Engineering Commons^™

Functional Nanocomposites From Self-Assembly Of Block Copolymers With Nanoparticles, Xinyu Wang

Doctoral Dissertations

This dissertation studied the proper distribution and location control of nanoparticles (NPs) within block copolymer (BCP) templates. A facile ligand exchange reaction was introduced for the hydrophilic magnetic NPs (MNPs) that are readily dispersed in polar solvents with outstanding stability. Small molecule ligands were selected to associate strongly with particle surfaces, provide hydrophilic termini for polarity matching with polar solvents, and offer the potential for hydrogen-bonding interactions to facilitate NP incorporation into polymers. Areal ligand densities of NPs indicated a significant increase in the ligand coverage after the exchange reaction. Hydrophilic MNPs were shown to drive the self-assembly of BCPs …

Introducing The Newton-Poisson-Brillouin Model In The Quest For Plasmons In Metallic Carbon Nanotubes, Richard P. Zannoni

Doctoral Dissertations

A new method is presented to model carbon nanotubes (CNT) of micron length. The Newton-Poisson-Brillouin (NPB) model uses Newtonian physics to model the interaction of a population of thermally excited quasi-particles. The NPB model is self-consistent with Poisson’s equation, and the quasi-particles are confined to the CNT’s band structure. In this work, we explore the parameter space of the model.

Engineering Surface Functionality Of Nanoparticles For Biological Applications, Yi-Cheun Yeh

Doctoral Dissertations

Engineering the surface functionality of nanomaterials is the key to investigate the interactions between nanomaterials and biomolecules for potent biological applications such as therapy, imaging and diagnostics. My research has been orientted to engineer both of the surface monolayers and core materials to fabricate surface-functionalized nanomaterials through the synergistic multidisciplinary approach that combine organic chemistry, materials science and biology. This thesis illustrates the design and synthesis of the surface-funcitonalized quantum dots (QDs) and gold nanoparticles (AuNPs) for the fundamental studies and practical applications. For QDs, A new class of cationic QDs with quaternary ammonium derivatives was synthesized to provide permanent …

Patterning And Mechanical Analysis Of Fiber-Based Materials, Samuel A. Pendergraph

Doctoral Dissertations

The ability to define and control the topography of a surface has been studied extensively due to its importance in a wide variety of applications. The control of a non-planar topography would be very valuable since a number of structures that are pervasive in artificial applications (e.g. fibers, lenses) are curved interfaces. This potential of enabling applications that incorporate non-planar geometries was the motivation for this thesis. The first study of this thesis comprises the study of patterning the circumference of micrometer sized fibers. Specifically, a unique technique was described to pattern the fiber with a periodic array of colloids. …

The Discovery And Study Of Fluvirucin B1 Polyketide Synthase, Tsung-Yi Lin

Doctoral Dissertations

Rapidly decreasing numbers of viable therapeutic leads in the pharmaceutical pipeline demand new, sustainable methods for improved drug discovery and development. Despite vast improvements in de novo drug design and target recognition, Nature remains the richest source of small molecule therapeutics. Among many natural products, polyketides are not only the most promising ones for developing new antibiotic leads, but also exhibit unusually high therapeutic value ranging from clinical use as anticancer, antiviral, and immunosuppressant drugs. Modular polyketide synthases (PKSs) are dedicated nano-machinery that can be manipulated to produce a structurally diverse library for drug discovery programs. The ability to manipulate …

Defining, Evaluating, And Improving The Process Of Verifying Patient Identifiers, Junghee Jo

Doctoral Dissertations

Patient identification errors are a major cause of medication errors. During medication administration, failure to identify patients correctly can lead to patients receiving incorrect medications, perhaps resulting in adverse drug events and even death. Most medication error studies to date have focused on reporting patient misidentification statistics from case studies, on classifying types of patient identification errors, or on evaluating the impact of technology on the patient identification process, but few have proposed specific strategies or guidelines to decrease patient identification errors. This thesis aims to improve the verification of patient identifiers (VPI) process by making three key contributions to …

