M. Moran Yanez

Open Access Dissertations

The integrity and efficiency of any national highway system relies on the condition of the various components. Bridges are fundamental elements of a highway system, representing an important investment and a strategic link that facilitates the transport of persons and goods. The cost to rehabilitate or replace a highway bridge represents an important expenditure to the owner, who needs to evaluate the correct time to assume that cost. Among the several factors that affect the condition of steel highway bridges, corrosion is identified as the main problem. In the USA corrosion is the primary cause of structurally deficient steel bridges. …

Corrosion Of Aluminum Current Collector In Cost Effective Rechargeable Lithium-Ion Batteries, Shengyi Li

Theses and Dissertations

Rechargeable lithium ion batteries (LIB) have been widely used as commercial energy storage systems for portable equipment, electronic devices and high power applications (e.g. electronic vehicles). One issue with the commercialized LIB is that expensive, highly toxic and flammable organic solvents are used in the electrolyte and the fabrication process of electrodes. The toxic organic based solvents increase the production cost and lead to significant safety concerns in the event of a battery overcharge or short circuit. The recent development of “green manufacturing” technology allows manufacturers to replace the organic solvents used in the cathode coating process by aqueous based …

Microstructure, Wetting Angle And Corrosion Of Aluminum-Silicon Alloys, Shvetashva Suri

Theses and Dissertations

In this study the effect of composition, surface roughness and water droplet size on contact angle and corrosion properties of cast Aluminum-Silicon alloys containing Si from 5% to 50% have been examined. The water contact angle was measured on a given sample using a goniometer. In addition, the effect of surface roughness and droplet size on contact angle has been measured for alloys at a fixed composition. The microstructures can be found in this report with sizes of primary and eutectic Silicon as well as inter-particle spacing between Silicon. Contact angle measurements are accompanied with a photographic validation of the …

The Economy Of Preventive Maintenance Of Concrete Bridges Due To Corrosion, Haotian Zhang

Dissertations - ALL

The current practice for physical evaluation and delayed maintenance of deteriorated concrete bridge is fundamentally wrong. This research presents a new approach for the evaluation of the condition states of steel reinforced concrete bridge members, which is based on their chemical conditions instead of the physical deficiencies such as cracks and delamination. Using the proposed chemical based inspection approach, a more effective and economic preventive maintenance plan could be achieved. The available non-destructive evaluation (NDE) methods and preventive maintenance measure are identified. Since the chloride induced corrosion is the major factor that dictates the service life of the steel reinforced …

Thin Film Concrete Coatings, Bobby W. Meade, Danny Wells, Theodore Hopwood Ii, Sudhir Palle

Kentucky Transportation Center Research Report

KTC researchers obtained eight types of concrete coatings to assess their performance and resistance to chloride penetration. Researchers evaluated eight of the systems in the field and seven in the laboratory. In the field, coatings were applied to a bridge pier that had suffered degradation and chloride contamination. This site will undergo long term monitoring in order to thoroughly evaluate the coating systems. Adhesion of all products in both field and laboratory application was sufficient to provide a durable coating, and ranged from approximately 500 psi to 1,600 psi. Researchers also tested color and gloss changes, which are early indicators …

Chloride Contamination Remediation On Steel Bridges, Bobby W. Meade, Christopher Goff, Sudhir Palle, Theodore Hopwood Ii

Kentucky Transportation Center Research Report

Researchers evaluated 32 steel surface preparation methods to determine how effectively they remove chloride from corroded chloride-contaminated steel panels. Wet methods proved more effective than dry methods. The three most effective wet methods injected mineral slag abrasives in a water stream and resulted in less than 1% chlorides remaining. Most dry surface preparation methods left significantly more chloride contamination after surface preparation. The three most effective dry methods used multiple blast cleaning cycles. These methods approached the effectiveness of the best wet methods, with 1.6 to 2.0% chlorides remaining. The least effective surface preparation was a single abrasive blast cleaning …

The Long-Term Performance Of Concrete Crack And Deck Surface Sealers, Emily A. Byl

Open Access Theses

Concrete bridge decks in the State of Indiana are undergoing continuous deterioration and loss of service life due to the use of deicing salts during winter weather conditions. As salt water penetrates the deck through cracks and the concrete surface, chlorides, water and oxygen are able to access the reinforcement to initiate corrosion. The corrosion of reinforcing steel over time creates an ongoing need for costly deck repairs and/or deck replacement. This study investigates the performance of crack sealers and deck surface sealers as a potentially cost-effective method of increasing bridge deck service life. An experimental program was developed and …

