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Nanoscience and Nanotechnology

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2005

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Articles 1 - 30 of 47

Full-Text Articles in Engineering

Simulation Of Phonon-Assisted Band-To Band Tunneling In Carbon Nanotube Field-Effect Transistors, Siyuranga O. Koswatta, Mark S. Lundstrom, M. P. Anantram, Dmitri E. Nikonov Dec 2005

Simulation Of Phonon-Assisted Band-To Band Tunneling In Carbon Nanotube Field-Effect Transistors, Siyuranga O. Koswatta, Mark S. Lundstrom, M. P. Anantram, Dmitri E. Nikonov

Other Nanotechnology Publications

Electronic transport in a carbon nanotube metal-oxide-semiconductor field effect transistor (MOSFET) is simulated using the nonequilibrium Green’s functions method with the account of electron-phonon scattering. For MOSFETs, ambipolar conduction is explained via phonon-assisted band-to-band (Landau–Zener) tunneling. In comparison to the ballistic case, we show that the phonon scattering shifts the onset of ambipolar conduction to more positive gate voltage (thereby increasing the off current). It is found that the subthreshold swing in ambipolar conduction can be made as steep as 40 mV/decade despite the effect of phonon scattering.


An Investigation On Poly(Vinyl Chloride-Co-Isobutyl Vinyl Ether) Coatings Modified By Rutile Nano-Tio_2 Pastes, Xiang Bin Nov 2005

An Investigation On Poly(Vinyl Chloride-Co-Isobutyl Vinyl Ether) Coatings Modified By Rutile Nano-Tio_2 Pastes, Xiang Bin

Journal of Electrochemistry

The anti-corrosion coating of Poly(Vinyl Chloride-Co-Isobutyl Vinyl Ether)(PVCCIVE) was modified by rutile nano-TiO_(2).The influence of nano-TiO_(2) pastes on the coating's corrosion resistance was investigated through electrochemistry impedance spectroscopy(EIS).The results show that the addition of nano-TiO_(2) pastes does not have obvious effect on the coating's performance of adhesion,flexility,impact resistance,but improves the coating's UV resistance and the gloss.Meanwhile,with the proper addition of rutile nano-TiO_(2) pastes,the(anti)-corrosion behavior of the coating was advanced.


The Electrocatalystic Investigation Of 3,4-Dihydroxybenzoic Acid On The Modified Multiply Wall Carbon Nanotubes, Ming-Qi Li Nov 2005

The Electrocatalystic Investigation Of 3,4-Dihydroxybenzoic Acid On The Modified Multiply Wall Carbon Nanotubes, Ming-Qi Li

Journal of Electrochemistry

The electrochemical behavior of 3,4-Dihydroxybenzoic acid(DHBA)on modified multiply wall carbon nanotubes electrode was investigated by cyclic voltammetry(CV) and square wave voltammetry(SWV).Results show that in 0.1 mol/L HCl solutions the modified carbon nanotube electrode has an obvious electrocatalytic effect on the oxidation and deoxidization of DHBA.The oxidation current of DHBA is linear to it's concentration in the range of 4.0×10~(-6)~1.0×10~(-4) mol/L and 2.0×10~(-4)~8.0×10~(-4)1mol/L with correlation coefficient of 0.9995 and 0.9992.The detection limit is 1.0 ×10~(-6)mol/ L.


In Vitro And In Vivo Two-Photon Luminescence Imaging Of Single Gold Nanorods, Haifeng Weng, Terry B. Huff, Daniel A. Zweifel, Wei He, Philip S. Low, Alexander Wei, Ji-Xin Cheng Nov 2005

In Vitro And In Vivo Two-Photon Luminescence Imaging Of Single Gold Nanorods, Haifeng Weng, Terry B. Huff, Daniel A. Zweifel, Wei He, Philip S. Low, Alexander Wei, Ji-Xin Cheng

Other Nanotechnology Publications

Gold nanorods excited at 830 nm on a far-field laser-scanning microscope produced strong two-photon luminescence (TPL) intensities, with a cos(4) dependence on the incident polarization. The TPL excitation spectrum can be superimposed onto the longitudinal plasmon band, indicating a plasmon-enhanced two-photon absorption cross section. The TPL signal from a single nanorod is 58 times that of the two-photon fluorescence signal from a single rhodamine molecule. The application of gold nanorods as TPL imaging agents is demonstrated by in vivo imaging of single nanorods flowing in mouse ear blood vessels.


