Open Access. Powered by Scholars. Published by Universities.®
- Keyword
-
- Decarbonylation (2)
- Decarboxylation (2)
- Deoxygenation (2)
- Hydrocarbons (2)
- Nickel (2)
-
- Additives (1)
- Amine (1)
- Amine emissions (1)
- Ammonia (1)
- Anderson-Schulz-Flory (ASF) distribution (1)
- Biofuels (1)
- Brown grease (1)
- CO2 capture (1)
- Capture (1)
- Carbon dioxide (1)
- Catalyst (1)
- Co/alumina catalyst (1)
- Cobalt (1)
- Copper (1)
- Fischer-Tropsch synthesis (FTS) (1)
- Fischer–Tropsch synthesis (1)
- Flue gas (1)
- Free fatty acids (1)
- Heat stable salt (1)
- Iron (1)
- Mass transfer (1)
- Microalgae (1)
- Monoethanolamine (1)
- Oxygenates (1)
- Pilot CO2 capture (1)
Articles 1 - 7 of 7
Full-Text Articles in Engineering
Fischer–Tropsch: Product Selectivity–The Fingerprint Of Synthetic Fuels, Wilson D. Shafer, Muthu Kumaran Gnanamani, Uschi M. Graham, Jia Yang, Cornelius M. Masuku, Gary Jacobs, Burtron H. Davis
Fischer–Tropsch: Product Selectivity–The Fingerprint Of Synthetic Fuels, Wilson D. Shafer, Muthu Kumaran Gnanamani, Uschi M. Graham, Jia Yang, Cornelius M. Masuku, Gary Jacobs, Burtron H. Davis
Center for Applied Energy Research Faculty and Staff Publications
The bulk of the products that were synthesized from Fischer–Tropsch synthesis (FTS) is a wide range (C1–C70+) of hydrocarbons, primarily straight-chained paraffins. Additional hydrocarbon products, which can also be a majority, are linear olefins, specifically: 1-olefin, trans-2-olefin, and cis-2-olefin. Minor hydrocarbon products can include isomerized hydrocarbons, predominantly methyl-branched paraffin, cyclic hydrocarbons mainly derived from high-temperature FTS and internal olefins. Combined, these products provide 80–95% of the total products (excluding CO2) generated from syngas. A vast number of different oxygenated species, such as aldehydes, ketones, acids, and alcohols, are also embedded in this product range. …
Effect Of Pt Promotion On The Ni-Catalyzed Deoxygenation Of Tristearin To Fuel-Like Hydrocarbons, Ryan Loe, Kelsey Huff, Morgan Walli, Tonya Morgan, Dali Qian, Robert Pace, Yang Song, Mark Isaacs, Eduardo Santillan-Jimenez, Mark Crocker
Effect Of Pt Promotion On The Ni-Catalyzed Deoxygenation Of Tristearin To Fuel-Like Hydrocarbons, Ryan Loe, Kelsey Huff, Morgan Walli, Tonya Morgan, Dali Qian, Robert Pace, Yang Song, Mark Isaacs, Eduardo Santillan-Jimenez, Mark Crocker
Center for Applied Energy Research Faculty and Staff Publications
Pt represents an effective promoter of supported Ni catalysts in the transformation of tristearin to green diesel via decarbonylation/decarboxylation (deCOx), conversion increasing from 2% over 20% Ni/Al2O3 to 100% over 20% Ni-0.5% Pt/Al2O3 at 260 °C. Catalyst characterization reveals that the superior activity of Ni-Pt relative to Ni-only catalysts is not a result of Ni particle size effects or surface area differences, but rather stems from several other phenomena, including the improved reducibility of NiO when Pt is present. Indeed, the addition of a small amount of Pt to the supported Ni …
Continuous Catalytic Deoxygenation Of Waste Free Fatty Acid-Based Feeds To Fuel-Like Hydrocarbons Over A Supported Ni-Cu Catalyst, Ryan Loe, Yasmeen Lavoignat, Miranda Maier, Mohanad Abdallah, Tonya Morgan, Dali Qian, Robert Pace, Eduardo Santillan-Jimenez, Mark Crocker
Continuous Catalytic Deoxygenation Of Waste Free Fatty Acid-Based Feeds To Fuel-Like Hydrocarbons Over A Supported Ni-Cu Catalyst, Ryan Loe, Yasmeen Lavoignat, Miranda Maier, Mohanad Abdallah, Tonya Morgan, Dali Qian, Robert Pace, Eduardo Santillan-Jimenez, Mark Crocker
Center for Applied Energy Research Faculty and Staff Publications
While commercial hydrodeoxygenation (HDO) processes convert fats, oils, and grease (FOG) to fuel-like hydrocarbons, alternative processes based on decarboxylation/decarbonylation (deCOx) continue to attract interest. In this contribution, the activity of 20% Ni-5% Cu/Al2O3 in the deCOx of waste free fatty acid (FFA)-based feeds—including brown grease (BG) and an FFA feed obtained by steam stripping a biodiesel feedstock—was investigated, along with the structure-activity relationships responsible for Ni promotion by Cu and the structural evolution of catalysts during use and regeneration. In eight-hour experiments, near quantitative conversion of the aforementioned feeds to diesel-like hydrocarbons was achieved. …
Enhancements In Mass Transfer For Carbon Capture Solvents Part I: Homogeneous Catalyst, Leland R. Widger, Moushumi Sarma, Jonathan J. Bryant, David S. Mannel, Jesse G. Thompson, Cameron A. Lippert, Kunlei Liu
