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Full-Text Articles in Engineering

First-Principles Study Of The Electric Field Effect On The Water-Adsorbed Rutile Titanium Dioxide Surface, Abraham L. Hmiel Jan 2014

First-Principles Study Of The Electric Field Effect On The Water-Adsorbed Rutile Titanium Dioxide Surface, Abraham L. Hmiel

Legacy Theses & Dissertations (2009 - 2024)

TiO2 is a semiconducting material that has been used extensively in many industrial applications, and recently has become a candidate for photocatalytic water splitting, fuel cell anode support materials, sensors, and other novel nanodevices. The interface of TiO2 with water, historically well-studied but still poorly understood, presents a ubiquitous environmental challenge towards the ultimate practical usefulness of these technologies. Ground-state density functional theory (DFT) calculations studying the characteristics of molecular adsorption on model surfaces have been studied for decades, showing constant improvement in the description of the energetics and electronic structure at interfaces. These simulations are invaluable in the …


Comparative Study On The Use Of Coherent Radar-Derived Electric Fields Vs. Statistical Electric Fields For The Initialization Of A High-Latitude Ionospheric Model, Christopher M. Hogue Jun 2004

Comparative Study On The Use Of Coherent Radar-Derived Electric Fields Vs. Statistical Electric Fields For The Initialization Of A High-Latitude Ionospheric Model, Christopher M. Hogue

Theses and Dissertations

The structure and time development of the magnetosphere-ionosphere system have significant impacts on the Air Force and its mission. Specifically, an accurate knowledge of ionospheric plasma densities is important for the operation of many Air Force systems. This research analyzes plasma density structure development through comparing two distinct electric field models. The two models compared here are a commonly used statistical model created by Heppner and Maynard 1987, and a more recently developed model using real-time coherent radar measurements from the SuperDARN radar network. Ionospheric simulations were run using Utah State University s Time-Dependent Ionospheric Model (TDIM) with the two …


Space Charge Structure Of A Glow Discharge In The Presence Of A Longitudinal Inhomogeneity, Frank A. Tersigni Mar 1999

Space Charge Structure Of A Glow Discharge In The Presence Of A Longitudinal Inhomogeneity, Frank A. Tersigni

Theses and Dissertations

A survey of space charge structures arising due to inhomogeneities in glow discharges was conducted. Space charge structures associated with tube geometries, the cathode sheath, striations, and shockwaves were examined. Space charge effects on the Electron Energy Distribution Function (EEDF) were explored for a geometric inhomogeneity using an approximate nonlocal solution to the one dimensional Boltzmann equation after Godyak. The approximate solution partially captured qualitative aspects of space charge effects on the EEDF. Simplification of collisional effects and adaptation of an approximate electric field restricted quantitative comparisons with experimental data. It is recommended that any future analysis of space charge …