Engineering Commons^™

Topologically Optimized Electrodes For Electroosmotic Actuation, Jianwen Sun, Jianyu Zhang, Ce Guan, Teng Zhou, Shizhi Qian, Yongbo Deng

Mechanical & Aerospace Engineering Faculty Publications

Electroosmosis is one of the most used actuation mechanisms for the microfluidics in the current active lab-on-chip devices. It is generated on the induced charged microchannel walls in contact with an electrolyte solution. Electrode distribution plays the key role on providing the external electric field for electroosmosis, and determines the performance of electroosmotic microfluidics. Therefore, this paper proposes a topology optimization approach for the electrodes of electroosmotic microfluidics, where the electrode layout on the microchannel wall can be determined to achieve designer desired microfluidic performance. This topology optimization is carried out by implementing the interpolation of electric insulation and electric …

Fabrication Of Binder-Free Electrodes Based On Graphene Oxide With Cnt For Decrease Of Resistance, Di Zhang

Masters Theses

In electrode double layer capacitor (EDLC), electrodes usually contain binder materials to provide adhesion between electrode materials. However, binder materials usually bring unwanted resistances to the component due to their non-conductivity properties and the occupation of ion cavities. The purpose of this thesis is to demonstrate the feasibility of fabricating electrodes for EDLCs by using carbon nanotubes (CNTs) and graphene oxide (GO) without using any binding materials. At the same time, investigating the binder-free electrode’s electrochemical properties and make an assumption of its potential application in the future.

The slurry of binder-free electrodes was fabricated by ultrasonicating water suspended CNTs …

Correlating Long-Term Lithium Ion Battery Performance With Solid Electrolyte Interphase (Sei) Layer Properties, Seong Jin An

Doctoral Dissertations

This study was conducted to understand effects of some of key factors (i.e., anode surface properties, formation cycling conditions, and electrolyte conditions) on solid electrolyte interphase (SEI) formation in lithium ion batteries (LIBs) and the battery cycle life. The SEI layer passivates electrode surfaces and prevents electron transfer and electrolyte diffusion through it while allowing lithium ion diffusion, which is essential for stable reversible capacities. It also influences initial capacity loss, self-discharge, cycle life, rate capability and safety. Thus, SEI layer formation and electrochemical stability are primary topics in LIB development. This research involves experiments and discussions on key factors …

Nanocomposite Bioelectronics For Biopotential Enabled Prosthesis, Dong Sup Lee

Theses and Dissertations

Soft material-enabled electronics can demonstrate extreme mechanical flexibility and stretchability. Such compliant, comfortable electronics allow continuous, long-term measurement of biopotentials on the skin. Manufacturing of the stretchable electronic devices is enabled by the recent development combining materials transfer printing and microfabrication. However, the existing method using inorganic materials and multi-layered polymers requires long material preparation time and expensive processing cost due to the requirement of microfabrication tools and complicated transfer printing steps. Here, this study develops a new fabrication method of soft electronics via a micro-replica-molding technique, which allows fast production, multiple use, and low cost by avoiding microfabrication and …

Impedance-Resolved Performance And Durability In Redox Flow Batteries, Alan Michael Pezeshki

Doctoral Dissertations

The realization of redox flow batteries (RFBs) as a grid-scale energy solution depends on improving the performance and lifetime of the technology to decrease the high capital costs. The electrodes are a key component in the RFB; performance enhancement is often achieved through chemical or thermal treatments of commercially available porous carbon materials.

This dissertation uses impedance spectroscopy-based methods to gain insight into performance and durability in RFBs, enabling intelligent cell design. Initial work focused on understanding the impact of improved electrode and membrane properties on system performance. An accelerated stress test was then developed that can be used to …

A Case Study Of Multiple-Use Finish Electrodes For Die-Sinking Edm, Troy A. Robertson

Masters Theses & Specialist Projects

This study examines the use of one finishing electrode to finish multiple dies without remachining the electrode. The multiple-use electrode finishing experiment in this study addresses technology in the die-forging industry. Methods of manufacturing spherical straight bevel forge gear dies have relied on die-sinking Electrical Discharge Machining (EDM) practices that showed great potential for advancement. The focus of this study is solely on the improvements of electrode use in EDM finishing-processes. The surface finish quality itself is not an area of concern other than maintaining that it does not diminish. The focused concern is maximizing the process by using one …

Investigating The Electrical Discharge Machining (Edm) Parameter Effects On Al-Mg2si Metal Matrix Composite (Mmc) For High Material Removal Rate (Mrr) And Less Ewr-Rsm Approach

Faculty of Engineering University of Malaya

Al-Mg2Si composite is a new group of metalmatrix composites (MMCs). Electrical discharge machining (EDM) is a nonconventional machining process for machining electrically conductive materials regardless of hardness, strength and temperature resistance, complex shapes, fine surface finish/textures and accurate dimensions. A copper electrode and oil-based dielectric fluid mixed with aluminum powder were used. The polarity of electrode was positive. Response surface methodology (RSM) was used to analyze EDM of this composite material. This research illustrates the effect of input variables (voltage, current, pulse ON time, and duty factor) on material removal rate (MRR), electrode wear ratio (EWR), and microstructure changes. The …

Synthesis And Characterization Of Birnessite And Cryptomelane Nanostructures In Presence Of Hoffmeister Anions, Marcos A. Cheney, Robin Jose, Arghya Banerjee, Pradip K. Bhowmik, Shizhi Qian, Joseph M. Okoh

Mechanical & Aerospace Engineering Faculty Publications

The effect of Hoffmeister anions Cl(-), SO(4) (2-), and ClO(4) (-) on the structure and morphology of birnessite and cryptomelane-type manganese dioxide nanostructures, produced by the reduction reaction of KMnO(4) and MnSO(4) in aqueous acidic media, was studied. The syntheses were based on the decomposition of aqueous KMnO(4) in presence of HCl for birnessite-type and acidified MnSO4 for cryptomelane-type manganese dioxide under soft hydrothermal conditions. They were characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), and high-resolution transmission electron microscopy (HRTEM) techniques. XRD patterns show the formation of birnessite for the first synthesis and a mixture of cryptomelane and …

An Investigation Into Fuel Cells And Flow Cytometers Optimal Design, Etim Sunday Udoetok

LSU Doctoral Dissertations

The aim of the fuel cells part of this project was to investigate the performance of Proton Exchange Membrane Fuel Cells and closely related fuel cell types like the Alkaline Fuel Cells and Phosphoric Acid Fuel Cells. The investigation involved understanding the performance of fuel cells, addressing the shortcomings of currently used designs, and finding new methods for improving the performance of fuel cells. CFD was used to study flow channels and information learned from the study was used to design a new and improved flow channel. A prototype of the new design was fabricated, tested and found to perform …