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2010

University of Massachusetts Amherst

Adsorption

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Quantifying Defects In Zeolites And Zeolite Membranes, Karl Daniel Hammond Feb 2010

Quantifying Defects In Zeolites And Zeolite Membranes, Karl Daniel Hammond

Open Access Dissertations

Zeolites are crystalline aluminosilicates that are frequently used as catalysts to transform chemical feedstocks into more useful materials in a size- or shape-selective fashion; they are one of the earliest forms of nanotechnology. Zeolites can also be used, especially in the form of zeolite membranes (layers of zeolite on a support), to separate mixtures based on the size of the molecules. Recent advances have also created the possibility of using zeolites as alkaline catalysts, in addition to their traditional applications as acid catalysts and catalytic supports. Transport and catalysis in zeolites are greatly affected by physical and chemical defects. Such …