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Full-Text Articles in Engineering
Characterization Of Aerosol Jet Printed Silver Thin Films Sintered By A Scanning Laser, William A. Metzger
Characterization Of Aerosol Jet Printed Silver Thin Films Sintered By A Scanning Laser, William A. Metzger
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Direct write printing, which is part of additive manufacturing (AM) technology, offers unique capabilities that can complement traditional methods of electronics fabrication. Printing of electrical interconnects via aerosolization is one of the areas in AM that is very important in electronics fabrication. Post-print sintering is a critical step in printed electrical interconnects because it strongly influences the electrical resistivity of the interconnects. Interconnects require the lowest possible resistivity to achieve better performance. Thermal sintering is the most common technique employed in printed interconnects. However, it is limited to substrates that can handle the high temperature requirement for sintering. For polymers …
Bandgap Engineering Of 2d Materials And Its Electric And Optical Properties, Kumar Vishal
Bandgap Engineering Of 2d Materials And Its Electric And Optical Properties, Kumar Vishal
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Since their invention in 1958, Integrated Circuits (ICs) have become increasingly more complex, sophisticated, and useful. As a result, they have worked their way into every aspect of our lives, for example: personal electronic devices, wearable electronics, biomedical sensors, autonomous driving cars, military and defense applications, and artificial intelligence, to name some areas of applications. These examples represent both collectively, and sometimes individually, multi-trillion-dollar markets. However, further development of ICs has been predicted to encounter a performance bottleneck as the mainstream silicon industry, approaches its physical limits. The state-of-the-art of today’s ICs technology will be soon below 3nm. At such …
Processing And Characterization Of Inkjet Printed Batio3/Su-8 Nanocomposite Dielectrics, Mustapha A. Muhammad
Processing And Characterization Of Inkjet Printed Batio3/Su-8 Nanocomposite Dielectrics, Mustapha A. Muhammad
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The persistent demand for flexible and wearable electronic components in healthcare, aerospace, media, and transit applications has led to a significant shift from traditional electronics processes to printed electronics. Printed electronics are anticipated to establish itself as the industry's dominant force due to their enhanced flexibility, rapid prototyping capabilities, and seamless integration with everyday objects. They are cost-effective and have the scalable option for large-scale production because additive manufacturing techniques are used. Among the various printing methods available, inkjet printing has recently gained popularity for printing electronics, especially capacitors that require precise and complex structures on different substrates. Inkjet printing …
Rheological Modeling And Inkjet Printability Of Electrode Ink Formulation For Miniature And Interdigital Lithium-Ion Batteries, Habib Temitope-Adebayo Ajose
Rheological Modeling And Inkjet Printability Of Electrode Ink Formulation For Miniature And Interdigital Lithium-Ion Batteries, Habib Temitope-Adebayo Ajose
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The rapid advancement of technology has resulted in a greater need for effective energy storage systems to meet the demands of the transportation and electronics industries. Among various energy storage systems, batteries are the most widely used, primarily because of their ability to store significant amounts of energy. In addition, lithium-ion batteries are prevalent for powering portable electronic devices due to their long cycle life, high energy density, and high operating voltage. The traditional doctor-blade approach has been used over the years for producing batteries. Currently, research is being directed to additively manufacture Li-ion batteries via Drop-on-Demand Inkjet Printing with …
Direct Ink Write Processing Of Signal Crossovers Using Aerosol Jet Printing Method, Lucas A. Clark
Direct Ink Write Processing Of Signal Crossovers Using Aerosol Jet Printing Method, Lucas A. Clark
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Electronics in different applications, such as in medical imaging devices, radar systems, communication transmitters, and optical drives, often require various power and signal lines to be integrated at board level. In such cases, different lines may cross over one another in three-dimensional space for efficient electronic integration. Crossovers are usually achieved by adding additional layers to a PCB. However, these additional layers increase the cost, weight, and complexity of the component. By creating a process and structure to offer board-level heterogenous integration, these factors may be reduced. RF-DC crossovers were designed and additively manufactured using an aerosol jet printer. Benzocyclobutene …
Effect Of Size And Shape Parameters On Microstructure Of Additively Manufactured Inconel 718, Showmik Ahsan
Effect Of Size And Shape Parameters On Microstructure Of Additively Manufactured Inconel 718, Showmik Ahsan
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Additive Manufacturing (AM) methods are promising in applications where complex part geometries, exotic materials and small lot sizes are required. Aerospace manufacturing stands to use AM methods extensively in the future, and frequently requires temperature- and corrosion-resistant alloy materials such as Inconel 718. However, the microstructural evolution of Inconel 718 during additive manufacturing is poorly understood and depends on part size and shape. We studied the microstructure of Inconel 718 parts manufactured by Laser Powder Bed Fusion in order to further elucidate these dependencies. Microstructural analysis, SEM imaging, EBSD scans and Microhardness testing were performed.
