Engineering Commons^™

Tio2 Coating Methods On Sb2o3 And Their Use As Anode Material In Lithium-Ion Batteries, Kithzia Czarina Gomez

Theses and Dissertations

The following thesis is concentrated on the development of TiO2Sb2O3 composite material through the hydrolysis of TiCl4 to be applied as anode material for lithium-ion batteries. Antimony (Sb) has been a material of interest due to its high capacity and good chemical properties. The TiO2 accommodated the harsh volume expansion that Sb encounters during the alloying process while still preserving the high capacity offered by Sb. Its electrochemical performance exhibited a stabilized capacity of 523 mAhg-1 after reaching 40 cycles with a capacity loss of 2.4% till reaching 100 cycles. High reversible capacity characteristics were present with an initial capacity …

Interfacial Engineering Of Nickel-Rich Layered Oxide Cathodes Via Atomic Layer Deposition (Ald), Xin Wang

Graduate Theses and Dissertations

Layered nickel-rich cathodes LiNixMnyCozO2 (NMCs, x + y + z =1, x ≥ 0.6) are regarded as one of the most promising cathode materials for next-generation lithium-ion batteries (LIBs), given their remarkably reduced cost and increased capacity compared to the conventional LiCoO2 cathode. However, the deployment of these Ni-rich cathodes has been hindered by the continuous loss of practical capacity and reduction in average working voltage, inherently due to their interfacial, structural, and thermodynamic instability. To address these issues, interfacial engineering via surface modification has been well-recognized as an effective strategy and a large number of coating materials have been …

Electric Vehicle Internal Support System, M A. Xudoyberdiyev, L V. Kravchenko, J E. Safarov, B B. Tuychiboyev

Technical science and innovation

At present, it remains relevant to protect the environment around the world, to prevent the deterioration of ecology, to ensure the health of people, to reduce the amount of exhaust gases emitted into the atmosphere in the preservation of the animal world. Currently, in solving these pressing problems, instead of cars with internal combustion engines, which are used in the automotive industry, energy-efficient electric cars that meet the modern demand, produce less exhaust gases to the environment, work without noise, have a high level of manageability, traction and braking dynamics, stability, safety and comfortability. During the use of these electric …

Development Of Novel Battery Materials For Lithium-Ion Batteries And Beyond, Jiyu Cai

Graduate Theses and Dissertations

As fossil fuels are depleting and causing environmental issues, it becomes imperative to widely implement renewable energies (e.g., solar and wind power). In this context, electrical energy storage (EES) systems are essential to accommodate the intermittent supply and uneven distribution of renewable energies. To this end, high-energy-density EES devices are highly demanded, such as rechargeable batteries. This dissertation presents my efforts in developing novel battery materials for lithium-ion batteries (LIBs), sodium-ion batteries (SIBs), and solidstate lithium batteries (SSLBs). These efforts include electrochemical evaluations of battery materials, surface modifications of electrodes via atomic layer deposition (ALD), and advanced characterizations of batteries …

Water-Soluble Polymers With Ceramic/Metal Nanoparticles For Use As Anode Materials In Lithium-Ion And Sodium-Ion Batteries, Roberto Orrostieta Chavez

Theses and Dissertations

Aqueous solutions of poly(vinylpyrrolidone) (PVP) with 20, 25, and 28 wt.% concentrations were successfully spun into fibers by centrifugal spinning. The pristine PVP fibers were annealed and carbonized to produce flexible carbon fibers for use as binder-free anodes in lithium-ion and sodium-ion batteries. These flexible carbon fibers were prepared by developing a novel three-step heat treatment to reduce the residual stresses in the pristine PVP precursor fibers and to prevent fiber degradation during carbonization. The average diameters of the pristine, annealed, and carbonized fibers were obtained using scanning electron microscopy (SEM), which showed that the average diameter of the carbon …

Advances In Materials Design For All-Solid-State Batteries: From Bulk To Thin Films, Gene Yang, Yuxi Ma, Myoungseok Lee, Evan Helfrick, Dahyun Oh, Dongkyu Lee

Faculty Publications

All-solid-state batteries (SSBs) are one of the most fascinating next-generation energy storage systems that can provide improved energy density and safety for a wide range of applications from portable electronics to electric vehicles. The development of SSBs was accelerated by the discovery of new materials and the design of nanostructures. In particular, advances in the growth of thin-film battery materials facilitated the development of all solid-state thin-film batteries (SSTFBs)—expanding their applications to microelectronics such as flexible devices and implantable medical devices. However, critical challenges still remain, such as low ionic conductivity of solid electrolytes, interfacial instability and difficulty in controlling …

Synthesis Of Sea Urchin-Like Nico2o4 Via Charge-Driven Self-Assembly Strategy For High Performance Lithium-Ion Batteries, Bin Wang, Chi-Wing Tsang, Ka Ho Li, Yuanyuan Tang, Yanping Mao, Xiao-Ying Lu

Faculty of Science & Technology (THEi)

In this study, hydrothermal synthesis of sea urchin-like NiCo2O4 was successfully demonstrated by a versatile charge-driven self-assembly strategy using positively charged poly(diallydimethylammonium chloride) (PDDA) molecules. Physical characterizations implied that sea urchin-like microspheres of ~ 2.5 μm in size were formed by self-assembly of numerous nanoneedles with a typical dimension of ~ 100 nm in diameter. Electrochemical performance study confirmed that sea urchin-like NiCo2O4 exhibited high reversible capacity of 663 mAh g−1 after 100 cycles at current density of 100 mA g−1. Rate capability indicated that average capacities of 1085, 1048, 926, 642, 261, and 86 mAh g−1 could be achieved …

Lead Doped Carbon Nanofibers In Li-Ion Batteries, Omar Torres

Theses and Dissertations

Lead acid batteries have been a very reliable rechargeable battery since its inception in the mid-1800s. Lithium-Ion batteries have been sought out for their light-weight and capacity of holding large amounts of energy in a small amount of space. Few studies have been conducted in the use of lead in lithium-ion batteries.

In this thesis, lead-doped carbon nanofibers were produced by using the Forcespinning® method and used as an anode on a lithium-ion battery. The morphology, material characterization and thermal properties of the anode material were analyzed using the Scanning Electron Microscopy (SEM), Energy Dispersive X-Ray Spectroscopy (EDS), Thermogravimetric Analysis …

Advances In Repurposing And Recycling Of Post-Vehicle-Application Lithium-Ion Batteries, Charles R. Standridge, Lindsay Corneal, Nicholas Baine

Mineta Transportation Institute

Increased electrification of vehicles has increased the use of lithium-ion batteries for energy storage, and raised the issue of what to do with post-vehicle-application batteries. Three possibilities have been identified: 1) remanufacturing for intended reuse in vehicles; 2) repurposing for non-vehicle, stationary storage applications; and 3) recycling, extracting the precious metals, chemicals and other byproducts. Advances in repurposing and recycling are presented, along with a mathematical model that forecasts the manufacturing capacity needed for remanufacturing, repurposing, and recycling. Results obtained by simulating the model show that up to a 25% reduction in the need for new batteries can be achieved …