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Numerical Stimulation Of Stress-Induced Crystallization Of Injection Molded Semicrystalline Thermoplastics, Jianxin Guo

Dissertations

Injection molded semicrystalline plastic products exhibit variable morphology along their thickness directions. The processing conditions have a significant effect on the crystallinity distribution in the final parts. However, because of the lack of sound theoretical models for stress-induced crystallization kinetics in thermoplastics, simulations of the injection molding process of semicrystalline plastics with the consideration of stress-induced crystallization have been scarce.

A stress-induced crystallization model for semicrystalline plastics is proposed based on the theory that stress induced orientation of polymer chains increase the melting temperature of the plastics, and hence, the supercooling which is the driving force for crystallization. By assuming …