Progress Towards Terahertz Acoustic Phonon Generation In Doping Superlattices, Thomas E. Wilson Oct 2005

Progress Towards Terahertz Acoustic Phonon Generation In Doping Superlattices, Thomas E. Wilson

Physics Faculty Research

Progress is described in experiments to generate coherent terahertz acoustic phonons in silicon doping superlattices by the resonant absorption of nanosecond-pulsed far-infrared laser radiation. Future experiments are proposed that would use the superlattice as a transducer in a terahertz cryogenic acoustic reflection microscope with sub-nanometer resolution.


Self-Assembly Of Nanoparticles On Live Bacterium: An Avenue To Fabricate Electronic Devices, Vikas Berry, Ravi F. Saraf Oct 2005

Self-Assembly Of Nanoparticles On Live Bacterium: An Avenue To Fabricate Electronic Devices, Vikas Berry, Ravi F. Saraf

Papers in Nanotechnology

Recently, hybrid structures of microorganisms with inorganic nanoscale moieties have received great interest due to their potential in fabricating electronic systems. Electronic properties of metal nanoparticles, due to single electron transport of current[1], make them ideal material for nanodevices. Concomitantly, the nanostructure of microorganisms such as bacteria[2], viruses[3;4] and yeast[5] are attractive scaffolds for nanoparticle templating due to surface charge and biological affinities for specific molecules [2-7]. However, the key challenges in building hybrid devices are patterning nanostructures without destroying the biological construct of the microorganism and achieving active integration of biological response to the electrical transport in nanoparticle device. …


Surface-Enhanced Raman Spectra Of Cytosine Adsorbed On A Roughened Gold Electrode, Yuan-Fei Wu, Jian-Feng Li, De-Yin Wu, Bin Ren, Zhong-Qun Tian Aug 2005

Surface-Enhanced Raman Spectra Of Cytosine Adsorbed On A Roughened Gold Electrode, Yuan-Fei Wu, Jian-Feng Li, De-Yin Wu, Bin Ren, Zhong-Qun Tian

Journal of Electrochemistry

Cytosine adsorbed on a roughened gold electrode has been investigated by using electrochemical cyclic voltammetry and surface-enhanced Raman spectroscopy (SERS). The results indicate that cytosine was adsorbed on the Au electrode in a perpendicular orientation via the N3 position. As the maximum enhancement of ring breathing mode appears at negative potentials compared with other modes, both the electromagnetic enhancement and the charge transfer mechanism were considered to contribute to the SERS intensity. The binding interaction between cytosine and the gold electrode was weakened when the potential was negatively moved. The result also indicates that the SERS technique can be used …


Surface And Sructure Investigations Of Membrane Electrode Assembly In Dmfc Lifetime Testing~*, Chengxuan Chengxuan, Cheng Peng, Meng-Di You, Jing Liu, Ying Zhang Aug 2005

Surface And Sructure Investigations Of Membrane Electrode Assembly In Dmfc Lifetime Testing~*, Chengxuan Chengxuan, Cheng Peng, Meng-Di You, Jing Liu, Ying Zhang

Journal of Electrochemistry

The lifetime and performance of a direct methanol fuel cell (DMFC) were investigatedto understand the correlation between thestructure of catalysts /membrane and cell performanceversus time.The cell polarization and performance curves were obtained during the DMFC operation with the time.The catalysts and Nafion~ membrane of the membrane electrode assembly (MEA) from the lifetime test were comprehensively examined by XRD, HRTEM, FTIRand Raman spectroscope techniques.The results revealed that there was significant performance degradation during the first 200 hours operation; while the degradation was slowing down between 200 and 704hours operation.The degradation became worse after 1 002 h operation.The increases of the catalyst …