Effect Of Severe Corrosion On Lateral Strength Of Square Rc Bridge Columns, Sara Sotoud

Dissertations - ALL

Corrosion of reinforcing steel bars is the primary durability problem that causes degradation of reinforced concrete structures located in aggressive environments. Severe corrosion of steel bars decreases the lateral load-carrying capacity of reinforced concrete members, causes loss in the mechanical properties of reinforcement and cross-sectional area of steel bars and concrete cover, bond deterioration, reduces anchorage of steel bars, and decreases the confinement by transverse reinforcement. Consequently, corrosion results in drop in the lateral strength of columns. Therefore, studying response of corroded reinforced concrete columns subjected to lateral loads is necessary.

According to the Federal Highway Administration (FHWA) report in …

Controlling The Corrosion And Cathodic Activation Of Magnesium Via Microalloying Additions Of Ge, R. L. Liu, M. F. Hurley, A. Kvryan, G. Williams, J. R. Scully, N. Birbilis

Materials Science and Engineering Faculty Publications and Presentations

The evolution of corrosion morphology and kinetics for magnesium (Mg) have been demonstrated to be influenced by cathodic activation, which implies that the rate of the cathodic partial reaction is enhanced as a result of anodic dissolution. This phenomenon was recently demonstrated to be moderated by the use of arsenic (As) alloying as a poison for the cathodic reaction, leading to significantly improved corrosion resistance. The pursuit of alternatives to toxic As is important as a means to imparting a technologically safe and effective corrosion control method for Mg (and its alloys). In this work, Mg was microalloyed with germanium …

Probability Model Of Corrosion-Induced Cracking Time In Chloride-Contaminated Reinforced Concrete, Chunhua Lu, Jinmu Yang, Ronggui Liu

International Conference on Durability of Concrete Structures

Corrosion-induced concrete cover cracking caused by chloride ion is an important indication of durability limit state for marine reinforced concrete (RC) structures and can ultimately determine the structural service life. In this paper, considering the random nature of factors affecting the corrosion cracking process, a probabilistic model which expands on the deterministic model of cover cracking time is developed by using Monte Carlo simulation technique. The results showed that the time to corrosion cracking can be modelled by the Weibull distribution. Finally, the probabilistic analysis for the cracking time is applied to an in-site RC bridge girder with four different …

An Experimental Study On Effect Of Steel Corrosion On The Bond–Slip Performance Of Reinforced Concrete, Xiaolin Zhang, Xuebing Liang, Hancheng Huang, Haijun Zhou

International Conference on Durability of Concrete Structures

This paper studied the effects of reinforcement corrosion on bond performance between rebar and concrete. Tests were carried out to evaluate the degradation of bond between reinforcing steel and concrete for different corrosion levels of reinforcing steel. A series of 20 specimens of different concrete strength with various reinforcing steel corrosion levels were designed and manufactured. Each specimen was casted as a 200-mm concrete cube, and a steel rebar was centrally embedded with two stirrups around it. The steel rebar were corroded using an electrochemical accelerated corrosion technique. The corrosion crack opening width and length were recorded after the corrosion …

Progress In Durability Study Of Frp Materials, Zeng-Zhu Zhu, Ying-Wu Zhou, Li-Li Sui, Feng Xing, Jia Du

International Conference on Durability of Concrete Structures

During the past decades, FRP strengthened RC structures have attracted worldwide interest in both application and research. Nowadays, as more and more infrastructures are being suffered from severe corrosions due to harsh and extreme environments, the durability of FRP strengthened RC structures has generally emerged as the most important issue in research. Thus, the paper presents the latest progress in durability study of the FRP materials through an in-depth review and analysis on existing extensive investigations. The time-dependent performances of two types of FRP materials of carbon FRP (CFRP) and glass FRP (GFRP) under severe environments of humidity, high temperature, …

Effect Of Pet Wrapping On Shear Performance Of Corroded Reinforced Concrete Columns, Dawei Zhang, Yuxi Zhao, Weiliang Jin, Tamon Ueda

International Conference on Durability of Concrete Structures

In this paper, an experimental study is presented on the influence of PET warping on shear performance, such as diagonal shear cracking load, peak load, and energy dissipation of RC columns with stirrup corrosion before strengthening. The experimental program involved an electrochemical process to accelerate the migration of chlorides from an external electrolyte into the tested columns, a wetting–drying cycle process with a controlled current to speed up the corrosion of the stirrup in the tested columns, the strengthening of corroded columns with PET warping, and a pseudostatic test to determine the shear capacity of the tested beams. The shear …

