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Full-Text Articles in Engineering

Experimental And Computational Study On Magnetic Nanowires Of Layered Titanates, Caleb Layne Heath May 2019

Experimental And Computational Study On Magnetic Nanowires Of Layered Titanates, Caleb Layne Heath

Graduate Theses and Dissertations

The intricate nanostructures of layered titanates are unique among nanomaterials due to their easy and inexpensive syntheses. These nanomaterials have been proven valuable for use in industries as varied as energy, water treatment, and healthcare, and can be produced at industrial scales using already existent equipment. They have complex morphology, and surface structure well suited to chemical modification and doping. However, there is a longstanding debate on their lattice structure after the doping. There is a long-unmet need to understand, using both experimental and simulation methods, how dopants alter the clay-like layered crystal structure and associated physical and chemical properties. …


Recent Progress On Tio2-Based Anode Materials For Sodium-Ion Batteries, Si-Tian Lian, Jian-Shuai Lv, Qiang Yu, Guang-Wu Hu, Zhuo Chen, Liang Zhou, Li-Qiang Mai Feb 2019

Recent Progress On Tio2-Based Anode Materials For Sodium-Ion Batteries, Si-Tian Lian, Jian-Shuai Lv, Qiang Yu, Guang-Wu Hu, Zhuo Chen, Liang Zhou, Li-Qiang Mai

Journal of Electrochemistry

Titanium dioxide (TiO2) represents a stable, low-cost, and nontoxic anode material for sodium-ion batteries (SIBs). However, the low electrical conductivity limits its electrochemical activity (specific capacity) and rate capability, hindering its widespread applications. In this article, we show that different crystal forms of TiO2 have different pore structures, resulting in the distinct sodium storage capacities. Accordingly, the article introduces how TiO2 microstructures influence sodium storage. The nanoparticle structure can improve the rate performance of the material due to its short ion diffusion distance, and the internal cavity of the hollow structure is beneficial to cycle stability. …