Studies On The Wrinkling Of Thin Polymer Films Floating On Liquid, Kamil B. Toga

Doctoral Dissertations

This dissertation aims to broaden our understanding on wrinkling instabilities occurring on floating polymeric sheets, and tries to establish innovative methods that exploit these patterns in studies on material behavior and interfacial phenomena. We will address three major topics in this thesis including, i) characterization of the conditions required to buckle an annular disc, ii) characterization of wrinkles occurring around a droplet/bubble placed on a membrane that is kept taut at the liquid-air interface, and iii) using wrinkling patterns as a probe to understand the interfacial behavior and dynamics of ultrathin films. The first project in this thesis is about …

Reliable And Efficient Multithreading, Tongping Liu

Doctoral Dissertations

The advent of multicore architecture has increased the demand for multithreaded programs. It is notoriously far more challenging to write parallel programs correctly and efficiently than sequential ones because of the wide range of concurrency errors and performance problems. In this thesis, I developed a series of runtime systems and tools to combat concurrency errors and performance problems of multithreaded programs. The first system, Dthreads, automatically ensures determinism for unmodified C/C++ applications using the pthreads library without requiring programmer intervention and hardware support. Dthreads greatly simplifies the understanding and debugging of multithreaded programs. Dthreads often matches or even exceeds the …

Molecular Engineering Strategies For The Design And Synthesis Of New Organic Photovoltaic Materials, Paul J. Homnick

Doctoral Dissertations

Dramatic improvements in organic photovoltaic device efficiency can be obtained by optimizing spectral absorbance and frontier molecular orbital (FMO) energies, increasing solid state exciton/charge mobility, and utilizing p-/n-type nanoarchitecture. Combining all of these properties into a new material presents a considerable synthetic challenge because potential commercial applications require materials that are high-performance and inexpensive. Thus, it is advantageous to design new materials using a versatile, modular synthetic approach that allows each design criterion to be engineered individually, in a synthetically efficient manner. Several strategies were successfully pursued using simple interchangeable electron donor and acceptor components as functional modules, which …

Creasing Instability Of Hydrogels And Elastomers, Dayong Chen

Doctoral Dissertations

CREASING INSTABILITY OF HYDROGELS AND ELASTOMERS MAY 2014 DAYONG CHEN, B.S., TIANJIN UNIVERISTY M.S., TIANJIN UNIVERSITY M.S., UNIVERSITY OF MASSACHUSETTS AMHERST Ph.D., UNIVERSITY OF MASSACHUSETTS AMHERST Directed by: Professor Ryan C. Hayward Soft polymers placed under compressive stress can undergo an elastic creasing instability in which sharp folds spontaneously form on the free surfaces. This process may play an important role in contexts as diverse as brain morphogenesis, failure of tires, and electrical breakdown of soft polymer actuators. While the creasing instability has been used for collotype printing since as early as the 1850s, the scientific appreciation of this instability …

Ionic Copolymers For Alkaline Anion Exchange Membrane Fuel Cells (Aaemfcs), Tsung-Han Tsai

Doctoral Dissertations

The advantages of alkaline anion exchange membrane fuel cells (AAEMFCs) over proton exchange membrane fuel cells is the motivation for this dissertation. The objectives of this dissertation were to develop durable membranes with high anion conductivity and an understanding of the ion conductivity relationship with morphology. The research results presented in this dissertation focuses on developing different architectures of ionic copolymers including diblock copolymers and random copolymers for AAEMFCs. A novel, and stable cobaltocenium cation, was incorporated into polymer for stable AAEM. Because of its 18 electron closed valence-shell configuration, the cobaltocenium cation is promising for use in AAEMFC. Two …

Methods Of Engine Degradation Assessment In The Time-Scale Domain, Jeffrey Charles Simmons

Doctoral Dissertations

This dissertation addresses health monitoring of aircraft engines. Two methods are offered for engine degradation assessment: (1) a direct method to isolate degradation of engine components in-flight, and (2) an inverse method to quantify the level of degradations post-flight. The noted feature of the degradation isolation method is its independence from training, which makes it suitable for on-board implementation. The degradation quantification method, on the other hand, is a multi-output method of parameter estimation with the advantage of leveraging the shape attributes of model outputs. The representation of the shape attributes of the various time series, by continuous wavelet transforms …

