Engineering Commons^™

Delamination Detection In Concrete Using Disposable Impactors For Excitation, Anjali Narendra Patil

Theses and Dissertations

Delaminations in concrete bridge decks result primarily from corrosion of the reinforcing bars (or rebar). This corrosion leads to volumetric expansion of the rebar. When the rebar expands, concrete cracks, and there is a localized separation of the concrete cover from the underlying concrete. Impact-echo testing is an effective technique to map delaminations on concrete bridge decks. However, mapping speed is limited by necessary retrieval of the impactor for traditional tests. To achieve higher scanning speeds, it is advantageous to use both a non-contact measurement (air-coupled impact-echo) and disposable-impactor excitation. Disposable impactors have the potential advantage of achieving greater deck …

Basic Principles And Applications Of Secm In Metal Corrosion, Fa-He Cao, Yan Xia, Wen-Juan Liu, Lin-Rong Chang, Jian-Qing Zhang

Journal of Electrochemistry

Scanning electrochemical microscopy (SECM) is chemical microscopy with higher spatial resolution. After 24 years of development, SECM has been widely applied in mapping and kinetics study of heterogeneous electron transfer in localized processes at solid-liquid or liquid-liquid interfaces. The fundamentals and recent advances of SECM in corrosion applications are described, including SECM mapping and kinetics on localized corrosion of metal or coating. Research work of SECM in corrosion by our group is also introduced. Future applications of SECM in corrosion are highlighted.

Applications Of Spectroscopic Ellipsometry In Corrosion Investigation, Ling-Jie Li, Yu-Ling He, Jing-Lei Lei, Sheng Tao Zhang

Journal of Electrochemistry

As a highly-sensitive and non-destructive in situ technique, spectroscopic ellipsometry has been widely applied in corrosion investigation to acquire the dynamic information of the “electrode-medium” interface during corrosion. This paper lays out some representative demonstrations in several established optical models used to interpret data obtained with spectroscopic ellipsometry in corrosion investigation. In addition, the latest trends in development of this technique are analyzed.

Iron-Magnesium Alloy Bioabsorbable Blood Stent, Kaitlyn Jarry, L Stanciu

The Summer Undergraduate Research Fellowship (SURF) Symposium

Bioabsorbable materials are fairly new and proper alloys for implantation in the body have not yet been established. There are a few polymers that have showed promise, but they do not provide the proper mechanical support that metal does. These materials would be used to create devices such as blood stents and orthopedic screws. Investigation into the properties of different alloys can help to establish a material that can be used for implanted devices that are only needed for a limited amount of time. In order to investigate these alloys many different experiments will to be run to test the …

A Real Case Study On The State Of Corrosion Of The Spanish Boats, José A Orosa, Juan José Galán, Mar Toledano

Journal of Marine Science and Technology

In this real case study we analyze various corrosion problems encountered in Spanish fleets and present possible solutions. As a first step, we developed a statistical analysis of the north Mediterranean Sea fleets to define the age of the vessels, hull construction material and main activities involved. As a result, different corrosion problems were identified as well as solutions like paint, sacrificial anodes and impressed currents, and of course, improved design. Generally, we can state that, according to the results obtained, a series of incidents have increased the repair and maintenance costs of the vessels in the area under study

Corrosion Of Magnesium And Aluminum In Palm Biodiesel: A Comparative Evaluation

A.S. Md Abdul Haseeb

The present study aims to investigate the comparative corrosion of light-weight metals such as aluminum and magnesium in palm biodiesel. Immersion test at room temperature was carried out for each metal for 1440 h. Sample characterization techniques employed include weight loss measurement, SEM (scanning electron microscope), XRD (X-ray diffraction), TAN (total acid number) and FTIR (Fourier transform infrared spectroscopy). Results showed that the corrosion rate of magnesium was much higher compared to that of aluminum. The surface morphology revealed a significant difference between the biodiesel exposed aluminum and magnesium specimens. Upon exposure to biodiesel, the magnesium surface was found to …

Density Functional Theory (Dft) Study On The Hydrolysis Behavior Of Degradable Mg/Mg Alloys For Biomedical Applications, Marjan Nezafati

