Engineering Commons^™

Development And Preliminary Evaluation Of A Spray Deposition Sensing System For Improving Pesticide Application, Melissa A. Kesterson, Joe D. Luck, Michael P. Sama

Biosystems and Agricultural Engineering Faculty Publications

An electronic, resistance-based sensor array and data acquisition system was developed to measure spray deposition from hydraulic nozzles. The sensor surface consisted of several parallel tin plated copper traces of varying widths with varying gap widths. The system contained an embedded microprocessor to monitor output voltage corresponding to spray deposition every second. In addition, a wireless module was used to transmit the voltage values to a remote laptop. Tests were conducted in two stages to evaluate the performance of the sensor array in an attempt to quantify the spray deposition. Initial tests utilized manual droplet placement on the sensor surface …

High Capacity Silicon Electrodes With Nafion As Binders For Lithium-Ion Batteries, Jiagang Xu, Qinglin Zhang, Yang-Tse Cheng

Chemical and Materials Engineering Faculty Publications

Silicon is capable of delivering a high theoretical specific capacity of 3579 mAh g⁻¹ which is about 10 times higher than that of the state-of-the-art graphite based negative electrodes for lithium-ion batteries. However, the poor cycle life of silicon electrodes, caused by the large volumetric strain during cycling, limits the commercialization of silicon electrodes. As one of the essential components, the polymeric binder is critical to the performance and durability of lithium-ion batteries as it keeps the integrity of electrodes, maintains conductive path and must be stable in the electrolyte. In this work, we demonstrate that electrodes consisting of …

An Organic Mixed Ion-Electron Conductor For Power Electronics, Abdellah Malti, Jesper Edberg, Hjalmar Granberg, Zia Ullah Khan, Jens W. Andreasen, Xianjie Liu, Dan Zhao, Hao Zhang, Yulong Yao, Joseph W. Brill, Isak Engquist, Mats Fahlman, Lars Wågberg, Xavier Crispin, Magnus Berggren

Physics and Astronomy Faculty Publications

A mixed ionic–electronic conductor based on nanofibrillated cellulose composited with poly(3,4-ethylene-dioxythio­phene):­poly(styrene-sulfonate) along with high boiling point solvents is demonstrated in bulky electrochemical devices. The high electronic and ionic conductivities of the resulting nanopaper are exploited in devices which exhibit record values for the charge storage capacitance (1F) in supercapacitors and transconductance (1S) in electrochemical transistors.

Petrology And Geochemistry Of The Harlan, Kellioka, And Darby Coals From The Louellen 7.5-Minute Quadrangle, Harlan County, Kentucky, Michelle N. Johnston, James C. Hower, Shifeng Dai, Peipei Wang, Panpan Xie, Jingjing Liu

Center for Applied Energy Research Faculty and Staff Publications

The Harlan, Kellioka, and Darby coals in Harlan County, Kentucky, have been among the highest quality coals mined in the Central Appalachians. The Middle Pennsylvanian coals are correlative with the Upper Elkhorn No. 1 to Upper Elkhorn No. 3½ coals to the northwest of the Pine Mountain thrust fault. Much of the mining traditionally was controlled by captive, steel-company-owned mines and the coal was part of the high volatile A bituminous portion of the coking coal blend. Overall, the coals are generally low-ash and low-sulfur, contributing to their desirability as metallurgical coals. We did observe variation both in geochemistry, such …

Creating A Highway Information System For Safety Roadway Features, Brian K. Howell, Kenneth R. Agent, Eric Green

Kentucky Transportation Center Research Report

Roadway departures are the leading cause of roadside fatalities. The Kentucky Transportation Cabinet (KYTC) has undertaken a number of roadside safety measures to reduce roadway departures. Specifically, KYTC has installed several low-cost, systemic roadway safety treatments to Kentucky’s roadways in recent years. These treatments include cable barriers, high friction surface treatments, rumble stripes, and Safety Edges. KYTC has installed approximately 44 cable barrier systems over 265 miles of roadway,112 HFST applications over 20 miles of roadway, 750 rumble stripe installations over 2,500 miles of roadway, and 147 Safety Edge treatments on 580 miles of roadway. The project team developed a …