Comparative Study Of Mof's In Phosphate Adsorption, Eniya Karunamurthy
Comparative Study Of Mof's In Phosphate Adsorption, Eniya Karunamurthy
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High concentrations of phosphate are known to adversely affect the environment. Excess phosphate can lead to eutrophication that eventually fosters uncontrollable growth of aquatic plants and algae. This can result in depletion of oxygen content which adversely impacts underwater organism’s survival rates. Metal organic frameworks (MOFs) consist of organic linkers in conjunction with metal ions or clusters arranged within a crystalline structure. They are highly porous and have larger surface area due to their ability to possess extensive void spaces while remaining bulky in nature. MOFs can absorb phosphate from aqueous solutions. We have investigated the use of commercially available …
Printing, Characterization, And Mechanical Testing Of Additively Manufactured Refractory Metal Alloys, Brianna M. Sexton
Printing, Characterization, And Mechanical Testing Of Additively Manufactured Refractory Metal Alloys, Brianna M. Sexton
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Refractory metal alloys in the tungsten molybdenum rhenium ternary system were additively manufactured using laser power bed fusion. Four ternary alloys with varying concentrations of tungsten, molybdenum, and rhenium were manufactured and manufactured again with an addition of 1 wt% hafnium carbide. Samples were heat treated to heal cracks, reduce porosity, and reduce inhomogeneity. Material microstructure was characterized before and after heat treatment using microscopy, energy dispersive x-ray spectroscopy, and electron backscatter diffraction mapping. Mechanical testing was conducted on both three-point bend specimens and compression specimens, resulting in maximum bending strengths of 677.86 MPa, and maximum compression 0.2% yield strengths …
Molecular Dynamics Simulation Study Of A Polymer Droplet Transport Over An Array Of Spherical Nanoparticles, Anish Thomas
Molecular Dynamics Simulation Study Of A Polymer Droplet Transport Over An Array Of Spherical Nanoparticles, Anish Thomas
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This study uses molecular dynamics simulations to evaluate the dynamic behavior of a partially wetting polymer droplet driven over a nanostructured interface. We consider the bead-spring model to represent a polymeric liquid that partially wets a rough surface composed of a periodic array of spherical particles. Results show that at sufficiently small values of external force, the droplet remains pinned at the particle's surface, whereas above the threshold its motion consists of alternating periods of pinning and rapid displacements between neighboring particles. The latter process involves large periodic variation of the advancing and receding contact angles due to the attachment …
Effect Of Build Geometry And Build Parameters On Microstructure, Fatigue Life, And Tensile Properties Of Additively Manufactured Alloy 718, Anna Dunn
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Additive Manufacturing (AM), particularly laser powder bed fusion, is being studied for use in critical component applications. Tensile and fatigue testing shows differences when built using different laser powers. However, when fabricated in an as-printed geometry, the gauge sections of the two specimens are different and experience different thermal behavior. This work explores microhardness, microstructure size, Niobium segregation, and porosity from samples made with varying laser power and different build geometry sizes representative of the gauge sections in the tensile and fatigue bars. Results show that microhardness varies spatially across the sample. Smaller diameter metallographic coupons (fatigue diameter) have a …
Influence Of Fill Percentage And Baking Parameters On The Feedability Of Metal-Cored Arc Welding Wires, Angelica Marie Black
Influence Of Fill Percentage And Baking Parameters On The Feedability Of Metal-Cored Arc Welding Wires, Angelica Marie Black
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Adequate feedability is essential for GMAW processes to ensure efficiency. The feedability of a wire refers to the wire’s ability to feed continuously through the contact tip. While there are several known causes of feedability difficulties when using cored welding wires, there are many variables that have yet to be explored thoroughly. Three factors are investigated in this research to determine their effects on feedability of cored wires: fill percentage, baking time, and baking temperature. A set of metal-cored arc welding wires were created with various fill percentages, baking times, and baking temperatures. Tension testing, microhardness testing, microstructural characterization, and …
