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High Resolution Laser Absorption Spectroscopy Of Ozone Near 1129.4 Cm-1, Lawrence N. Majorana Dec 1980

High Resolution Laser Absorption Spectroscopy Of Ozone Near 1129.4 Cm-1, Lawrence N. Majorana

Physics Theses & Dissertations

A Beer's Law experiment was performed with a tunable laser to determine self broadened line shape parameters of one infrared absorption ozone line in the v1 band for ten pressures from 0.26 to 6.29 Torr at 285K. SO2 line positions were used for wavelength calibration. Line shapes were iteratively fitted to the Voigt function at a Doppler width of 29.54 MHz (HWHM) resulting in values for the integrated line• strength, ( S), of (0.144 +/- 0.007 ) x ·10-20 cm-1/molecule cm-2, line center frequency, (υο) of 1129.426 cm-1 and the Lorentzian contributions to half width, (α …


Sound Absorption In N2-H2O Gas Mixtures At Elevated Temperatures, Roger W. Meredith Dec 1980

Sound Absorption In N2-H2O Gas Mixtures At Elevated Temperatures, Roger W. Meredith

Physics Theses & Dissertations

Sound absorption measurements were conducted in N2 -H2O gas mixtures at 297, 343, and 387 Kelvin to determine the location of the vibrational relaxation peak of nitrogen on the frequency/pressure, (f/P), axis as a function of humidity and temperature. At low humidities the best fit of the data is to a linear relationship between (f/P)max and humidity (h) yields a slope of 1 .84 X 104 Hz/ atm mole fraction at all three temperatures. The slope is the same as that reported by Zuckerwar and Griffin (2.00 X 104 Hz/atm mole fraction) but is …