Engineering Commons^™

Centrifugally Spun Α-Fe2o3/Tio2/Carbon Composite Fibers As Anode Materials For Lithium-Ion Batteries, Luis Zuniga, Gabriel Gonzalez, Roberto Orrostieta Chavez, Jason C. Myers, Timothy P. Lodge, Mataz Alcoutlabi

Mechanical Engineering Faculty Publications and Presentations

We report results on the electrochemical performance of flexible and binder-free α-Fe₂O₃/TiO₂/carbon composite fiber anodes for lithium-ion batteries (LIBs). The composite fibers were produced via centrifugal spinning and subsequent thermal processing. The fibers were prepared from a precursor solution containing PVP/iron (III) acetylacetonate/titanium (IV) butoxide/ethanol/acetic acid followed by oxidation at 200 °C in air and then carbonization at 550 °C under flowing argon. The morphology and structure of the composite fibers were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), …

Synthesis Of Multiwall Α-Fe2o3 Hollow Fibers Via A Centrifugal Spinning Technique, Mandana Akia, K. A. Mkhoyan, Karen Lozano

Mechanical Engineering Faculty Publications and Presentations

Highlights

• Hollow hematite (α-Fe2O3) fine fibers were fabricated via a simple, flexible, and scalable technique.

• An aqueous solution with iron precursor/polymer was used in the centrifugal spinning process

• Developed fibers show average wall thickness of 55 ± 15 nm and outer fiber diameter of 852 ± 86 nm

Abstract

Hollow hematite (α-Fe2O3) fine fibers with multiwall structure were synthesized by utilizing a centrifugal spinning technique. Aqueous solutions of polyvinyl pyrrolidone and iron (III) nitrate nonahydrate were prepared and spun into fibers. The precursor fibers were heat treated at 650 °C to form iron oxide fibers. Scanning electron micrographs revealed the …

Fabrication And Characterization Of Centrifugally Spun Poly(Acrylic Acid) Nanofibers, David De La Garza, Francisco De Santiago, Luis Materon, Mircea Chipara, Mataz Alcoutlabi

Mechanical Engineering Faculty Publications and Presentations

The production of poly(acrylic acid) (PAA) nanofibers by the centrifugal spinning of PAA solutions in water is reported. The effect of the spinneret rotational speed and concentration of PAA solutions on the diameter of nanofibers and on their quality (assessed by the absence of beads) is discussed. The main physical properties of PAA such as glass-transition temperature (Tg) are studied in detail and compared to the feature of the as-received homopolymer. It is shown that the glass-transition temperature of the bulk PAA and PAA nanofibers (as measured by differential scanning calorimetry) depends on the heating rate according …