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Missouri University of Science and Technology

Materials Science and Engineering Faculty Research & Creative Works

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Full-Text Articles in Engineering

Control Of High-Temperature Static And Transient Thermomechanical Behavior Of Simo Ductile Iron By Al Alloying, Semen Naumovich Lekakh, Catherine E. Johnson, L. Godlewski, Mei Li Feb 2022

Control Of High-Temperature Static And Transient Thermomechanical Behavior Of Simo Ductile Iron By Al Alloying, Semen Naumovich Lekakh, Catherine E. Johnson, L. Godlewski, Mei Li

Materials Science and Engineering Faculty Research & Creative Works

Silicon and molybdenum (SiMo) ductile iron is commonly used for exhaust manifolds because these components experience thermal cycling in oxidizing environment, which requires resistance to fatigue during transient thermomechanical loads. Previous studies have demonstrated that alloying elements, such as Al, to SiMo ductile iron reduces the amount of surface degradation during static high-temperature exposure. However, deterioration of sphericity of the graphite nodules and a decrease in ductility could affect the tendency of cracking during thermal cycling. In this article, the effect of Al alloying on static and transient thermomechanical behavior of SiMo ductile iron was investigated to optimize the amount …


Detonation Synthesis Of Nanoscale Silicon Carbide From Elemental Silicon, Martin J. Langenderfer, Yue Zhou, Jeremy Lee Watts, William Fahrenholtz, Catherine E. Johnson Feb 2022

Detonation Synthesis Of Nanoscale Silicon Carbide From Elemental Silicon, Martin J. Langenderfer, Yue Zhou, Jeremy Lee Watts, William Fahrenholtz, Catherine E. Johnson

Materials Science and Engineering Faculty Research & Creative Works

Direct reaction of precursors with the products of detonation remains an underexplored area in the ever-growing body of detonation synthesis literature. This study demonstrated the synthesis of silicon carbide during detonation by reaction of elemental silicon with carbon products formed from detonation of RDX/TNT mixtures. Continuum scale simulation of the detonation showed that energy transfer by the detonation wave was completed within 2–9 μs depending on location of measurement within the detonating explosive charge. The simulated environment in the detonation product flow beyond the Chapman-Jouguet condition where pressure approaches 27 GPa and temperatures reach 3300 K was thermodynamically suitable for …


Effects Of Inert Additives On Cyclotrimethylene-Trinitramine (Rdx)/Trinitrotoluene (Tnt) Detonation Parameters To Predict Detonation Synthesis Phase Production, Martin Langenderfer, William Fahrenholtz, Catherine E. Johnson Nov 2020

Effects Of Inert Additives On Cyclotrimethylene-Trinitramine (Rdx)/Trinitrotoluene (Tnt) Detonation Parameters To Predict Detonation Synthesis Phase Production, Martin Langenderfer, William Fahrenholtz, Catherine E. Johnson

Materials Science and Engineering Faculty Research & Creative Works

A methodology was developed to predict pressure and temperature regimes achieved during detonation of RDX/TNT compositions with inert granular inclusions. The predicted pressures and temperatures are used as inputs for thermochemical simulations to design detonation synthesis experiments that utilize shock-induced chemical reactions to produce ceramic nanomaterials. This study computationally assessed the effects of inert spherical sand inclusions and porosity produced by inert additives on the sensitivity of the explosive composition during the shock-to-detonation transition using a limited scope approach through Lee-Tarver ignition and growth modeling. On the continuum scale, the effects of inert additives on pressure generation behind the detonation …


Framing Energy And Minerals For Future Pathways, Michelle Michot Foss, Michael S. Moats, Kwame Awuah-Offei Oct 2020

Framing Energy And Minerals For Future Pathways, Michelle Michot Foss, Michael S. Moats, Kwame Awuah-Offei

Materials Science and Engineering Faculty Research & Creative Works

We present a challenge for Group of Twenty (G20) discussions that entails (1) greater awareness of the role of non-fuel minerals in the global economy overall, but specifically in the energy sector; and (2) the introduction and acceleration of alternative energy sources and technologies. We focus on chemical battery energy storage, given its prominence in all views and outlooks of energy futures, especially for mobility. We present recommendations for G20 discussions and actions on battery materials, and the crucial underlying supply chains for mineral commodities.