Aqueous Fabrication Of Pristine And Oxide Coated Znse Nanoparticles, Nicholas L. Van Zandt
Aqueous Fabrication Of Pristine And Oxide Coated Znse Nanoparticles, Nicholas L. Van Zandt
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Semiconducting nanoparticles have received significant attention due to their unique optoelectronic properties. Quantum dots (QDs), a class of spherical nanoparticles, possess a size-dependent bandgap and photoluminescence at visible wavelengths. QDs have many applications including biological labelling, solar cells, chemical impurity detection, and optical glasses. Doping QDs into optical glasses is highly desirable. High-quality QDs can be synthesized via liquid solution methods. However, solution-synthesized QDs often degrade over time and they cannot survive incorporation into a glass melt without protection. In this work, the aqueous synthesis of ZnSe QDs and coating with nanometer silica and alumina protective shells are investigated. The …
Phase Transformation In The Aluminum/Tungsten System, Ammar Azeez Mahdi Al Yasari
Phase Transformation In The Aluminum/Tungsten System, Ammar Azeez Mahdi Al Yasari
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Formation and growth mechanisms of intermetallic compounds in the aluminum/tungsten system were studied during consolidation and subsequent heat treatment. Three different processes, spark plasma sintering (SPS), laser powder bed fusion (LPBF), and metal inert gas welding (MIG) were used, and each of these processes were followed up with heat treatment at different conditions. Al12W, Al5W and Al4W are the three intermetallics that are stable in the system in room temperature, and they were expected to form at the interface between tungsten and aluminum at different temperature ranges. Contrary to expectations, the Al5W phase was not observed during this study and …
Fabrication And Analysis Of High-Performance Thermochemically Densified Wood, Victor Arulappan Pushparaj
Fabrication And Analysis Of High-Performance Thermochemically Densified Wood, Victor Arulappan Pushparaj
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While wood construction may be as ancient as humanity itself, wood remains one of the most utilized structural materials because of it’s availability, low cost, durability, surprisingly high specific mechanical properties, and renewability. Recent research into wood-based materials has focused on strategies for enhancing the strength and stiffness of as-grown materials. We fabricated densified wood by thermochemically treating raw white oak wood in Na2SO3 and NaOH solutions, followed by compressing the treated wood at 5MPa at high temperature. Treating the raw wood in NaOH and Na2SO3 cleaves the alpha-O-4 ether bond and beta-O-4 ether bonds, thus dissolving most of the …
Functionalizing Ceramic Matrix Composites By The Integration Of A Metallic Substructure With Comparable Feature Size, Elizabeth Pierce Heckman
Functionalizing Ceramic Matrix Composites By The Integration Of A Metallic Substructure With Comparable Feature Size, Elizabeth Pierce Heckman
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A metallic network has been embedded in a silicon carbide fiber– silicon carbide (SiC) matrix ceramic composite (CMC) in order to combine the functional properties of the metal and the structural properties of the CMC. The processing of the composite involves iterative pre-ceramic polymer infiltration and heating to temperatures at 1100°C. The metallic structure embedded in the CMC must retain its unique properties during processing and cannot convert to a silicide or carbide resulting from diffusion of Si and C species from the SiC matrix. To gain an understanding of the diffusion process, a fully processed CMC with tungsten, tantalum, …
Texture-Driven Image Clustering In Laser Powder Bed Fusion, Alexander H. Groeger
Texture-Driven Image Clustering In Laser Powder Bed Fusion, Alexander H. Groeger
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The additive manufacturing (AM) field is striving to identify anomalies in laser powder bed fusion (LPBF) using multi-sensor in-process monitoring paired with machine learning (ML). In-process monitoring can reveal the presence of anomalies but creating a ML classifier requires labeled data. The present work approaches this problem by printing hundreds of Inconel-718 coupons with different processing parameters to capture a wide range of process monitoring imagery with multiple sensor types. Afterwards, the process monitoring images are encoded into feature vectors and clustered to isolate groups in each sensor modality. Four texture representations were learned by training two convolutional neural network …