Properties Of Pan Fibers Solution Spun Into A Chilled Coagulation Bath At High Solvent Compositions, E. Ashley Morris, Matthew C. Weisenberger, Gregory Wilson Rice

Center for Applied Energy Research Faculty and Staff Publications

In this work, multifilament, continuous polyacrylonitrile (PAN) fiber tow was solution spun mimicking industrial processing at the small pilot scale (0.5 k tow), while carefully altering the composition of the coagulation bath, in order to determine the effect on the resulting fiber shape, density, orientation, and tensile properties at varying points in the spinning process. Novel here are the abnormally high coagulation bath solvent compositions investigated, which surpass those often reported in the literature. In addition, the coagulation bath was maintained at a slightly chilled temperature, contrary to reported methods to produce round fibers. Further, by altering the composition of …

Fiscal Year 2015 Fhwa-536 Report For The Kentucky Transportation Cabinet, Steven Douglas Kreis, Candice Y. Wallace, Bryan Gibson, Sarah M. Mccormack

Kentucky Transportation Center Research Report

The Federal Highway Administration (FHWA) requires state transportation agencies to submit a biennial report on local highway finances. The purpose of these reports is to provide FHWA with the data it needs to capture the financing of highway activities at the local level. Based on this information, it can identify trends in revenue, expenditures, investments, and program development, and in turn make decisions about future investments. The report, FHWA-536, asks agencies to report on four areas of local highway finance: 1) disposition of highway-user revenues; 2) revenues used for roads and streets identified by source and funding type; 3) road …

Evaluation Of Thermal Imaging Technology For Commercial Vehicle Screening, Jennifer R. Walton, Mark S. Spellman, Joseph D. Crabtree

Kentucky Transportation Center Research Report

Brake and tire violations are common problems identified through commercial vehicle inspections. Identifying and correcting these types of problems before a crash occurs can produce significant safety benefits. Thermal imaging technology can be used by commercial vehicle enforcement to screen vehicles as they approach a weigh station to determine if they may have flat tires and inoperable brakes. The vehicles do not have to be stopped at a weigh station to be screened. Kentucky currently has three stations outfitted with thermal imaging technology. The objectives of this study were to evaluate the benefits of using the thermal imaging cameras to …

Methodology Update For Estimating Volume To Service Flow Ratio, Mei Chen, Xu Zhang

Kentucky Transportation Center Research Report

Volume/service flow ratio (VSF) is calculated by the Highway Performance Monitoring System (HPMS) software as an indicator of peak hour congestion. It is an essential input to the Kentucky Transportation Cabinet’s (KYTC) key planning applications, such as highway adequacy rating. After the Federal Highway Administration (FHWA) reassessed the HPMS, the standalone HPMS software was no longer supported. This conclusion was based on the 2000 Highway Capacity Manual (HCM2000). As a result, the peak capacity and VSF estimates based on the submittal file are no longer available to KYTC. The calculation of VSF ratios requires AADT, K factor, directional factor, and …

Update Of Data For Estimating Esals, Jerry G. Pigman, R. Clark Graves, Brad W. Rister, David H. Cain, Neil Tollner

Kentucky Transportation Center Research Report

This project involved updating processing traffic characteristics data using a series of quality control and analytical programs to produce an estimate of the following parameters of interest; 1) average daily traffic, 2) percent trucks, 3) percent trucks classified as heavy/coal, 4) axles per truck, 5) axles per heavy/coal truck, 6) ESALs per truck axle, 7) ESALs per heavy/coal truck axle, and 8) total ESALs. ESAL estimation parameters used WIM data collected during 2007, 2011, and 2012–2013 (representing 41 stations); and classification data collected in 2010, 2011 and 2012 (representing 1,669 stations).