Theses and Dissertations

Magnesium-based (Mg and/or Mg alloys) materials possess many advantageous physicochemical/biological characteristics such as good biocompatibility and similarity of the mechanical properties to the human bone tissue, which renders this material a promising candidate for the biomedical and implant applications. One of the most attractive features of Mg-based materials is the degradability in the physiological environment. With the burst of research on the biodegradable materials for the healthcare device applications, Mg and its alloys attracted a strong attention in the bioengineering field in recent years. However, the major limitation of applying Mg-based materials to biomedical applications is the fast degradation/corrosion rate …

Corrosion Activity In Precast Concrete Elements And Cementitious Closure Pours, Shabi Abbas Udaipurwala

All Theses

The use of prefabricated elements in the construction of highway bridges has been a common practice in the United States since 1950s. Precast concrete adjacent box beam girder bridges are quite popular given that the precast elements not only have structural capacity to span across the supports, but also form the bridge deck. These bridges have generally performed well during the initial years after construction, but recent failures in Pennsylvania and Indiana have aroused a nationwide alarm to investigate the causes of failure and find solutions to repair these bridges or develop design for new replacement bridges. It was found …

Multifunctional Corrosion Inhibition Behavior Of Zn-Al Calcined Layered Double Hydroxides For Steel Rebar In Nacl Solution, Xiao-Juan Zhang, Jing-Jing Wang, Shi-Gang Dong, Chang-Jian Lin

Journal of Electrochemistry

The Zn-Al layered double hydroxides (Zn-Al LDHs) and calcined products (Zn-Al CLDHs) were synthesized successfully under a routine air atmosphere. The results showed that both Zn-Al LDHs and Zn-Al CLDHs had obvious flake structures. The corrosion inhibition of Zn-Al CLDHs for steel rebar in NaCl solution was studied by electrochemical techniques. It was found that the corrosion rate of steel rebar decreased significantly after the steel rebar was treated by Zn-Al CLDHs in NaCl solution for 3 h. It was indicated that Zn-Al CLDHs could absorb Cl^- and release OH^- during their reconstruction process, which provided dual protection …

An Assessment Of Novel Biodegradable Magnesium Alloys For Endovascular Biomaterial Applications, Dharam Persaud-Sharma

FIU Electronic Theses and Dissertations

Magnesium alloys have been widely explored as potential biomaterials, but several limitations to using these materials have prevented their widespread use, such as uncontrollable degradation kinetics which alter their mechanical properties. In an attempt to further the applicability of magnesium and its alloys for biomedical purposes, two novel magnesium alloys Mg-Zn-Cu and Mg-Zn-Se were developed with the expectation of improving upon the unfavorable qualities shown by similar magnesium based materials that have previously been explored. The overall performance of these novel magnesium alloys has been assessesed in three distinct phases of research: 1) analysing the mechanical properties of the as-cast …

Evaluation Of Corrosion Properties Of Proprietary Metal Alloy Stents For In-Vivo Use, Michael David Bremner

Materials Engineering

To assess corrosion rates of metal alloy bio-absorbable stents an experimental set-up was designed to mimic the coronary artery environment. The artery was modeled using 4mm diameter Tecoflex tubing and the metal alloy stents were inserted into the tubing using a catheter. As is the case in cardiac surgery, the catheter with the stent and a microballoon were maneuvered to the desired position. The microballoon was then slowly inflated to expand the stent and compress it against the tubing walls. The catheter and microballoon were then withdrawn. A circulating pump system was set up to cycle fetal bovine serum (FBS) …

Evaluation Of Forging Strain For Maximum Grain Size In Open-Die Forged 6061 Aluminum, Eric Strehl

Materials Engineering

In an effort to maximize grain growth of open-die forged 6061 aluminum alloy parts, samples from three of Weber Metals’s suppliers (Hidal Co-Almex USA Inc., TST Inc., and Vista Metals Corp.; to be called Supplier H, Supplier T, Supplier V respectively) were cut into cylinders with diameters of 0.75˝ and heights of 2˝, and put through a simulated forging process and heat treatment. It is possible that additional alloying elements may be promoting or inhibiting grain growth in the final part. Maximizing grain growth for aluminum alloy parts results in improved resistance to intergranular corrosion. Samples from each vendor had …

