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Full-Text Articles in Engineering
La0.85Sr0.15Mno3− Infiltrated Y0.5Bi1.5O3 Cathodes For Intermediate-Temperature Solid Oxide Fuel Cells, Jiang Zhiyi, Changrong Xia, Fei Zhao, Fanglin Chen
La0.85Sr0.15Mno3− Infiltrated Y0.5Bi1.5O3 Cathodes For Intermediate-Temperature Solid Oxide Fuel Cells, Jiang Zhiyi, Changrong Xia, Fei Zhao, Fanglin Chen
Fanglin Chen
Porous yttria-stabilized bismuth oxides (YSB) were investigated as the backbones for La0.85Sr0.15MnO3−#1;(LSM) infiltrated cathodes in intermediate-temperature solid oxide fuel cells. The cathodes were evaluated using anode-supported single cells with scandia-stabilized zirconia as the electrolytes. With humidified H2 as the fuel, the cell showed peak power density of 0.33, 0.52, and 0.74 W cm−2 at 650, 700, and 750°C, respectively. At 650°C, the cell polarization resistance was only 1.38 Ω cm2, <50% of the lowest value previously reported, indicating that YSB is a promising backbone for the LSM infiltrated cathode.
Sol-Gel Synthesis Of A New Oxide-Ion Conductor Sr- And Mg-Doped Lagao3 Perovskite, Kevin Huang, Man Feng, John Goodenough
Sol-Gel Synthesis Of A New Oxide-Ion Conductor Sr- And Mg-Doped Lagao3 Perovskite, Kevin Huang, Man Feng, John Goodenough
Kevin Huang
No abstract provided.
Increasing Power Density Of Lsgm-Based Solid Oxide Fuel Cells Using New Anode Materials, Kevin Huang, Jen-Hau Wan, John Goodenough
Increasing Power Density Of Lsgm-Based Solid Oxide Fuel Cells Using New Anode Materials, Kevin Huang, Jen-Hau Wan, John Goodenough
Kevin Huang
Chemical reactions between the superior perovskite oxide-ion conductor Sr- and Mg-doped LaGaO3 (LSGM), CeO2, and NiO have been studied by powder X-ray diffraction. The results showed that an extensive reactivity occurs as a result of La migration driven by a gradient of La chemical activity. La migration across the LSGM/electrode interfaces in a fuel cell leads to the formation of resistive phases at the interface, either LaSrGa3O7 or LaSrGaO4. Use of 40 mol % La2O3 -doped CeO2 as an interlayer between anode and electrolyte as well as in the NiO-containing anode prevents all reactions found. Consequently, the air-H2 cell maximum …
Electrode Performance Test On Single Ceramic Fuel Cells Using As Electrolyte Sr‐ And Mg‐Doped Lagao3, Kevin Huang, Man Feng, John Goodenough, Christopher Milliken
Electrode Performance Test On Single Ceramic Fuel Cells Using As Electrolyte Sr‐ And Mg‐Doped Lagao3, Kevin Huang, Man Feng, John Goodenough, Christopher Milliken
Kevin Huang
The electrode performance of a single solid oxide fuel cell was evaluated using a 500 μm thick La0.9Sr0.1Ga0.8Mg0.2O2.85 (LSGM) as the electrolyte membrane. Comparison of La0.6Sr0.4CoO3-δ (LSCo) and La0.9Sr0.1MnO3 (LSM) as cathodes showed LSCo gave an exchange current density two orders of magnitude higher than that of LSM. Comparison of CeO2/Ni and LSGM/Ni as anodes showed a degradation of the latter with time, and studies of the anode‐electrolyte interface and the reactivity of NiO and LSGM suggest better anode …
Oxygen Permeation Through Cobalt-Containing Perovskites: Surface Oxygen Exchange Vs. Lattice Oxygen Diffusion, Kevin Huang, John B. Goodenough
Oxygen Permeation Through Cobalt-Containing Perovskites: Surface Oxygen Exchange Vs. Lattice Oxygen Diffusion, Kevin Huang, John B. Goodenough
Kevin Huang
The oxygen permeation fluxes from p′O2 to pnO2 (p′O2>pnO2) across cobalt-containing perovskite ceramic membranes La1−xSrxCoO3−δ and SrCo0.8Fe0.2O3−δ were measured by gas chromatography as functions of oxygen chemical potential gradient, temperature, thickness, and catalytic activity on the surface. Power indexes 0.5>n>0 for uncatalyzed La1−xSrxCoO3−δ and 1>n>0.5 for SrCo0.8Fe0.2O3−δ were obtained when JO2 vs. p′nO2−p'′nO2 …