Computer programs used to process classification data, process weight …

2d Cine Dense With Low Encoding Frequencies Accurately Quantifies Cardiac Mechanics With Improved Image Characteristics, Gregory J. Wehner, Jonathan D. Grabau, Jonathan D. Suever, Christopher M. Haggerty, Linyuan Jing, David Powell, Sean M. Hamlet, Moriel H. Vandsburger, Xiaodong Zhong, Brandon K. Fornwalt

Biomedical Engineering Faculty Publications

BACKGROUND: Displacement Encoding with Stimulated Echoes (DENSE) encodes displacement into the phase of the magnetic resonance signal. The encoding frequency (k_e) maps the measured phase to tissue displacement while the strength of the encoding gradients affects image quality. 2D cine DENSE studies have used a k_e of 0.10 cycles/mm, which is high enough to remove an artifact-generating echo from k-space, provide high sensitivity to tissue displacements, and dephase the blood pool. However, through-plane dephasing can remove the unwanted echo and dephase the blood pool without relying on high k_e. Additionally, the high sensitivity comes …

Chemical Processing Cell With Nanostructured Membranes, Dibakar Bhattacharyya, Scott R. Lewis, Saurav Datta

Chemical and Materials Engineering Faculty Patents

A chemical processing cell includes an upstream membrane and a downstream membrane. The upstream membrane generates a first reaction product. The downstream membrane converts the first reaction product to a second reaction product.

Nitrogen Fertilizer Composition And Method To Improve Detection And Lessen The Explosive Potential Of Nitrogen-Based Fertilizers, Darrell Neal Taulbee

Center for Applied Energy Research Faculty Patents

A nitrogen fertilizer composition includes urea and a nitrate-based fertilizer such as ammonium nitrate, calcium ammonium nitrate and mixtures of ammonium nitrate and calcium ammonium in which the urea and total nitrogen are at concentrations of 20 percent by weight or greater and the concentration of ammonium nitrate is at 30 percent or greater by weight. One or both of the urea and nitrate-based fertilizer are coated with an agriculturally compatible material. The fertilizer composition provides significant nitrate nitrogen for legitimate agricultural use yet is not amenable to the production of an explosive by crushing or by aqueous extraction. A …

Electrode Kinetics Of Vanadium Flow Batteries: Contrasting Responses Of VIi-VIii And VIv-VV To Electrochemical Pretreatment Of Carbon, A. Bourke, M. A. Miller, R. P. Lynch, Xin Gao, James Landon, J. S. Wainright, R. F. Savinell, D. N. Buckley

Center for Applied Energy Research Faculty and Staff Publications

Electrochemical impedance spectroscopy and cyclic voltammetry were used to investigate the electrode kinetics of V^II-V^III and V^IV-V^V in H₂SO₄ on glassy carbon, carbon paper, carbon xerogel, and carbon fibers. It was shown that, for all carbon materials investigated, the kinetics of V^II-V^III is enhanced by anodic, and inhibited by cathodic, treatment of the electrode; in contrast, the kinetics of V^IV-V^V is inhibited by anodic, and enhanced by cathodic, treatment. The potential region for each of these effects varied only slightly with carbon material. Rate constants …

Nanowire Cds-Cdte Solar Cells With Molybdenum Oxide As Contact, Hongmei Dang, Vijay P. Singh

Electrical and Computer Engineering Faculty Publications

Using a 10 nm thick molybdenum oxide (MoO_3-x) layer as a transparent and low barrier contact to p-CdTe, we demonstrate nanowire CdS-CdTe solar cells with a power conversion efficiency of 11% under front side illumination. Annealing the as-deposited MoO₃ film in N₂ resulted in a reduction of the cell's series resistance, from 9.97 Ω/cm² to 7.69 Ω/cm², and increase in efficiency from 9.9% to 11%. Under illumination from the back, the MoO_3-x/Au side, the nanowire solar cells yielded J_sc of 21 mA/cm² and efficiency of 8.67%. Our results demonstrate …

