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Full-Text Articles in Engineering
Intragranular Nanocomposite Powders As Building Blocks For Ceramic Nanocomposites, Ryan D. Dempsey, Xiaoqing He, Jonathan A. Scott, David W. Lipke
Intragranular Nanocomposite Powders As Building Blocks For Ceramic Nanocomposites, Ryan D. Dempsey, Xiaoqing He, Jonathan A. Scott, David W. Lipke
Materials Science and Engineering Faculty Research & Creative Works
A powder-based bottom-up processing scheme is introduced for the production of ceramic nanocomposites. Internal displacement reactions between solid solution powders and metallic reactants proceeding via gaseous intermediates are utilized to generate nanostructured building blocks for the synthesis of ceramic nanocomposites. Subsequent rapid sintering results in ceramic nanocomposites, whose microstructures are inherited from the building blocks. This processing scheme is demonstrated for the production of titanium carbide nanocomposites featuring up to 28 wt.% intragranular tungsten inclusions derived from titanium-tungsten mixed carbide powders. Heat treatment of mixed carbide powders in evacuated ampoules containing titanium sponge and iodine at 1000°C for 24 h …
Fusion Welding Of Refractory Metals And Zrb2-Sic-Zrc Ceramics, Jecee D. Jarman, William Fahrenholtz, Greg Hilmas, Jeremy Lee Watts, Tieshu Huang
Fusion Welding Of Refractory Metals And Zrb2-Sic-Zrc Ceramics, Jecee D. Jarman, William Fahrenholtz, Greg Hilmas, Jeremy Lee Watts, Tieshu Huang
Materials Science and Engineering Faculty Research & Creative Works
Molybdenum and a molybdenum alloy were fusion welded to ZrB2-based ceramics to determine if the electrical and thermal properties of the metals and ceramics affected their weldability. Commercial ceramic powders were hot pressed, machined into coupons, and preheated to 1600 °C before joining the ceramics to commercial metals using plasma arc welding. Weldability varied as indicated by the range of porosity observed within the fusion zones. Measured thermal and electrical properties appeared to have little to no effect on the weldability of metal-ceramic welds despite the large range of values measured across each property. Differences in melting temperatures between metal …
High-Entropy Boride–Carbide Ceramics By Sequential Boro/Carbothermal Synthesis, Steven M. Smith, Lun Feng, William Fahrenholtz, Greg Hilmas, Tieshu Huang
High-Entropy Boride–Carbide Ceramics By Sequential Boro/Carbothermal Synthesis, Steven M. Smith, Lun Feng, William Fahrenholtz, Greg Hilmas, Tieshu Huang
Materials Science and Engineering Faculty Research & Creative Works
A dual-phase high-entropy boride (HEB)/carbide (HEC) ceramic with a fine grain size was synthesized by a sequential boro/carbothermal process. In the first step, an Hf–Nb–Ta–Ti–Zr-containing carbide was synthesized by a carbothermal reduction of oxides followed by the reaction of the carbide with B4C and ZrH2 to convert part of the carbide to boride. The resulting composition was ∼29 vol% HEB with an average grain size of ∼1.1 μm. Solid solution formation occurred at the densification temperature of 1900°C resulting in a relative density higher than 99%. The Vickers hardness was 26.5 ± 1.4 GPa. This is the first report of …
Mechanical Properties Of Fusion Welded Ceramics In The Sic-Zrb2 And Sic-Zrb2-Zrc Systems, Jecee D. Jarman, William Fahrenholtz, Greg Hilmas, Jeremy Lee Watts, Derek S. King
Mechanical Properties Of Fusion Welded Ceramics In The Sic-Zrb2 And Sic-Zrb2-Zrc Systems, Jecee D. Jarman, William Fahrenholtz, Greg Hilmas, Jeremy Lee Watts, Derek S. King
Materials Science and Engineering Faculty Research & Creative Works
Mechanical properties of welded SiC-ZrB2 and SiC-ZrB2-ZrC ceramics were measured up to 1700 °C. Commercial powders were hot pressed, machined into coupons, and preheated to 1600 °C before joining the ceramics using either tungsten inert gas welding or plasma arc welding. Toughness of the parent materials was 3–4 MPa*m1/2 which decreased after welding to 2–2.5 MPa*m1/2. Strength of the SiC-ZrB2-ZrC parent material was ~700 MPa at 25 °C, ~300 MPa at 1700 °C, and retained 40–60% of this strength once welded. Strength of the SiC-ZrB2 parent material was ~600 MPa at 25 °C and 1700 °C and retained 20–30% of …
The Role Of Microstructure On High-Temperature Oxidation Behavior Of Hafnium Carbide, Jonathan A. Scott, Xiaoqing He, David W. Lipke
The Role Of Microstructure On High-Temperature Oxidation Behavior Of Hafnium Carbide, Jonathan A. Scott, Xiaoqing He, David W. Lipke
Materials Science and Engineering Faculty Research & Creative Works
Microstructure development of the products formed upon oxidation of hafnium carbide (HfCx, x = 0.65, 0.81, or 0.94) at 1300°C and 0.8 mbar oxygen pressure was investigated using Raman spectroscopy, X-ray diffraction, electron microscopy, and electron energy-loss spectroscopy. For all specimens a multilayered oxide scale was observed featuring an outermost porous hafnia layer and an interlayer adjacent to the parent carbide containing hafnia interspersed with carbon. The outermost hafnia features coarse pores presumably formed during initial stages of oxidation to allow rapidly evolving gaseous products to escape from the oxidation front. As the oxidation scale thickens, diffusional resistance results in …
Freeze-Form Extrusion Fabrication Of Functionally Graded Material Composites Using Zirconium Carbide And Tungsten, Ang Li, Aaron S. Thornton, Bradley K. Deuser, Jeremy Lee Watts, Ming-Chuan Leu, Greg Hilmas, Robert G. Landers
Freeze-Form Extrusion Fabrication Of Functionally Graded Material Composites Using Zirconium Carbide And Tungsten, Ang Li, Aaron S. Thornton, Bradley K. Deuser, Jeremy Lee Watts, Ming-Chuan Leu, Greg Hilmas, Robert G. Landers
Materials Science and Engineering Faculty Research & Creative Works
Ultra-high-temperature ceramics are being investigated for future use in aerospace applications due to their superior thermo-mechanical properties, as well as their oxidation resistance, at temperatures above 2000⁰C. However, their brittleness makes them susceptible to thermal shock failure. As graded composites, components fabricated as functionally-graded materials (FGMs) can combine the superior properties of ceramics with the toughness of an underlying refractory metal. This paper discusses the grading of two materials through the use of a Freeze-form Extrusion Fabrication (FEF) system to build FGM parts consisting of zirconium carbide (ZrC) and tungsten (W). Aqueous-based colloidal suspensions of ZrC and W were developed …