The Application Of Astm C1202-93 On Evaluating The Performance Of Anti-Corrosion Of Concrete, Yuan Chen Yuan Aug 2005

The Application Of Astm C1202-93 On Evaluating The Performance Of Anti-Corrosion Of Concrete, Yuan Chen Yuan

Journal of Electrochemistry

The test of chloride ion penetration based on the standards of ASTM C1202-93 is applied to evaluate the anti-corrosion performance of concrete in this research. Concrete specimens were produced according to ACI 318-89 mixture proportioning design and the Desenfied Mixture Design Algorithm (DMDA) and were measured the 6-hour coulombs at the age of 91 days. Results show that w/b is not the factor influencing chloride penetration of ACI concrete, as the ion penetration of ACI specimens is all higher than 2 000 Coulombs and can even be poorer than 10 000 Coulombs. With a proper amount of pozzolanic material, the …


The Research Of Nano-Sized Nio Anode Materials For Lithium Ion Batteries, Jun-Mei Yan, Jing Zhang, Yong Yang Aug 2005

The Research Of Nano-Sized Nio Anode Materials For Lithium Ion Batteries, Jun-Mei Yan, Jing Zhang, Yong Yang

Journal of Electrochemistry

The nano-sized NiO materials were synthesized by solid phase method and sol-gel method. The synthesis conditions were optimized by DSC and TG techniques. The sol-gel method was optimized by changing the solvent and regulating the solution's pH for preparing NiO material. The structure and morphology of the materials were also characterized by means of XRD and TEM techniques, and the electrochemical performances of the materials were studied by the galvanostatically charge and discharge experiments.


Cyclic Voltammetry And Surface Enhanced Raman Spectroscopy Of Dissociative Adsorption Of Ethanol On Pt-Ru Electrodes, Zhang Bin Aug 2005

Cyclic Voltammetry And Surface Enhanced Raman Spectroscopy Of Dissociative Adsorption Of Ethanol On Pt-Ru Electrodes, Zhang Bin

Journal of Electrochemistry

The behaviors of dissociative adsorption of ethanol on roughened platinum-ruthenium electrode with high activity of SERS were studied by using cyclic voltammetry and in-situ surface enhanced Raman spectroscopy, surface enhanced Raman spectra of dissociative adsorption of ethanol on Pt electrode in acid was obtained for the first time. It is shown that the Pt-Ru could lower the over-potential of CO oxidation when compared to Pt electrode. The results show that the ethanol in acid medium can be self-dissociated at Pt-Ru electrode to produce CO, which discourage the further oxidation of ethanol, some information of Pt-C and Pt-C-Pt stretching vibration from …


Investigation, On The Accelerated Dissolution Of Metal Induced By Afm Tip Scratching And Suppressed By Inhibitors, Jun-E Qu, Xing-Peng Guo Aug 2005

Investigation, On The Accelerated Dissolution Of Metal Induced By Afm Tip Scratching And Suppressed By Inhibitors, Jun-E Qu, Xing-Peng Guo

Journal of Electrochemistry

The accelerated dissolution behavior of Cu-Ni alloy induced by AFM tip scratching and the inhibition effect of corrosion inhibitors were investigated. The results showedthat, with a tip loading of 750nN ,continuous scan for 30 min in a contact mode on 4×4 μm~(2) of copper-nickel alloy in 1.5mol/L NaCl and 0.01mol/L HCl could enhance the dissolution of the sample and produced pits on the scratched area. Adding inorganic inhibitors, sodium chromateand organic inhibitor dodecylamine, to the solution suppressed the dissolution of copper-nickel alloyinduced by tip scratching, respectively, by improving the surface passivationperformance of metal surface and forming adsorption films on copper-nickel …


Electrocatalytic Oxidation And Degration Of Active Red X-3b By Nanotubes Catalytic Electrodes, Yi Wen, Jian-Hui Fang Aug 2005

Electrocatalytic Oxidation And Degration Of Active Red X-3b By Nanotubes Catalytic Electrodes, Yi Wen, Jian-Hui Fang