Commercial Truck Parking And Other Safety Issues, Jerry G. Pigman, Graham Winchester, Nathaniel Swallom

Kentucky Transportation Center Research Report

Commercial truck parking is a safety issue, since trucks are involved in approximately 10% of all fatal accidents on interstates and parkways in Kentucky. Drivers experience schedule demands and long hours on the road, yet they cannot easily determine available parking locations. The objective of this study was to identify information related to parking demand, locations with documented or potential safety issues, and potential countermeasures. The literature review indicated substantial research has been done on commercial vehicle parking, and works have outlined the necessary facilities to accommodate trucks before drivers exceed their allowable hours of driving. Attention to commercial truck …

Best Practices For The Implementation Of The Real Id Act, Jennifer R. Walton, Candice Y. Wallace, Andrew Martin

Kentucky Transportation Center Research Report

The REAL ID Act specifies the minimum standards that must be used to produce and issue driver’s license and identification cards that are REAL ID compliant. Beginning in 2020, if a person does not possess a form of identification that meets REAL ID standards they will not be able to board an aircraft that is regulated by the Federal Aviation Administration. Currently, of the 56 states and jurisdictions required to implement the REAL ID Act, only 23 are in compliance. Although the Commonwealth of Kentucky has not yet implemented the REAL ID Act, an extension allowing Federal agencies to accept …

Identifying Significant Environmental Features Using Feature Recognition, Megan White, Junfeng Zhu, Benjamin L. Blandford, Ted H. Grossardt

Kentucky Transportation Center Research Report

The Department of Environmental Analysis at the Kentucky Transportation Cabinet has expressed an interest in feature-recognition capability because it may help analysts identify environmentally sensitive features in the landscape, including those relating to historic preservation, archaeology, endangered species habitat, and geology. LIDAR Analyst and Feature Analyst are a pair of geoprocessing software packages that have been developed by Textron Systems. Using this software, users can use LIDAR data to identify finely-scaled user-specified features. The software’s automated feature extraction saves time that might otherwise be spent manually analyzing images and digitizing features.

This report explores the capabilities and accuracy of this …

Heterogeneous Oxidation Of Catechol, Elizabeth A. Pillar, Ruixin Zhou, Marcelo I. Guzman

Chemistry Faculty Publications

Natural and anthropogenic emissions of aromatic hydrocarbons from biomass burning, agro-industrial settings, and fossil fuel combustion contribute precursors to secondary aerosol formation (SOA). How these compounds are processed under humid tropospheric conditions is the focus of current attention to understand their environmental fate. This work shows how catechol thin films, a model for oxygenated aromatic hydrocarbons present in biomass burning and combustion aerosols, undergo heterogeneous oxidation at the air–solid interface under variable relative humidity (RH = 0–90%). The maximum reactive uptake coefficient of O₃(g) by catechol γ_O3 = (7.49 ± 0.35) × 10^–6 occurs for …

Structural And Functional Characterization Of A Lytic Polysaccharide Monooxygenase With Broad Substrate Specificity, Anna S. Borisova, Trine Isaksen, Maria Dimarogona, Abhishek A. Kognole, Geir Mathiesen, Anikó Várnai, Åsmund K. Røhr, Christina M. Payne, Morten Sørlie, Mats Sandgren, Vincent G. H. Eijsink

Chemical and Materials Engineering Faculty Publications

The recently discovered lytic polysaccharide monooxygenases (LPMOs) carry out oxidative cleavage of polysaccharides and are of major importance for efficient processing of biomass. NcLPMO9C from Neurospora crassa acts both on cellulose and on non-cellulose β-glucans, including cellodextrins and xyloglucan. The crystal structure of the catalytic domain of NcLPMO9C revealed an extended, highly polar substrate-binding surface well suited to interact with a variety of sugar substrates. The ability of NcLPMO9C to act on soluble substrates was exploited to study enzyme-substrate interactions. EPR studies demonstrated that the Cu²⁺ center environment is altered upon substrate binding, whereas isothermal titration …