Texture Evolution In Materials With Layered Crystal Structures, Vamsi Krishna Vempati
Texture Evolution In Materials With Layered Crystal Structures, Vamsi Krishna Vempati
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Materials with a layered structure consist of crystalline layers that are bonded to each other with secondary bonds (van der Waals interactions). The bonding between crystalline layers is relatively weak compared to the interatomic bonding within the crystalline layers. This research hypothesizes that under appropriate conditions, such as elevated temperature, the deformation of layered materials occurs like the classic “deck of cards” with no preferred direction of slip on the slip planes. The motivation for this study is from the experimental texture evolution of one such material, Bismuth Telluride ,(Bi2Te3), commonly used materials for thermoelectric applications in the range of …
Influence Of Build Direction On Interface Regions In Additive Manufacturing Of Multi-Material Refractory Alloys, Cherish Christina Clark Lesko
Influence Of Build Direction On Interface Regions In Additive Manufacturing Of Multi-Material Refractory Alloys, Cherish Christina Clark Lesko
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In the pursuit of optimum performance, materials engineering seeks to design the microstructure and thus the properties of a material through the control of the material composition and processing. Functionally graded materials (FGM) are designed to incorporate location-specific material properties through compositional changes within the part. Moving toward location-specific design of material properties requires the ability to produce material gradients in three dimensions which can be accomplished through the use of additive manufacturing (AM). This research examines the composition-process-structure-property relationship of early iteration titanium (Ti) and tantalum (Ta) graded alloys built in a novel laser powder bed fusion (LPBF) process …
Ab Initio Methylammonium Orientation And Monolayer Effects In Hybrid Perovskite Solar Cells, Jacob M. Artz
Ab Initio Methylammonium Orientation And Monolayer Effects In Hybrid Perovskite Solar Cells, Jacob M. Artz
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Methylammonium lead triiodide (MAPbI3) has garnered attention due to their high solar cell efficiencies and low cost to manufacture, but commercialization is not yet possible owing to poor environmental stability. Thus, researchers seek ways which optimize the performance of the MAPbI3 solar cell by modifying the architecture and through interfacial engineering of the charge transport layers. Difficulties in understanding these devices arise from ion migration, charge separation and recombination, and metastable, thermally active precessions of the methylammonium (MA) moiety in the lead iodide framework. In this work, focus is given to the perovskite and an adsorbed monolayer, 2,3,4,5,6-pentafluorothiophenol (C6F5SH), which …
Texture-Driven Image Clustering In Laser Powder Bed Fusion, Alexander H. Groeger
Texture-Driven Image Clustering In Laser Powder Bed Fusion, Alexander H. Groeger
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The additive manufacturing (AM) field is striving to identify anomalies in laser powder bed fusion (LPBF) using multi-sensor in-process monitoring paired with machine learning (ML). In-process monitoring can reveal the presence of anomalies but creating a ML classifier requires labeled data. The present work approaches this problem by printing hundreds of Inconel-718 coupons with different processing parameters to capture a wide range of process monitoring imagery with multiple sensor types. Afterwards, the process monitoring images are encoded into feature vectors and clustered to isolate groups in each sensor modality. Four texture representations were learned by training two convolutional neural network …
Ab Initio Methylammonium Orientation And Monolayer Effects In Hybrid Perovskite Solar Cells, Jacob M. Artz
Ab Initio Methylammonium Orientation And Monolayer Effects In Hybrid Perovskite Solar Cells, Jacob M. Artz
