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Full-Text Articles in Engineering

Synthesis Of Vo2/Poly(Mma-Co-Dmemuabr) Antimicrobial/Thermochromic Dual-Functional Coating And Reactivity Ratios Study, Yixian Liu Nov 2019

Synthesis Of Vo2/Poly(Mma-Co-Dmemuabr) Antimicrobial/Thermochromic Dual-Functional Coating And Reactivity Ratios Study, Yixian Liu

Electronic Thesis and Dissertation Repository

Antimicrobial/thermochromic dual-functional coatings were successfully synthesized via UV-curing. The quaternary ammonium compound (QAC) N,N-dimethyl-N-{2-[(2-methylprop-2-enoyl)oxy]ethyl}undecane-1-aminium bromide (dMEMUABr) was synthesized and copolymerized with methyl methacrylate (MMA) for antimicrobial properties. Vanadium oxide (VO2) nanoparticles were evenly dispersed within the coating, providing thermochromic properties. The dual-functional coating showed high luminous transmittance (Tlum(25°C) =36.1 %) and solar energy modulation ( Tsol=5.8 %). 90.3 % of bacteria reduction was observed against Escherichia coli within 24 h contact. To further understand the sequence distribution of the copolymer poly(MMA-co-dMEMUABr), the reactivity ratios of MMA and dMEMUABr monomer were studied and compared under thermal …


Progress Toward Durable Icephobic Materials, Matthew J. Coady Oct 2019

Progress Toward Durable Icephobic Materials, Matthew J. Coady

Electronic Thesis and Dissertation Repository

Ice accumulation is a major engineering challenge in many fields including aerospace, power generation, transportation, and infrastructure. A variety of solutions are being researched to address this challenge. Perhaps the most promising method of combating ice accumulation is by applying coatings with low values of interfacial ice adhesion strength, τice. Icephobic materials are those with ice adhesion below 100 kPa, and it has been shown that passive delamination can occur on surfaces with τice below 20 kPa. While various low adhesion surfaces have been prepared, durability concerns pervade applications where surfaces experience repeated icing or freeze-thaw cycles, …


Enhanced Carbon Fiber-Epoxy Composites For Rowing Racing Shells, Rayehe Samimi Jul 2019

Enhanced Carbon Fiber-Epoxy Composites For Rowing Racing Shells, Rayehe Samimi

Electronic Thesis and Dissertation Repository

This thesis investigates the thermomechanical properties of two commercial composites using carbon fiber reinforcement in epoxy resins for manufacturing marine based rowing racing shells. The main goal of this project was to investigate how to control the resin properties and curing temperatures to improve the final product properties including adhesion, toughness modulus and tensile strength. Moreover, an efficient curing process was required by our supporting company to be used at low temperatures to enhance the curing characteristics and to provide improved mechanical properties. Accordingly, the current research tries to improve the manufacturing curing process and build up high performance structure …


A Ph-Sensitive Delivery System For The Prevention Of Dental Caries Using Salivary Proteins, Yi Zhu May 2019

A Ph-Sensitive Delivery System For The Prevention Of Dental Caries Using Salivary Proteins, Yi Zhu

Electronic Thesis and Dissertation Repository

Dental caries remains one of the most common chronic diseases worldwide. Salivary proteins such as histatins have demonstrated biological functions directly related to tooth homeostasis and prevention of dental caries. However, histatins are susceptible to the high proteolytic activities in the oral environment. Therefore, pH-sensitive chitosan nanoparticles (CNs) have been proposed as potential carriers to target major oral diseases that occur under acidic conditions (e.g. dental caries and dental erosion). Four different types of chitosan polymers were investigated and the optimized CNs successfully loaded histatin 3 and released it selectively under acidic conditions. Through loading the survival time of histatin …