Journal of Electrochemistry

The catalytic splitting decomposition of carbon nanotubes isprocessed by dispersing with dilute nitric acid and thermal oxidation. Then well-proportionedphenolic resin is mixed in the carbon nanotubes. Then, the carbon nanotubesare made into electrodes by hot-press molding after the process of milling with high speed. The surface of the carbon nanotubes electrodes is analyzed by SEM. Active red X-3B simulated waster water is disposed by carbon nanotubes catalyticelectrode (anode) and stainless steel(cathode). The influencing factors of degradation by current density, concentrationof electrolyte, systemtemperature and pH are investigated. The experimental results indicated that acidiccondition is propitious tothe degradationreaction of organicdyestuff and wastewater …


Magnetization Reversal In Particulate L10 Nanostructures, Jian Zhou, Ralph Skomski, Kory D. Sorge, David J. Sellmyer Aug 2005

Magnetization Reversal In Particulate L10 Nanostructures, Jian Zhou, Ralph Skomski, Kory D. Sorge, David J. Sellmyer

Nebraska Center for Materials and Nanoscience: Faculty Publications

Magnetization processes in particulate L10 FePt nanostructures are investigated by model calculations and numerical simulations. The systems considered include anisotropic nanograins embedded in non-magnetic matrix; randomly oriented nanoclusters embedded in a C matrix, and nanocomposites of FePt particles in a semi-hard matrix. The reversal mechanisms depend on both intra- and intergranular features. Quasi-coherent rotation dominates the reversal in weakly-coupled granular magnets, but interface imperfections yield a disproportionately strong coercivity reduction. Strong intergranular exchange leads to a transition to a discrete pinning regime, which is accompanied by a coercivity maximum.


Phase Transformations And Thermodynamic Properties Of Nanocrystalline Fept Powders , J. Lyubina, O. Gutfleisch, Ralph Skomski, K.-H. Müller, L. Schultz Aug 2005

Phase Transformations And Thermodynamic Properties Of Nanocrystalline Fept Powders , J. Lyubina, O. Gutfleisch, Ralph Skomski, K.-H. Müller, L. Schultz

Nebraska Center for Materials and Nanoscience: Faculty Publications

The solid state reactions and structural evolution in nanocrystalline FePt powders during mechanical ball milling at 77 K and subsequent annealing have been investigated. Above 310 °C the formation of L10 FePt is observed. As the milling time increases, the enthalpy evolved during the transformations is reduced, whereas the corresponding activation energy increases. For accelerating the ordering process a fine lamellar structure of Fe and Pt is favourable.


Atomic And Micromagnetic Aspects Of L10 Magnetism, Ralph Skomski, Arti Kashyap, Jian Zhou Aug 2005

Atomic And Micromagnetic Aspects Of L10 Magnetism, Ralph Skomski, Arti Kashyap, Jian Zhou

Nebraska Center for Materials and Nanoscience: Faculty Publications

Atomic and continuum effects in L10 magnets are investigated. Emphasis is on the competition between ferromagnetism, antiferromagnetism, and noncollinear order in both perfect and imperfect structures, and on the temperature dependence of the magnetic anisotropy. The applicability of micromagnetic and atomistic approaches depends on the length scales involved, but there is a broad range of phenomena where both can be used.


Evolutionary Algorithm For The Placement Of Fluid Power Valves On A Valve Stand, Trichy M. Kethara Pasupathy, Ravi Teja Seethamraju, Robert G. Wilhelm Aug 2005

Evolutionary Algorithm For The Placement Of Fluid Power Valves On A Valve Stand, Trichy M. Kethara Pasupathy, Ravi Teja Seethamraju, Robert G. Wilhelm

Department of Mechanical and Materials Engineering: Faculty Publications

The choice of placement of fluid power valves on a valve stand and routing by pipes has an impact on operational costs. Choosing the right placement that provides optimum routing configuration or determining the optimum routing for a chosen placement are both computationally hard problems. An evolutionary algorithm (EA), to minimize operational costs while optimizing placement and routing of valves, is developed here. The best practices in the industry are abstracted and implemented in the EA. In this paper, the algorithm and its performance for examples with varying complexities are presented. Our results meet or exceed experienced designers’ solutions.


