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A Reference High-Pressure Co2 Adsorption Isotherm For Ammonium Zsm-5 Zeolite: Results Of An Interlaboratory Study, H. G.T. Nguyen, L. Espinal, R. D. Van Zee, M. Thommes, B. Toman, M. S.L. Hudson, E. Mangano, S. Brandani, D. P. Broom, M. J. Benham, K. Cychosz, P. Bertier, F. Yang, B. M. Krooss, R. L. Siegelman, M. Hakuman, K. Nakai, A. D. Ebner, L. Erden, J. A. Ritter, A. Moran, Orhan Talu, Y. Huang, K. S. Walton, P. Billemont, G. De Weireld
A Reference High-Pressure Co2 Adsorption Isotherm For Ammonium Zsm-5 Zeolite: Results Of An Interlaboratory Study, H. G.T. Nguyen, L. Espinal, R. D. Van Zee, M. Thommes, B. Toman, M. S.L. Hudson, E. Mangano, S. Brandani, D. P. Broom, M. J. Benham, K. Cychosz, P. Bertier, F. Yang, B. M. Krooss, R. L. Siegelman, M. Hakuman, K. Nakai, A. D. Ebner, L. Erden, J. A. Ritter, A. Moran, Orhan Talu, Y. Huang, K. S. Walton, P. Billemont, G. De Weireld
Chemical & Biomedical Engineering Faculty Publications
© 2018, The Author(s). This paper reports the results of an international interlaboratory study led by the National Institute of Standards and Technology (NIST) on the measurement of high-pressure surface excess carbon dioxide adsorption isotherms on NIST Reference Material RM 8852 (ammonium ZSM-5 zeolite), at 293.15 K (20 °C) from 1 kPa up to 4.5 MPa. Eleven laboratories participated in this exercise and, for the first time, high-pressure adsorption reference data are reported using a reference material. An empirical reference equation nex=d(1+exp[(-ln(P)+a)/b])c, [nex-surface excess uptake (mmol/g), P-equilibrium pressure (MPa), a = −6.22, b = 1.97, c = 4.73, and d …
Pure Component Adsorption Of Methane, Ethylene, Propylene And Carbon Dioxide In Silicalite, Qianqian Zhou
Pure Component Adsorption Of Methane, Ethylene, Propylene And Carbon Dioxide In Silicalite, Qianqian Zhou
ETD Archive
Adsorption isotherms are measured for pure methane, ethylene, propylene and carbon dioxide in silicalite. Isotherm data are collected using a volumetric method at three different temperatures of 10C, 35C and 65C at pressure up to 100psi. The Virial equation and Langmuir equation have been applied to represent excess amount adsorbed in each pure component system. The binary adsorption equilibrium for various mixtures are predicted from the pure component adsorption data, using the Ideal Adsorption Solution Theory (IAST)