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Full-Text Articles in Engineering

An Investigation Of The Effect Of Direct Metal Deposition Parameters On The Characteristics Of The Deposited Layers, Tarak A. Amine, Joseph William Newkirk, Frank W. Liou Jul 2014

An Investigation Of The Effect Of Direct Metal Deposition Parameters On The Characteristics Of The Deposited Layers, Tarak A. Amine, Joseph William Newkirk, Frank W. Liou

Materials Science and Engineering Faculty Research & Creative Works

Multilayer direct laser deposition (DLD) is a fabrication process through which parts are fabricated by creating a molten pool into which metal powder is injected as particles. During fabrication, complex thermal activity occurs in different regions of the build; for example, newly deposited layers will reheat previously deposited layers. The objective of this study was to provide insight into the thermal activity that occurs during the DLD process. This work focused on the effect of the laser parameters of newly deposited layers on the microstructure and mechanical properties of the previously deposited layers in order to characterize these effects to …


Redox Stable Anodes For Solid Oxide Fuel Cells, Guoliang Xiao, Fanglin Chen Jun 2014

Redox Stable Anodes For Solid Oxide Fuel Cells, Guoliang Xiao, Fanglin Chen

Faculty Publications

Solid oxide fuel cells (SOFCs) can convert chemical energy from the fuel directly to electrical energy with high efficiency and fuel flexibility. Ni-based cermets have been the most widely adopted anode for SOFCs. However, the conventional Ni-based anode has low tolerance to sulfur-contamination, is vulnerable to deactivation by carbon build-up (coking) from direct oxidation of hydrocarbon fuels, and suffers volume instability upon redox cycling. Among these limitations, the redox instability of the anode is particularly important and has been intensively studied since the SOFC anode may experience redox cycling during fuel cell operations even with the ideal pure hydrogen as …


Bridging The Nano- And Macro-Worlds: Thermal Property Measurement Using Thermal Microscopy And Photothermal Radiometry – Application To Particle-Irradiation Damage Profile In Zirconium Carbide, Colby Bruce Jensen May 2014

Bridging The Nano- And Macro-Worlds: Thermal Property Measurement Using Thermal Microscopy And Photothermal Radiometry – Application To Particle-Irradiation Damage Profile In Zirconium Carbide, Colby Bruce Jensen

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Multiscaled experimental investigations of heat transfer from nanoscales to macroscales are requisite to progress in energy technologies. In nuclear applications, material properties can undergo significant alteration due to destructive interaction with irradiating particles at microstructural levels that affect bulk properties. This study expands the current knowledge base regarding thermal transport in ion-irradiated materials through the use of a multiscaled experimental approach using four complementary thermal wave methods. For the first time, the in-depth thermal conductivity profile of an ion-irradiated sample is measured directly.


Microstructure, Quasi-Static, And High-Strain Rate Dynamic Characterization Of Metakaolin And Fly Ash Based Geopolymers For Structural Applications, Damian Lee Stoddard Jan 2014

Microstructure, Quasi-Static, And High-Strain Rate Dynamic Characterization Of Metakaolin And Fly Ash Based Geopolymers For Structural Applications, Damian Lee Stoddard

Electronic Theses and Dissertations

Geopolymers are a class of rapid setting cementing systems that have been used as mortar or additives in concrete mixes to improve properties. Several types of geopolymer systems such as metakaolin and fly ash based geopolymers are widely used, and are available in different mixture proportions [1, 2]. Metakaolin (Al2Si2O7), a dehydroxylated form of Kaolinite (Al2Si2O5(OH)4) clay readily available from many sources, provides several benefits whenadded to a concrete mix design or used as a mortar system, including durability, freeze/thaw, acid resistance, and high temperature resistance [3]. Class F fly ash-based mortar geopolymers provide added fire retardation, reduces crack formation, …


Synthesis, Microstructure And Performance Evaluation Of Gadolinium Incorporated Cobalt Ferrite Ceramics, Md Taibur Rahman Jan 2014

Synthesis, Microstructure And Performance Evaluation Of Gadolinium Incorporated Cobalt Ferrite Ceramics, Md Taibur Rahman

Open Access Theses & Dissertations

Spinel structured ferrites exhibit remarkable properties and phenomena, which are attractive for application in sensors and actuators, magneto-electronics, and electrochemical energy storage devices. Among spinel ferrites, cobalt ferrite CoFe2O4 (CFO) has attracted remarkable attention and widely studied because of their electro-magnetic properties, chemical stability and mechanical hardness. The properties and phenomena of CFO ceramics are dependent on microstructure and chemistry, which in turn depend on the synThesis processes and conditions employed for fabrication. Generally exact chemical composition, processing temperature, reactive or processing atmosphere (if any) and the ions that substitute Fe3+/Fe2+ ions dictate the …


Influence Of Crystal Structure On The Electrochemical Performance Of A-Site-Deficient Sr1-SNb0.1Co0.9O3-Δ Perovskite Cathodes, Yinlong Zhu, Ye Lin, Xuan Shen, Jaka Sunarso, Wei Zhou, Shanshan Jiang, Dong Su, Fanglin Chen, Zongping Shao Jan 2014

Influence Of Crystal Structure On The Electrochemical Performance Of A-Site-Deficient Sr1-SNb0.1Co0.9O3-Δ Perovskite Cathodes, Yinlong Zhu, Ye Lin, Xuan Shen, Jaka Sunarso, Wei Zhou, Shanshan Jiang, Dong Su, Fanglin Chen, Zongping Shao

Faculty Publications

The creation of A-site cation defects within a perovskite oxide can substantially alter the structure and properties of its stoichiometric analogue. In this work, we demonstrate that by vacating 2 and 5% of Asite cations from SrNb0.1Co0.9O3-δ (SNC1.00) perovskites (Sr1-sNb0.1Co0.9O3-δ,s = 0.02 and 0.05; denoted as SNC0.98 and SNC0.95, respectively), a Jahn–Teller (JT) distortion with varying extents takes place, leading to the formation of a modified crystal lattice within a the perovskite framework. Electrical conductivity, electrochemical performance, chemical compatibility and microstructure of Sr1-sNb0.1Co …