Electronic Signatures: Review And Analysis, Bryan Gibson

Kentucky Transportation Center Technical Assistance Report

Electronic signatures, or e-signatures, are an increasingly ubiquitous component of a rapidly digitizing world. Compared to traditional paper signature, e-signatures have emerged as a viable, potentially more efficient method of entering into a contract. An e-signature can be thought of as an electronic symbol or marking associated with the signer. It acts as a signature and functions in lieu of a manual paper signature. This technical assistance report briefly reviews relevant Kentucky statutes and guidelines regarding e-signatures and public recordkeeping as well as applicable federal law. Following this, the report presents conclusions and points for continued discussion. Relevant statues and …

Petrology, Palynology, And Geochemistry Of Gray Hawk Coal (Early Pennsylvanian, Langsettian) In Eastern Kentucky, Usa, James C. Hower, Courtland F. Eble, Jennifer M. K. O'Keefe, Shifeng Dai, Peipei Wang, Panpan Xie, Jingjing Liu, Colin R. Ward, David French

Center for Applied Energy Research Faculty and Staff Publications

This study presents recently collected data examining the organic petrology, palynology, mineralogy and geochemistry of the Gray Hawk coal bed. From the Early Pennsylvanian, Langsettian substage, Gray Hawk coal has been mined near the western edge of the eastern Kentucky portion of the Central Appalachian coalfield. While the coal is thin, rarely more than 0.5-m thick, it has a low-ash yield and a low-S content, making it an important local resource. The Gray Hawk coal palynology is dominated by Lycospora spp., and contains a diverse spectrum of small lycopods, tree ferns, small ferns, calamites, and gymnosperms. The maceral assemblages show …

Analysis Of Traffic Crash Data In Kentucky (2010-2014), Eric R. Green, Kenneth R. Agent, Jerry G. Pigman, Michael A. Fields

Kentucky Transportation Center Research Report

This report documents an analysis of traffic crash data in Kentucky for the years of 2010 through 2014. A primary objective of this study was to determine average crash statistics for Kentucky highways. Rates were calculated for various types of highways and for counties and cities. Difference criteria were used for exposure.

Evaluation Of Deterioration Of Structural Concrete Due To Chloride Intrusion And Other Damaging Mechanisms, Sudhir Palle, Brian K. Howell, Theodore Hopwood Ii, Bobby W. Meade

Kentucky Transportation Center Research Report

Kentucky's bridges continue to age and experience distress. The intrusion of chlorides into concrete remains the primary mechanism for deterioration. It leads to reinforcing steel corrosion that damages the adjoining concrete structure. This study found problematic chloride concentrations in Kentucky concrete bridge elements (decks, pier caps, abutments). Chloride levels have been found at concentrations sufficient to initiate reinforcing steel corrosion. In some cases, chloride concentrations were sufficient to cause accelerated corrosion and produce major section loss of reinforcing steel. Advanced stages of corrosion such as these typically require costly repairs and maintenance to extend the service life of bridges.

