Engineering Commons^™

3d Printing Technology Applied In Lithium Metal Batteries: From Liquid To Solid., Xuejie Gao

Electronic Thesis and Dissertation Repository

Li-metal batteries are strongly considered to be one of the most promising candidates for high energy density energy storage devices in our modern society. However, the state-of-the-art Limetal batteries are still limited by several challenges including 1) low energy/power density; 2) Li dendrite growth; 3) low coulombic efficiency, and 4) safety concerns within the liquid electrolyte. This thesis mainly focuses on addressing these challenges by using a 3D printing technique to realize high energy/power density Li-metal batteries.

A self-standing high areal energy density cathode for Li-S battery was developed by the 3D printing method in the first part. The optimized …

3d Printed Polypyrrole Scaffolds For Ph Dependent Drug Delivery With Applications In Bone Regeneration, Matthew T. Lawrence

Electronic Thesis and Dissertation Repository

Areas of large bone loss are typically healed using autologous bone grafts, seen as the gold standard of care. These materials have a complication rate of 10–40% during harvesting and are limited by the quantity available; therefore the use of 3D printed polymer scaffolds as bone graft alternatives are proposed. Polypyrrole (PPy) is a biocompatible electroactive polymer that has metal-like electrical properties that can be harnessed to hold and release charged drug molecules, triggered by a change in pH. pH fluctuations are seen inside the human body in areas of bone regrowth, which would act as the triggering mechanism for …

Study Of Recyclable And Repairable Dynamic Covalent Polymers For Sustainable 3d Printing Development, Mingyue Zheng

Electronic Thesis and Dissertation Repository

3D printing technology with valuable features, including cost-saving, easy access, and unlimited structure design, has attracted significant attention and been employed for production use. This technology has also been considered as a sustainable manufacturing method and quickly developed in recent years. However, the development of sustainable 3D printing is still facing challenges, especially in waste management. Thanks to the flexibility of 3D printing and diversified printing mechanisms, the big step forward can be approachable by the transformation from materials. This dissertation presents a variety of strategies designed for sustainable 3D printing development based on the combination of dynamic covalent chemistry …

Metallization Process For 3d Printed Electronics: From I3dp Ii To 3d Co-Printing Technology, Junfeng Xiao

Electronic Thesis and Dissertation Repository

3D printing has emerged as a powerful additive manufacturing technique and becomes as a viable alternative to conventional manufacturing processes in an increasing number of applications. Thus, the development of printable materials also continues to expand, while polymers are still the most utilized materials in 3D printing. There is a great advance for developing polymers with versatile mechanical and chemical properties. However, the end-use products are demanding various functions. It is imperative to develop functional 3D printed polymeric materials to achieve enhanced functionalities.

Usually, one polymer can meet one specific application. This has considerably limited the capability of 3D printing …