Corrosion Of Steel In Concrete And Its Prevention In Aggressive Chloride-Bearing Environments, Luca Bertolini, Maddalena Carsana, Matteo Gastaldi, Federica Lollini, Elena Redaelli

International Conference on Durability of Concrete Structures

This keynote paper deals with the durability of reinforced concrete (RC) structures exposed to aggressive environments characterized by high concentration of chloride ions, namely, marine environments or the use of de-icing salts. The mechanism of chloride-induced corrosion of steel in concrete is introduced, and its influence on the service life of RC structures is analyzed. Factors affecting the time to corrosion initiation are described with regard to both concrete properties and environmental exposure conditions. Design approaches available for achieving durability targets associated with the design service life are analyzed, focusing on studies carried out by the authors in recent years …

Eigenstress Model For Electrochemistry Of Solid Surfaces, Hongxin Ma, Xilin Xiong, Panpan Gao, Xi Li, Yu Yan, Alex A. Volinsky, Yanjing Su

Mechanical Engineering Faculty Publications

Thermodynamic analysis and molecular dynamics simulations were conducted to systematically study the size-dependent electrochemical response of solids. By combining the generalized Young-Laplace equation with the popular Butler-Volmer formulation, the direct influence of surface stress on solid film electrochemical reactions was isolated. A series of thermodynamic formulas were developed to describe the size-dependent electrochemical properties of the solid surface. These formulas include intrinsic surface elastic parameters, such as surface eigenstress and surface elastic modulus. Metallic films of Au, Pt, Ni, Cu and Fe were studied as examples. The anodic current density of the metal film increased, while the equilibrium potential decreased …

Material Weakening Due To Corrosion In Hardened Bearing Steels, R.H. Vegter, M. Ersson, Bo Han

International Workshop on the Environmental Damage in Structural Materials Under Static Load/Cyclic Loads at Ambient Temperatures

In rolling and ball bearings, materials are designed to withstand extremely high loads for long operation times. Most bearing steels are hardened steels with high carbon content that typically can function up to the Very High Cycle Fatigue regime (>1010 load cycles). The loads under which this occurs are given by the fatigue limit, which is a parameter that does depend on the strength of the material, but is commonly seen as a fixed parameter Therefore, material weakening is playing an important role when components fail as a result of rolling contact fatigue loading. In this paper, the effects …

Evaluation Of The Use Of Painted And Unpainted Weathering Steel On Bridges, Theodore Hopwood Ii, Sudhir Palle, Bobby W. Meade, Rick Younce

Kentucky Transportation Center Research Report

KTC researchers studied the use of unpainted weathering steel on bridges, using findings of inspections performed on Kentucky Transportation Cabinet (KYTC) bridges constructed with both painted and unpainted weathering steel as well as laboratory testing. Laboratory tests were conducted on test panels of conventional and weathering grades of steel to determine the performance of barrier and zinc-based coatings over abrasive-blasted substrates of those steel types in both the new and corroded conditions. The report provides the following recommendations for the use of painted and unpainted weathering steel on Kentucky bridges based upon both the field and laboratory findings:

• KYTC should …

Interactions Between Inflammatory Cells And Cocrmo Alloy Surfaces Under Simulated Inflammatory Conditions, Huiyu Shi

Dissertations - ALL

Metallic biomaterials continue to be the primary materials for medical devices because of their excellent physical and mechanical properties especially for certain implants which need high strength (hip, spinal, shoulder, knee etc.). However there is no perfect material to meet all the requirements of a medical device. Metallic biomaterials are prone to corrosion and wear which has been associated with implant failure (osteolysis, aseptic loosening, pseudo tumor etc.) This study focused on investigating how inflammatory cells interact with CoCrMo alloy surfaces under simulated inflammatory conditions (H2O2 treatment). It is hypothesized that the presence of Reactive Oxygen Species (ROS) in cell …

Novel Methods And Self-Reinforced Composite Materials For Assessment And Prevention Of Fretting Corrosion In Modular Tapers, Eric S. Ouellette

Dissertations - ALL

Novel methods for assessing the electrochemical and micromechanical performance of modular tapers were evaluated, and self-reinforced composite materials were developed for their potential to prevent the onset of mechanically assisted corrosion in modular taper devices.