Theoretical Investigation Of Surface Roughness Scattering In Silicon Nanowire Transistors, Jing Wang, Eric Polizzi, Avik Ghosh, Supriyo Datta, Mark Lundstrom Jul 2005

Theoretical Investigation Of Surface Roughness Scattering In Silicon Nanowire Transistors, Jing Wang, Eric Polizzi, Avik Ghosh, Supriyo Datta, Mark Lundstrom

Other Nanotechnology Publications

Using a full three-dimensional (3D), quantum transport simulator, we theoretically investigate the effects of surface roughness scattering (SRS) on the device characteristics of Si nanowire transistors (SNWTs). The microscopic structure of the Si/SiO2 interface roughness is directly treated by using a 3D finite element technique. The results show that (1) SRS reduces the electron density of states in the channel, which increases the SNWT threshold voltage, and (2) the SRS in SNWTs becomes less effective when fewer propagating modes are occupied, which implies that SRS is less important in small-diameter SNWTs with few modes conducting than in planar metal-oxide-semiconductor field-effect-transistors …


Effective Electromechanical Moduli Of Ferroelectric Ceramics With Fiber Textures, Y.C. Zhou, J. Liu, Jiangyu Li Jun 2005

Effective Electromechanical Moduli Of Ferroelectric Ceramics With Fiber Textures, Y.C. Zhou, J. Liu, Jiangyu Li

Nebraska Center for Materials and Nanoscience: Faculty Publications

In this letter, we report the predictions on the effective piezoelectric coefficients and electromechanical coupling factors of ferroelectric ceramics BaTiO 3 and Pb(Mg 1/3Nb 2/3)O 3–PbTiO 3 (PMN-PT) with various fiber textures, including [001], [011], and [111], using a two-scale micromechanical model that accounts for microstructural phenomena at both domain and grain levels. It was observed that for BaTiO 3 the [011] texture is optimal with highest d 31 and d 33, while for PMN-PT [001] texture is optimal despite the fact that [011]-oriented single-crystalline PMN-PT has higher d 32 than that of [001]-oriented PMN-PT single …


Jecp/Holz — An Interactive Computer Program For Simulation Of Holz Patterns, Xingzhong Li Jun 2005

Jecp/Holz — An Interactive Computer Program For Simulation Of Holz Patterns, Xingzhong Li

Nebraska Center for Materials and Nanoscience: Faculty Publications

In the present work, an interactive computer program for simulation of the HOLZ line patterns, JECP/HOLZ, is reported. A feature of this program is the integration of the simulation of the HOLZ reflections and the HOLZ (curved and straight) lines, which is interactive with respect to changes of the lattice parameter, the accelerator voltage, the zone axis, and the beam tilt. The program can be used as a teaching aid for students as well as a tool for scientists working on electron diffraction experiments.


Fabrication Of Nano Capacitor And Its Electrical Properties, Ling Liu, Qin Zhou, Neng-Qin Jia, Zhi-Yu Jiang May 2005

Fabrication Of Nano Capacitor And Its Electrical Properties, Ling Liu, Qin Zhou, Neng-Qin Jia, Zhi-Yu Jiang

Journal of Electrochemistry

A step-by-step assembling method was developed for preparing nano capacitors using anodic aluminum oxide (AAO) membrane as templates. The nano capacitor consisted of three parts: electrochemically polymerized PPy electrode/ el ectrochemically precipitated porous TiO_(2) separator / chemically polymerized PPy electrode, and demonstrated the charge/discharge behavior as a typical electrochemical supercapacitor with good cyclic ability.


