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Impact Of Cycloalkanes On Ignition Propensity Measured As Derived Cetane Number In Multi-Component Surrogate Mixtures, Dalton Odell Carpenter

Theses and Dissertations

Cycloalkanes are one type of hydrocarbons present in real jet fuels. The distinct cyclic structure of the cyclo-alkanes impacts the chemical kinetic behavior differently compared to n- and iso-alkanes. At high temperatures, thermal decomposition reactions dominate, producing n-alkyl radicals similar to the oxidation reactions of n-alkanes thus promoting the reactivity. Whereas in low temperatures, the presence of the ring structure essentially suppresses the formation of alkylhydroperoxy radicals (QOOH) from alkylperoxy radicals (RO2), thus exhibiting similar reactivity to iso-alkanes. In previous generations of surrogate fuels, the cyclo-alkane functional group were largely ignored due to low levels of cycloalkanes in traditional jet …