Engineering Commons^™

Defect-Related Optical Absorption Bands In Cdsip2 Crystals, Elizabeth M. Scherrer, Brant T. Kananen, Eric M. Golden, F. Kenneth Hopkins, Kevin T. Zawilski, Peter G. Schunemann, Larry E. Halliburton, Nancy C. Giles

Faculty Publications

When used as optical parametric oscillators, CdSiP₂ crystals generate tunable output in the mid-infrared. Their performance, however, is often limited by unwanted optical absorption bands that overlap the pump wavelengths. A broad defect-related optical absorption band peaking near 800 nm, with a shoulder near 1 µm, can be photoinduced at room temperature in many CdSiP₂ crystals. This absorption band is efficiently produced with 633 nm laser light and decays with a lifetime of ∼0.5 s after removal of the excitation light. The 800 nm band is accompanied by a less intense absorption band peaking near 1.90 µm. Data …