Comparison Of Polyurethane And Polysiloxane Coating Systems In Marine Environments, Jake Jarman, Jessica Salvatin

Materials Engineering

This project investigates the performance benefits of polysiloxane and polyurethane coating systems for corrosion protection in marine environments. PPG Industries Amercoat 450H and International Paint Interthane 990HS were the polyurethane topcoats tested. PPG Industries Ameron PSX 700 (New Blend) and International Paint Interfine 878 were the polysiloxane topcoats tested. Each coating was sprayed onto carbon steel panels that were prepared through hand blasting with glass beads. Scribed and unscribed panels were tested in a salt fog chamber for 1,200 hours according to ASTM Standard B0117-11 and in a UV/Humidifier for 1,650 hours according to ASTM Standard D4587-11. Panels were tested …

Performance Of Reinforced Concrete Beams Strengthened With Mechanically-Fastened Composite System Under Corrosive Environment, Amna Zaid Suwaid Al Nassibi

Theses

This study examines the effects of corrosion exposure on the flexural response of reinforced concrete (RC) beams strengthened with a powder-actuated fastened (PAF) composite system. Twenty-one RC beams were constructed and tested to failure under four-point bending. The corroded beams were subjected to 30, 60, and 100 days of accelerated corrosion that corresponded to measure tensile steel mass losses of 6, 11 and 18% respectively. Other test parameters included width of fiber reinforced polymer (FRP) composite strip, fastener length, and number of fasteners rows.

For the non-corroded beams, the PAF-FRP system resulted in up to 24% increase in beam flexural …

System For Detection Of Defects In Cables Of Bridge Structures, Emad Ismail Abdel Salam

Theses and Dissertations

Over the last 75 years, many cable-supported bridges have been built in America, Europe, Asia and other parts of the world. However, over the years these bridges have aged and been exposed to environmental conditions such as rain, snow, de-icing and harmful chemicals. These conditions cause various levels of deterioration in bridges, particularly corrosion. Corrosion causes a loss of cross-section in the steel, adversely affecting the bridge's capacity to carry its service loads, and can possibly cause bridge failures. Although many methods have been attempted to inspect these bridges, most have offered limited success. In the recent years, it has …

Influence Of Fluoride And Chromium(Vi) Ions On Corrosion Mechanisms Of Pb-3wt%Sn-0.5wt%Ag Anode, Jianzhong Li, Xiuli Sun, Yanwen Tian, Yue Zhao

Faculty of Engineering and Information Sciences - Papers: Part A

A mix solution of fluorine and chromium ions (Cr-F solution) for applications in chromium plating field has a characteristic of strong corrosion and oxidation, promoting lead alloys anode degraded rapidly. The present study explores the time dependence on corrosion mechanisms of lead alloys anode oxidised in Cr-F solution under conditions of high current density. Scanning electron microscopy (SEM) with an energy dispersive X-ray spectroscopy (EDX) shows a double-layer oxide film is electrochemically developed on lead alloys anode after oxidation for above 0.5h. The outer layer is primarily PbO and PbO2, and the inner layer contains PbCrO4 and PbF2, followed by …

Laboratory Study On Rockbolt Corrosion, Naj Aziz, P Craig, Jan Nemcik

Faculty of Engineering and Information Sciences - Papers: Part A

The effect of long term exposure of full size bolts to corrosive environments is presented. A special test rig was used to test four bolts under different loading conditions. Four, X-grade identical corrosioin testing using acid sulphate water. the pH value of the curculated water varied between 3.4 and 4.3. The corrosion exposure test period lasted three and half years. Two bolts were axially loaded to 10 and 20 tonnes force respectively, the third bolt was subjected to a 360 Nm torsion load and the fourth bolt was left unstressed to act as a reference bolt. After the test period …

In-Plant And Distribution System Corrosion Control For Reverse Osmosis, Nanofiltration, And Anion Exchange Process Blends, Samantha Jeffery