A study of the seating and taper locking mechanics of modular taper samples was conducted, and the effect on taper engagement strength of seating load, loading rate, taper moisture, and taper design/material combination was studied. The load-displacement behavior was captured during seating, and the subsequent pull off load was correlated to seating displacement, seating energy, and seating load. The primary factor affecting taper engagement strength …

Influence Of Permeate From Domestic Reverse Osmosis Filters On Lead Corrosion And Leaching From Plastic Pipes, Jyotsna Shrestha

Theses and Dissertations

Reverse Osmosis filters are gaining popularity nowadays, in domestic water supply system, to meet the increasing demand of pure and improved drinking water. There are various types of domestic RO filters with varying sizes, capacities, and treatment stages available. However, there exist a few concerns regarding the RO treatment system. One of the major issues in the quality and distribution of drinking water is the corrosive water that the RO system produces. Therefore, this research herein tends to focus on the corrosive effect of the permeate water on lead metal, as lead is considered a serious problematic drinking water contaminant. …

Magnetron Sputtering And Corrosion Of Ti-Al-C And Cr-Al-C Coatings For Zr-Alloy Nuclear Fuel Cladding, Devin Alan Roberts

Masters Theses

The disaster at the Fukushima Daiichi Nuclear Power Plant in March 2011 bought renewed focus to the issue of corrosion in nuclear fuel cladding applications. This thesis reports on the background behind these issues, the investigation strategy, and the analysis of experiments focused on mitigating oxidation of Zr-alloy fuel cladding. This thesis seeks to develop magnetron sputtered Ti-Al-C and Cr-Al-C coatings for Zr-alloy substrates and characterize the as-deposited and corroded samples.

Ti-Al-C and Cr-Al-C coatings were deposited onto ZIRLO, Si, and Al₂O₃ [Aluminum Oxide] substrates under various sputtering conditions. A combinatorial sputtering method was employed to refine …

Performance Assessment Of Deteriorated And Retrofitted Steel Hp Piles, Steven T. Stauffer

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Deterioration of aging bridges can be attributed to an assortment of mechanisms throughout the structure, with remediation policies also varying. This study focused on assessing the validity of the Nebraska Department of Roads’ (NDOR) reinforced concrete encasement retrofit for corroded steel HP piles. Experiments were designed and conducted to test the capacity of the NDOR retrofit and evaluate failure limit states. Two pile locations were considered: abutment and pile bent. For each location there was a non-deteriorated, deteriorated, and retrofitted case. These cases represented the pile at key stages during its life. NDOR’s concrete encasement retrofit provided the required stability …

Corrosion Of Rebar Under Carbonation And Salt Environment, Wei-Chung Yeih, Jiang-Jhy Chang, Yu-Ping Huang, Ran Huang

Journal of Marine Science and Technology

In this study, the behavior of reinforced concrete under carbonation and in a salt environment was investigated. Three types of cements- Type I cement, Type II cement and highalumina cement (HAC) - were used to study the influence of cement on reinforced concrete behavior. To simulate chloridecontaminated concrete, 1% NaCl (by cement weight) was added to some groups of specimens. Results revealed that the carbonation released chloride ions from Friedel's salt, which increased the chloride content near the carbonation front. The carbonation rate of HAC concrete was higher than that of Type I and Type II cement concrete. The corrosion …

Microgalvanic Corrosion Behavior Of Cu-Ag Active Braze Alloys Investigated With Skpfm, Armen Kvryan, Kari Livingston, Corey M. Efaw, Kyle Knori, Brian J. Jaques, Paul H. Davis, Darryl P. Butt, Michael F. Hurley

Materials Science and Engineering Faculty Publications and Presentations

The nature of microgalvanic couple driven corrosion of brazed joints was investigated. 316L stainless steel samples were joined using Cu-Ag-Ti and Cu-Ag-In-Ti braze alloys. Phase and elemental composition across each braze and parent metal interface was characterized and scanning Kelvin probe force microscopy (SKPFM) was used to map the Volta potential differences. Co-localization of SKPFM with Energy Dispersive Spectroscopy (EDS) measurements enabled spatially resolved correlation of potential differences with composition and subsequent galvanic corrosion behavior. Following exposure to the aggressive solution, corrosion damage morphology was characterized to determine the mode of attack and likely initiation areas. When exposed to 0.6 …

On The Role Of The Pore Water Chemistry Of Deficient Post-Tension Grout To Promote Steel Corrosion, Samanbar Permeh