Exploiting Energy Harvesting For Passive Embedded Computing Systems, Jeremy Joel Gummeson

Doctoral Dissertations

The key limitation in mobile computing systems is energy - without a stable power supply, these systems cannot process, store, or communicate data. This problem is of particular interest since the storage density of battery technologies do not follow scaling trends similar to Moore's law. This means that depending on application performance requirements and lifetime objectives, a battery may dominate the overall system weight and form factor; this could result in an overall size that is either inconvenient or unacceptable for a particular application. As device features have scaled down in size, entire embedded systems have been implemented on a …

Application Of Stormwater Management Techniques For Mitigation And Education At The Stockbridge School Agricultural Learning Center, Samantha R. Anderson

Landscape Architecture & Regional Planning Masters Projects

The Stockbridge School Agricultural Learning Center (SSALC) will be a 40-acre hands-on agricultural learning laboratory for students, staff, visitors, and neighbors. Still in its planning phases, the Center will be located on what is currently a hay field just north of UMass Amherst campus. A conceptual master plan was created in 2013 that is being used for fundraising as well as planning for agricultural demonstration plots and architectural hubs. Improperly managed agricultural landscapes are known as one of the biggest threats to water quality in the United States. As a model of forward thinking agricultural practices, properly managed stormwater on …

Wrinkling In Buckling And A Thin Sheet, Narayanan Menon

Patterns Around Us

Module 1: Euler Buckling

Learning Objectives:

• What is an instability? A sudden change in behaviour in response to a small change in conditions.

• Instabilities usually involve a change in symmetry from a more symmetric situation to a less symmetric one

• The mechanism for an instability usually involves two competing forces (one force stabilizing the symmetric state, and the other one destabilizing it), with one suddenly winning the contest

• These competing forces in thin objects are often the forces of compression (destabilizing force - favors buckling or wrinkling) and of bending (stabilizing force).

Understanding by data collapse, the power of using …

Evaluation Report, Alan Peterfreund

STEM Digital

This evaluation report synthesizes the results of evaluation activities conducted by SageFox Consulting Group of the STEM DIGITAL project led by the UMass STEM Ed Institute for its no-cost extension year, covering the period September 2013 to August 2014. The goals of the program are to facilitate the participants’ abilities to stimulate student interest in STEM careers while engaging them in ways to think critically about their environment. Participating teachers incorporated digital cameras and Analyzing Digital Images (ADI) software into lab activities focusing on environmental science. STEM DIGITAL materials focused on three strands related to (1) ozone and air quality, …

Free Wake Potential Flow Vortex Wind Turbine Modeling: Advances In Parallel Processing And Integration Of Ground Effects, Nathaniel B. Develder

Masters Theses 1911 - February 2014

Potential flow simulations are a great engineering type, middle-ground approach to modeling complex aerodynamic systems, but quickly become computationally unwieldy for large domains. An N-body problem with N-squared interactions to calculate, this free wake vortex model of a wind turbine is well suited to parallel computation. This thesis discusses general trends in wind turbine modeling, a potential flow model of the rotor of the NREL 5MW reference turbine, various forms of parallel computing, current GPU hardware, and the application of ground effects to the model. In the vicinity of 200,000 points, current GPU hardware was found to be nearly 17 …

Why Waste The Wind? A Look Into Small Scale Wind Energy, Mitchell Negus, Jon Swanton, Ben Chilcoat, Mark Settembrino

Student Showcase

The human race’s dependence on fossil fuels for energy generation has started to cause major changes in the environment. Climate change is a universal issue and it is evident that our current energy schematic is not sustainable. At the University of Massachusetts, small-scale wind power has the potential to be a key component in UMass’ energy portfolio as the university shifts from reliance on fossil fuels to renewable energy. Strategically placed turbines would produce clean, renewable energy, reduce greenhouse gas emissions, and help to decentralize energy dependence on the Central Heating Plant. Small-scale turbines, like the eddyGT, are tested technologies …