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Methylammonium lead triiodide (MAPbI3) has garnered attention due to their high solar cell efficiencies and low cost to manufacture, but commercialization is not yet possible owing to poor environmental stability. Thus, researchers seek ways which optimize the performance of the MAPbI3 solar cell by modifying the architecture and through interfacial engineering of the charge transport layers. Difficulties in understanding these devices arise from ion migration, charge separation and recombination, and metastable, thermally active precessions of the methylammonium (MA) moiety in the lead iodide framework. In this work, focus is given to the perovskite and an adsorbed monolayer, 2,3,4,5,6-pentafluorothiophenol (C6F5SH), which …
Influence Of Build Direction On Interface Regions In Additive Manufacturing Of Multi-Material Refractory Alloys, Cherish Christina Clark Lesko
Influence Of Build Direction On Interface Regions In Additive Manufacturing Of Multi-Material Refractory Alloys, Cherish Christina Clark Lesko
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In the pursuit of optimum performance, materials engineering seeks to design the microstructure and thus the properties of a material through the control of the material composition and processing. Functionally graded materials (FGM) are designed to incorporate location-specific material properties through compositional changes within the part. Moving toward location-specific design of material properties requires the ability to produce material gradients in three dimensions which can be accomplished through the use of additive manufacturing (AM). This research examines the composition-process-structure-property relationship of early iteration titanium (Ti) and tantalum (Ta) graded alloys built in a novel laser powder bed fusion (LPBF) process …
Correlating In-Situ Monitoring Data With Internal Defects In Laser Powder Bed Fusion Additive Manufacturing, Andrew J. Harvey
Correlating In-Situ Monitoring Data With Internal Defects In Laser Powder Bed Fusion Additive Manufacturing, Andrew J. Harvey
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The presence of defects within laser powder bed fusion (LPBF) parts can lead to reduced mechanical properties and life of components. Because of this, the ability to detect these defects within the parts is critical before the part is subject to its intended loading. Normally the parts are subjected to a quality analysis once they are completed however, this process is typically expensive and time consuming. A solution for these problems is to sense the creation of defects and pores in the parts in-situ, while the part is being fabricated. One proposed method of in-situ monitoring is visible spectroscopy to …
Metal Coupon Testing In An Axial Rotating Detonation Engine For Wear Characterization, Gary S. North
Metal Coupon Testing In An Axial Rotating Detonation Engine For Wear Characterization, Gary S. North
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Rotating Detonation Engines (RDE) are being explored as a possible way to get better fuel efficiency for turbine engines than is otherwise possible. The walls of the RDE are subjected to cyclic thermal and mechanical shock loading at rates of approximately 3 KHz, with gas temperatures as high as 2976 K. This project performed testing with Inconel 625 and 304 stainless steel coupons in an RDE outer body to attempt to measure material ablation rates. Significant microstructural changes were observed to include grain growth in both alloys, carbide formation and grain boundary melting in Inconel, and formation of delta ferrite …
The Thermal And Mechanical Characteristics Of Lithiated Peo Lagp Composite Electrolytes, Jacob Michael Denney
The Thermal And Mechanical Characteristics Of Lithiated Peo Lagp Composite Electrolytes, Jacob Michael Denney
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Lithium-ion batteries are part of a multibillion-dollar industry that strives to meet the demands for an increasingly advanced technological future. Flexible batteries can be easily adapted from emerging novel wearable electronics to electrical vehicles and advanced solar panels. Solid-state batteries can greatly reduce the risk of fire or leaking hazardous materials due to puncture. For the development of solid-state flexible lithium based batteries polymer-ceramic composites are attractive electrolyte candidates because of their combined properties, such as electrical, thermal and mechanical properties, that not only overcome limitations from the base materials but may also render some enhanced performances resulting from the …
Stabilization Of Β-Cristobalite In The Sio2-Alpo4-Bpo4 System, Kathryn Doyle
Stabilization Of Β-Cristobalite In The Sio2-Alpo4-Bpo4 System, Kathryn Doyle