FIU Electronic Theses and Dissertations

Corrosion failure of post-tension tendons with pre-packaged thixotropic grout was documented in Florida Bridges in less than 10 years of service. Analysis of deficient grout in Florida post-tensioned (PT) bridges where severe corrosion developed indicated enhanced sulfate ion concentration, high pore water pH, enhanced moisture and low chloride content. The corrosion wasn’t consistent with the conventional causes of steel corrosion such as bleed water accumulation in grout void spaces, chloride contamination and pore water carbonation. Corrosion development was associated with deficient grout with enhanced sulfate levels. However, limited information is available on the corrosion behavior of PT strand in grout …

Microstructural Investigation Of Vintage Pipeline Steels Highly Susceptible To Stress Corrosion Cracking, Monica Adriana Torres

Open Access Theses & Dissertations

The use of pipelines for the transmission of gas offers not only efficiency, but a number of economic advantages. Nevertheless, pipelines are subject to aggressive operating conditions and environments which can lead to in-service degradation [1] and thus to failures. These failures can have catastrophic consequences, such as environmental damage and loss of life [2]. One of the most dangerous threats to pipeline integrity is stress corrosion cracking (SCC). Despite the substantial progress that has been achieved in the field, due to the complex nature of this phenomenon there is still not a complete understanding of this form of external …

Correlation Between Zn-Rich Phase And Corrosion/Oxidation Behavior Of Sn-8zn-3bi Alloy, Xin Zhang, Chong Li, Zhiming Gao, Yongchang Liu, Zongqing Ma, Liming Yu, Hui Jun Li

Faculty of Engineering and Information Sciences - Papers: Part A

The microstructure of Sn-8Zn-3Bi alloy was refined by increasing the solidification rate and the correlation between Zn-rich phase and the corrosion/oxidation behavior of the alloy was investigated. The Zn-rich phase transforms from coarse flakes to fine needles dispersed in the β-Sn matrix with the increase of the cooling rate. The transformation of Zn-rich precipitates enhances the anticorrosive ability of Sn-8Zn-3Bi alloy in 3.5 wt.% NaCl solution. On the contrary, Sn-8Zn-3Bi alloy with a fine needle-like Zn-rich phase shows poor oxidation resistance under air atmosphere, due to the fast diffusion of Zn atoms in Sn matrix.

Probability-Based Hurricane Resilience Evaluation And Retrofitting For Residential Community, Yadong Dong

Dissertations, Master's Theses and Master's Reports

Wood residential construction is vulnerable to hurricanes, as evident in recent hurricane events. Many studies indicated that the changing climate may very likely alter hurricane patterns, which could lead to more severe hurricane damage to the wood residential construction that accounts for 90% of the residence in the USA. On the other hand, deterioration of material increases the chance of structural failure by reducing the structural capacity (e.g., corrosion of fasteners in roof panel could significantly reduce the withdrawal capacity of the roofing structure during hurricane events).

Currently, most hurricane damage estimations only focus on direct loss (e.g., structural loss). …

A Practical Anodic And Cathodic Curve Intersection Model To Understand Multiple Corrosion Potentials Of Fe-Based Glassy Alloys In Oh-Contained Solutions, Yingjie Li, Yonggang Wang, Bang An, Hui Xu, Yihua Liu, Laichang Zhang, Houyi Ma, Weimin Wang

Research outputs 2014 to 2021

A practical anodic and cathodic curve intersection model, which consisted of an apparent anodic curve and an imaginary cathodic line, was proposed to explain multiple corrosion potentials occurred in potentiodynamic polarization curves of Fe-based glassy alloys in alkaline solution. The apparent anodic curve was selected from the measured anodic curves. The imaginary cathodic line was obtained by linearly fitting the differences of anodic curves and can be moved evenly or rotated to predict the number and value of corrosion potentials. © 2016 Li et al. This is an open access article distributed under the terms of the Creative Commons Attribution …

Distinction In Corrosion Resistance Of Selective Laser Melted Ti-6al-4v Alloy On Different Planes, Nianwei Dai, Laichang Zhang, Junxi Zhang, Xin Zhang, Qingzhao Ni, Yang Chen

Research outputs 2014 to 2021

Electrochemical measurements and microstructural analysis were performed to study the corrosion resistance of different planes of Ti-6Al-4V alloy manufactured by selective laser melting (SLM). The electrochemical results suggest that its XY-plane possesses a better corrosion resistance compared to XZ-plane in 1 M HCl solution, in spite of slight difference in 3.5 wt.% NaCl solution, suggesting that the different planes exhibit more pronounced distinction in corrosion resistance in harsher solution system. The inferior corrosion resistance of XZ-plane is attributed to the presence of more α′ martensite and less β-Ti phase in microstructure for XZ-plane than for XY-plane of the SLM-produced Ti-6Al-4V …