Using Electrodeposition To Fabricate Mould For Polymer Microfluidic Chip, Luo Yi May 2005

Using Electrodeposition To Fabricate Mould For Polymer Microfluidic Chip, Luo Yi

Journal of Electrochemistry

Many researches have been focused on polymer microfluidic chip in recent years and the mould plays an important role in its fabrication process. Using electrodepositingmethod to fabricate a metal mould for polymer microfluidic chip has been presented in this paper. An ultra-thick photoresist SU-8 was coated on a pretreated metal plate, after photolithography, nickel was electrodeposited in the patterned SU-8, then was removed the SU-8 to obtain a final metal mould. This methodreduces workload of electrodeposit largely. Applying counter current before deposit, adding additive to solution and vacuum anneal after demould have been used to improve the binding force between …


Preparation, Characterization And Electrochemical Properties Of Nano Tio_(2)-Cnt-Pt On Ti Substrate Complex Electrode, Dao-Bao Chu May 2005

Preparation, Characterization And Electrochemical Properties Of Nano Tio_(2)-Cnt-Pt On Ti Substrate Complex Electrode, Dao-Bao Chu

Journal of Electrochemistry

The nanoTiO_(2)-CNT-Pt on Ti substrate complex electrodes were prepared from precursor of (Ti(OEt)_(4)) directly hydrolyzed and by cyclic voltammograms electroplating method . The XRD and SEM results showed that the nano TiO_(2) (anatase) particle sizes ranged 5~10 nm and the Pt nanoparticle (average size 9nm) dispersed uniformly on nanoTiO_(2)-CNT film surface. The electrocatalytic activity of Ti/nanoTiO_(2)-CNT-Pt electrode was investigated by cyclic voltammetry and chronopotentiogram. The results indicated that the Ti/nanoTiO_(2)-CNT-Pt electrode exhibited very high electrocatalytic activity and stability for the electro-oxidation of methanol at room temperature. When Pt loading was 0.32 mg/cm~(2), the oxidation peak current of methanol was 480 …


Influence Of Nitrogen Growth Pressure On The Ferromagnetic Properties Of Cr-Doped Aln Thin Films, Jun Zhang, Xingzhong Li, B. Xu, David J. Sellmyer May 2005

Influence Of Nitrogen Growth Pressure On The Ferromagnetic Properties Of Cr-Doped Aln Thin Films, Jun Zhang, Xingzhong Li, B. Xu, David J. Sellmyer

Nebraska Center for Materials and Nanoscience: Faculty Publications

We report the magnetic properties of Cr-doped AlN thin films grown by reactive magnetron sputtering under various nitrogen pressures. Ferromagnetism is observed up to the highest temperature measured, 400 K, and shows strong dependence on the Cr concentration and, especially, the nitrogen growth pressure. By varying the nitrogen pressure during film growth, the magnetic properties of the films can be changed while keeping a constant Cr concentration. The ferromagnetism is enhanced in the films that were grown at low nitrogen pressures and thus nitrogen deficient, suggesting an important role of defects in the ferromagnetism of this material.


Magnetic Behavior Of Sm-Co-Based Permanent Magnets During Order/Disorder Phase Transformations, Shampa Aich, J. Kostogorova, Jeffrey E. Shield May 2005

Magnetic Behavior Of Sm-Co-Based Permanent Magnets During Order/Disorder Phase Transformations, Shampa Aich, J. Kostogorova, Jeffrey E. Shield

Nebraska Center for Materials and Nanoscience: Faculty Publications

The structural transformation from the metastable disordered TbCu7-type SmCo7 structure to the equilibrium ordered Th2Zn17-type Sm2Co17 structure was revealed by x-ray diffraction analysis using Reitveld refinement. The magnetic properties depended strongly on the stage of the transformation, as the coercivity strongly depended on the annealing temperature. The as-solidified alloy in the TbCu7-type structure had a coercivity of 4 kOe, which increased to greater than 9 kOe. The coercivity decreased to around 5 kOe as the transformation neared completion upon annealing at higher temperatures. The magnetization processes were also strongly influenced …


Texture Formation In Fept Thin Films Via Thermal Stress Management, P. Rasmussen, X. Rui, Jeffrey E. Shield May 2005

Texture Formation In Fept Thin Films Via Thermal Stress Management, P. Rasmussen, X. Rui, Jeffrey E. Shield