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Fused silica (silica glass) is transparent in the optical and near-infrared and has a low dielectric constant, making it suitable as a window material for radio frequency radiation. However, at high temperatures (>1100C), fused silica will easily creep and lose dimensional stability. Crystallized silica is much more creep resistant than fused silica. Silica crystallizes to many different structures including quartz, tridymite, and α- and β cristobalite. The only cubic polymorph, which is suitable for both optical and radio frequency transmission in polycrystalline form, is β -cristobalite. Unfortunately, this polymorph transforms to α-cristobalite at ~300C, and the volume change during …
A First Principles Study Of Pipe Diffusion In Nickel, Luke J. Wirth
A First Principles Study Of Pipe Diffusion In Nickel, Luke J. Wirth
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Vacancy-mediated diffusion along dislocations, often referred to as pipe diffusion, can contribute to creep deformation of metals in many engineering applications. This process is studied along an a/2⟨1 -1 0⟩ screw dislocation in fcc Ni using a density functional theory approach. An accurate geometrical configuration of the screw dislocation core, dissociated into Shockley partial dislocations and separated by a stacking fault, was previously derived using a lattice Green's function technique. Activation energies and frequencies are calculated for atom-vacancy exchanges that contribute to diffusion around and along one of the partial cores. This analysis reveals the significant role of the sites …
Ab Initio Modeling Of An Electron Transport Layer Interface In Hybrid Perovskite Solar Cells, Krantikumar Subhash Pawar
Ab Initio Modeling Of An Electron Transport Layer Interface In Hybrid Perovskite Solar Cells, Krantikumar Subhash Pawar
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Hybrid organic-inorganic perovskite solar cell is an emerging technology which has shown the fastest advancement in power conversion efficiency within a few years since introduction, thus making it one of the clean energy breakthroughs. These cells are based on thin-film technology which makes them suitable to manufacture using low-cost solution processing methods. As these types of cells are easily tunable with the selection of different materials, interfacial engineering is an important approach to increasing their efficiency. One of the main hurdles in this regard is the loss caused by the recombination of separated charges. An approach to tackle these issues …
Hierarchical Hybrid Materials From Flexible Fabric Substrates, Wenhu Wang
Hierarchical Hybrid Materials From Flexible Fabric Substrates, Wenhu Wang
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The goal of this project is to investigate fabrication approaches and structure-property relationships of porous and flexible hierarchical hybrid solids suitable for advanced surface-active devices. Multi-scale hierarchical carbon materials are being fabricated by strong covalent attachment of multiwall carbon nanotube(MWCNTs) arrays on flexible carbon fabric substrates in order to enhance the surface area per unit volume. This was done using chemical vapor deposition (CVD) after functionalizing the surface with a plasma-derived nano-oxide coating. Structural and chemical characterization is performed using scanning electron microscope(SEM), energy dispersive spectroscopy(EDS) and x-ray photoelectron spectroscopy(XPS). Surface area estimates have been made by building structural models …
Primary Processing Parameters And Their Influence On Porosity And Fatigue Life Of Additively Manufactured Alloy 718, Luke C. Sheridan
Primary Processing Parameters And Their Influence On Porosity And Fatigue Life Of Additively Manufactured Alloy 718, Luke C. Sheridan
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In many structural applications void-like defects cause significant performance debits which call for component redesign or post-processing to account for or remove the defects. For laser powder bed fusion (LPBF) processes, it has been shown that many of these features and their size and shape characteristics are controllable through LPBF process parameter manipulation. For design efforts, however, it is necessary to understand the direct influences of processing on the formation of porosity and the role that individual pores and porosity distributions have on the properties and performance of AM components. Additionally, design criteria must be established to facilitate implementation of …