Field …

Work Vehicle Warning Lights: Color Options And Effectiveness, Brian K. Howell, Jerry G. Pigman, Kenneth R. Agent

Kentucky Transportation Center Research Report

KTC reviewed existing regulations, guidance, and practices to assess the Kentucky Transportation Cabinet’s warning lights program on highway work vehicles. The Kentucky Revised Statutes categorizes KYTC vehicles as “public safety vehicles” and requires their use of amber lights. Because the use of red can be confused with emergency vehicles, KYTC prohibits the use of red on work vehicles. At the national level, standards for warning light colors do not exist. Rather, AASHTO provides guidance on roadway operations equipment and recommends the use of amber and white lights as the primary warning light colors for highway vehicles. AASHTO guidance also prescribes …

Online Driver’S License Renewal, Valerie J. Keathley, Andrew Martin, Jennifer R. Walton

Kentucky Transportation Center Research Report

The Kentucky Department of Vehicle Regulation is exploring the possibility of developing and implementing online driver’s license renewal. The objective of this project was to: 1) evaluate online driver’s license and REAL ID renewal programs in other states to identify best practices; 2) examine two options to institute online renewal; and 3) identify what legislative changes would be required in Kentucky to authorize an online renewal program. KTC surveyed 25 states with online license renewal programs in place, and received responses from 14 states. Survey respondents indicated that online renewal is more efficient, improves customer service, cuts down on foot …

Analysis Of Historical Travel Time Data, Mei Chen, Xu Zhang, Eric R. Green

Kentucky Transportation Center Research Report

Travel speed is a critical piece of information for many applications. The Moving Ahead for Progress in the 21st Century Act (MAP-21) states that calculating travel speeds illuminates the performance of the nation’s highway system. New technologies make the collection of speed data more straightforward than ever. Private vendors collect and sell this data, and KTC purchased speed data for 2010-2013 from NAVTEQ (now HERE). The main objectives of the research were to:

• Evaluate private sector speed data and its use in generating travel time based performance measures
• Create a mechanism to integrate this speed data with networks maintained by …

Water Expert: A Conceptualized Framework For Development Of A Rule-Based Decision Support System For Distribution System Decontamination, J. L. Gutenson, A. N. S. Ernest, J. R. Fattic, L. E. Ormsbee, A. A. Oubeidillah, X. Zhang

Civil Engineering Faculty Publications

Significant drinking water contamination events pose a serious threat to public and environmental health. Water utilities often must make timely, critical decisions without evaluating all facets of the incident. The data needed to enact informed decisions are inevitably dispersant and disparate, originating from policy, science, and heuristic contributors. Water Expert is a functioning hybrid decision support system (DSS) and expert system framework that emphasizes the meshing of parallel data structures in order to expedite and optimize the decision pathway. Delivered as a thin-client application through the user's web browser, Water Expert's extensive knowledgebase is a product of inter-university collaboration …

Noncontact Diffuse Correlation Tomography Of Human Breast Tumor, Lian He, Yu Lin, Chong Huang, Daniel Irwin, Margaret M. Szabunio, Guoqiang Yu

Biomedical Engineering Faculty Publications

Our first step to adapt our recently developed noncontact diffuse correlation tomography (ncDCT) system for three-dimensional (3-D) imaging of blood flow distribution in human breast tumors is reported. A commercial 3-D camera was used to obtain breast surface geometry, which was then converted to a solid volume mesh. An ncDCT probe scanned over a region of interest on the mesh surface and the measured boundary data were combined with a finite element framework for 3-D image reconstruction of blood flow distribution. This technique was tested in computer simulations and in vivo human breasts with low-grade carcinoma. Results from computer simulations …

Synthesis Of Public-Private Partnerships: Potential Issues And Best Practices For Program And Project Implementation And Administration, Bryan Gibson, Candice Y. Wallace, Roy E. Sturgill

Kentucky Transportation Center Research Report

Public-private partnerships (P3s or PPPs) offer an innovative procurement method for the public sector. P3s involve collaborations between the public and private sectors to finance, develop or maintain transportation infrastructure. In an era of shrinking budgets and increased demand for transportation infrastructure, the Kentucky Transportation Cabinet (KYTC) can analyze experiences in other states to determine a best path forward on the issue of P3s. The objective of this study is to examine benefits and drawbacks of using P3s, current trends and past performance of P3s in the procurement of state transportation infrastructure projects, and common legislative statutes relating to P3s. …