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Fabrication And Characterization Of Centrifugally Spun Poly(Acrylic Acid) Nanofibers, David De La Garza, Francisco De Santiago, Luis Materon, Mircea Chipara, Mataz Alcoutlabi

Mechanical Engineering Faculty Publications and Presentations

The production of poly(acrylic acid) (PAA) nanofibers by the centrifugal spinning of PAA solutions in water is reported. The effect of the spinneret rotational speed and concentration of PAA solutions on the diameter of nanofibers and on their quality (assessed by the absence of beads) is discussed. The main physical properties of PAA such as glass-transition temperature (Tg) are studied in detail and compared to the feature of the as-received homopolymer. It is shown that the glass-transition temperature of the bulk PAA and PAA nanofibers (as measured by differential scanning calorimetry) depends on the heating rate according …