Nebraska Center for Materials and Nanoscience: Faculty Publications

The transformation variant of the fcc to fct transformation in FePt thin films was tailored by controlling the stresses in the thin films, thereby allowing selection of in- or out-of-plane c-axis orientation. FePt thin films were deposited at ambient temperature on several substrates with differing coefficients of thermal expansion relative to the FePt, which generated thermal stresses during the ordering heat treatment. X-ray diffraction analysis revealed preferential out-of-plane c-axis orientation for FePt films deposited on substrates with a similar coefficients of thermal expansion, and random orientation for FePt films deposited on substrates with a very low coefficient of …


Role Of Phonon Scattering In Carbon Nanotube Field-Effect Transistors, Jing Guo, Mark Lundstrom May 2005

Role Of Phonon Scattering In Carbon Nanotube Field-Effect Transistors, Jing Guo, Mark Lundstrom

Other Nanotechnology Publications

The role of phonon scattering in carbon nanotube field-effect transistors 􏰏CNTFETs􏰀 is explored by solving the Boltzmann transport equation using the Monte Carlo method. The results show that elastic scattering in a short-channel CNTFET has a small effect on the source-drain current due to the long elastic mean-free path (mfp)(~ 1µm). If elastic scattering with a short mfp were to exist in a CNTFET, the on current would be severely degraded due to the one-dimensional channel geometry. At high drain bias, optical phonon scattering, which has a much shorter mfp (-10 nm), is expected to dominate, even in a short-channel …


The Electrophoretic Deposition Of Nano Hydroxyapatite Coating On Titanium Surface, Fei Chen, Chang-Jian Lin Feb 2005

The Electrophoretic Deposition Of Nano Hydroxyapatite Coating On Titanium Surface, Fei Chen, Chang-Jian Lin

Journal of Electrochemistry

A hydroxyapatite coating with nano-structure on the roughened titanium surface was prepared by electrophoretic deposition process. To decrease sintering temperature the HAp nanoparticles synthesizedby a wet chemical method was used. It is observed that the coating is uniform without cracks. After sintering the nano-strueture of HAp coating remains unchanged. The surface treatment of Ti is applied to form a distribution of small pits and TiO_2thin layer that improve the adhesion of coatingto Ti substrate. It is shown that the bonding strength of coating is as high as 18±2.5MPa. The hardness and Young's modulus are 40.6 and 0.42 GPa, respectively.


Preparation And Electrochemical Property Of Aao Nano-Channels Filled With Nio, Chi Gu, Jun-Mei Yan, Yong Yang Feb 2005

Preparation And Electrochemical Property Of Aao Nano-Channels Filled With Nio, Chi Gu, Jun-Mei Yan, Yong Yang

Journal of Electrochemistry

The AAO template with nano-channels was synthesized and filled with transient metal-oxide NiO by sol-gel method, and their electrochemical properties were primarily studied. The results showed that the porous nano-channels were well defined with the diameter about 50nm. The nano-structured NiO was filled into the template's nano-channels successfully., Cyclic voltammetry studies show that the NiO in AAO template has good cycle stability.It was suggested that the AAO-metal-oxides composites could be used as novel anode materials for Lithium ion battery.


The Fabrication And Electrochemical Studies On Carbon Nanotube Array Electrodes, Quan-Yong Gao, Jing Zhang, Yangyong Yangyong Feb 2005

The Fabrication And Electrochemical Studies On Carbon Nanotube Array Electrodes, Quan-Yong Gao, Jing Zhang, Yangyong Yangyong

Journal of Electrochemistry

An improved technique for fabrication of carbon nanotube array electrodes has been proposed in this work. Firstly, carbon nanotubes (CNs) array electrodes were prepared by combsination of Chemical Vapor Decomposition (CVD) method and sputtering techniques in anodized aluminum oxide (AAO) membrane. The CNs/AAO was immersed into HF solution to remove the barrier layer. Controlling the immersing time, the CNs array electrodes with different length contacted with electrolyte can be prepared. The morphology of CNs array electrodes was observed by SEM. The electrochemical properties of CNs array electrodes were investigated by cyclic voltammetry and electrochemical impedance spectroscopy. Cyclic voltammetric curves of …