Enhancements In Mass Transfer For Carbon Capture Solvents Part I: Homogeneous Catalyst, Leland R. Widger, Moushumi Sarma, Jonathan J. Bryant, David S. Mannel, Jesse G. Thompson, Cameron A. Lippert, Kunlei Liu
Center for Applied Energy Research Faculty and Staff Publications
The novel small molecule carbonic anhydrase (CA) mimic [CoIII(Salphen-COO−)Cl]HNEt3 (1), was synthesized as an additive for increasing CO2 absorption rates in amine-based post-combustion carbon capture processes (CCS), and its efficacy was verified. 1 was designed for use in a kinetically slow but thermally stable blended solvent, containing the primary amines 1-amino-2-propanol (A2P) and 2-amino-2-methyl-1-propanol (AMP). Together, the A2P/AMP solvent and 1 reduce the overall energy penalty associated with CO2 capture from coal-derived flue gas, relative to the baseline solvent MEA. 1 is also effective at increasing absorption kinetics of kinetically fast solvents, such …
Solvent Degradation And Emissions From A 0.7mwe Pilot Co2 Capture System With Two-Stage Stripping, Jesse Thompson, Heather Nikolic, Megan Combs, Saloni Bhatnagar, Jonathan Pelgen, Keemia Abad, Kunlei Liu
Solvent Degradation And Emissions From A 0.7mwe Pilot Co2 Capture System With Two-Stage Stripping, Jesse Thompson, Heather Nikolic, Megan Combs, Saloni Bhatnagar, Jonathan Pelgen, Keemia Abad, Kunlei Liu
Center for Applied Energy Research Faculty and Staff Publications
The UKy-CAER team successfully tested an advanced 0.7 MWe post-combustion CO2 capture system on a coal-fired power plant using a heat integration process combined with two-stage stripping to enhance the CO2 absorber performance. One of the unique feature of the UKy-CAER integrated process is a two-stage stripping unit for solvent regeneration. The secondary stripper is empowered by the heat rejection from a conventional steam-heated (primary) stripper. The secondary stripper outlet stream at the commercial scale can be used as boiler secondary combustion air, consequently enriching the flue gas with CO2, resulting in less energy penalty required …
Fischer–Tropsch Synthesis: Effect Of Ammonia On Product Selectivities For A Pt Promoted Co/Alumina Catalyst, Venkat Ramana Rao Pendyala, Wilson D. Shafer, Gary Jacobs, Michela Martinelli, Dennis E. Sparks, Burtron H. Davis
Fischer–Tropsch Synthesis: Effect Of Ammonia On Product Selectivities For A Pt Promoted Co/Alumina Catalyst, Venkat Ramana Rao Pendyala, Wilson D. Shafer, Gary Jacobs, Michela Martinelli, Dennis E. Sparks, Burtron H. Davis
Center for Applied Energy Research Faculty and Staff Publications
The effects of co-fed ammonia in synthesis gas on the activity and product selectivities of a typical cobalt catalyst (0.5% Pt–25% Co/Al2O3) were investigated during the Fischer–Tropsch synthesis using a continuously stirred tank reactor (CSTR). The product selectivities were compared at a similar CO conversion level for various concentrations (10–1000 ppmv) of ammonia, as well as clean (un-poisoned) conditions. The addition of 10–1000 ppmv ammonia (concentration of ammonia with respect to the syngas feed) significantly decreased activity; the percentage of deactivation was similar (∼40%) for the various concentrations of ammonia used. At similar CO conversions, the …
Co2 Recycling Using Microalgae For The Production Of Fuels, Michael H. Wilson, John Groppo, Andrew Placido, S. Graham, S. A. Morton Iii, Eduardo Santillan-Jimenez, Aubrey Shea, Mark Crocker, Czarena Crofcheck, Rodney Andrews
Co2 Recycling Using Microalgae For The Production Of Fuels, Michael H. Wilson, John Groppo, Andrew Placido, S. Graham, S. A. Morton Iii, Eduardo Santillan-Jimenez, Aubrey Shea, Mark Crocker, Czarena Crofcheck, Rodney Andrews
Center for Applied Energy Research Faculty and Staff Publications
CO2 capture and recycle using microalgae was demonstrated at a coal-fired power plant (Duke Energy’s East Bend Station, Kentucky). Using an in-house designed closed loop, vertical tube photobioreactor, Scenedesmus acutus was cultured using flue gas as the CO2 source. Algae productivity of 39 g/(m2 day) in June–July was achieved at significant scale (18,000 L), while average daily productivity slightly in excess of 10 g/(m2 day) was demonstrated in the month of December. A protocol for low-cost algae harvesting and dewatering was developed, and the conversion of algal lipids—extracted from the harvested biomass—to diesel-range hydrocarbons via catalytic …