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Full-Text Articles in Engineering
Modeling The Effects Of Ion Association On Alternating Current Impedance Of Solid Polymer Electrolytes, Changqing Lin, Ralph E. White, Harry J. Ploehn
Modeling The Effects Of Ion Association On Alternating Current Impedance Of Solid Polymer Electrolytes, Changqing Lin, Ralph E. White, Harry J. Ploehn
Faculty Publications
This work presents a rigorous continuum model describing the transport of ions and associated ion pairs in solid polymer electrolytes subjected to small amplitude alternating current (ac) excitation. The model treats ion association as a reversible reaction among ions and ion pairs. Dimensionless governing equations are developed from component mass balances, flux equations based on dilute solution theory, and the Poisson equation. Assuming reversible electrode reactions and electroneutrality, the model equations have an analytical solution. Further simplifications are possible in limiting cases (weak and strong association, zero and infinite frequency excitation), giving expressions consistent with previously published models. We use …
Estimation Of Diffusion Coefficient Of Lithium In Carbon Using Ac Impedance Technique, Qingzhi Guo, Venkat R. Subramanian, John W. Weidner, Ralph E. White
Estimation Of Diffusion Coefficient Of Lithium In Carbon Using Ac Impedance Technique, Qingzhi Guo, Venkat R. Subramanian, John W. Weidner, Ralph E. White
Faculty Publications
The validity of estimating the solid phase diffusion coefficient, Ds, of a lithium intercalation electrode from impedance measurement by a modified electrochemical impedance spectroscopy (EIS) method is studied. A macroscopic porous electrode model and concentrated electrolyte theory are used to simulate the synthetic impedance data. The modified EIS method is applied for estimating Ds. The influence of parameters such as the exchange current density, radius of active material particle, solid phase conductivity, porosity, volume fraction of inert material, and thickness of the porous carbon intercalation electrode, the solution phase diffusion coefficient, and transference number, on the …