Electronic Theses and Dissertations

The integration of advanced technologies into existing water treatment facilities (WTFs) can improve and enhance water quality; however, these same modifications or improvements may adversely affect finished water provided to the consumer by public water systems (PWSs) that embrace these advanced technologies. Process modification or improvements may unintentionally impact compliance with the provisions of the United States Environmental Protection Agency’s (USEPA’s) Safe Drinking Water Act (SDWA). This is especially true with respect to corrosion control, since minor changes in water quality can affect metal release. Changes in metal release can have a direct impact on a water purveyor’s compliance with …

Investigation Of The Telluric Effects Arising Along The Cathodically Protected Natural Gas Pipeline Between Karadeniz Ereğli And Düzce, Bi̇lal Demi̇rel, Hayri̇ Yalçin

Turkish Journal of Electrical Engineering and Computer Sciences

Cathodic protection is one of the most widely used applications for protecting underground and submarine metallic structures from corrosion. This method is based on providing the electrons, which metallic structures lose as a result of electrolytic reaction, by the cathodic protection system. However, from time to time, it may be possible that there is some unwanted interference input into the metallic structure in such applications. This study is aimed at ascertaining the existence, arising frequency, and magnitude of an interference called the telluric effect that is going in and out of the natural gas pipeline between Düzce and Karadeniz Ereğli …

Assessing Corrosion Damage In Post -Tensioned Concrete Structures Using Acoustic Emission & A Preliminary Investigation Of Biopolymer Doped Cement Mortar For Use In Structural Restoration, Aditya Appalla

Theses and Dissertations

A sizeable portion of the civil infrastructure is made from concrete. An estimate shows that about 7 billion cubic meters of concrete is made annually worldwide. With the deterioration of the infrastructure due to aging or external factors, significant monetary and technological investment is needed for condition evaluation, maintenance and repair. Two areas that account for a considerable portion of this investment are condition evaluation for maintenance of corroded concrete structures and mortar patching for repair and rehabilitation.

The primary method of evaluation of a structure is by visual inspection. But this method is limited as some crucial areas in …

Assessment Of Damage In Concrete Structures Using Acoustic Emission, Marwa Abdelrahman

Theses and Dissertations

Evaluating the integrity of concrete structures is an essential procedure to ensure structural safety and durability. Non-destructive testing (NDT) is needed for localizing and characterizing the growing damage in existing structures and also for quality control of new structures. Visual inspection is a commonly used method; however it is not suitable for early detection of damage and very dependent on the experience of the inspector. More research is needed to establish advanced methods for structural health diagnosis such as acoustic emission (AE). Acoustic emission is notably sensitive to active damage in concrete structures. This thesis includes three studies that mainly …

Kelvin Probe Electrode For Contactless Potential Measurement On Concrete-Properties And Applications, Michael Thomas Walsh

USF Tampa Graduate Theses and Dissertations

The practical feasibility of using a Kelvin Probe as a novel reference electrode in the measurement of both potential and polarization pulse response of reinforcing steel in concrete is demonstrated. Potential values measured using a KP reflect greater stability and repeatability than can typically be attained with conventional reference electrodes. Duplicate reinforced concrete beam test specimens with well-differentiated centrally corroding rebar segments were analyzed using both the Kelvin Probe (KP) and a conventional Saturated Calomel Electrode (SCE). Potential profile maps were developed using potential values recorded under static conditions with both the SCE and the KP. Nominal polarization resistance was …

A Study On The Cleaning And Modification Of Metal Surfaces By Direct Current Cathodic Electrolytic Plasma Process, Jiandong Liang

LSU Doctoral Dissertations

The processes of surface treatments or surface modifications, more formally known as surface engineering, tailor the surfaces of engineering materials. The treatments are usually intended to change physical properties such as thermal or electrical conductivity, modify the surface dimensions, i.e. roughness, etc. A novel surface treatment method, Electrolytic Plasma Process (EPP), was developed for coating purposes, in its early developmental stage. In this work, the major effort is to avoid using any environmental hazardous chemical (coatings) and to extend such its application to some new fields. The general response of the substrate material under electrolytic plasma process was summarized including …